Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000100011 |
Resumo: | Effects of hyperbranched polyesters on kinetics of the reaction between hydroxyl-terminated polybutadiene (HTPB) and isophorone diisocyanate (IPDI) were investigated. HTPB and IPDI were in-situ cured in the presence of two different hyperbranched polyesters, stearic acid ester-terminated hyperbranched polyester (SHPE) and acetate-terminated hyperbranched polyester (AHPE). The curing processes were monitored by quantitative Fourier transform infrared (FTIR) spectroscopy. The results showed the stearic acid ester-terminated hyperbranched polyester had catalytic effects on the reaction between HTPB and IPDI, while acetate-terminated hyperbranched polyester did not have an influence on the reaction between HTPB and IPDI. |
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Materials research (São Carlos. Online) |
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Effect of hyperbranched polyesters on HTPB polyurethane curing kineticpolyurethanecuring kineticshyperbranched polyestercatalysis effectFTIRend-groupEffects of hyperbranched polyesters on kinetics of the reaction between hydroxyl-terminated polybutadiene (HTPB) and isophorone diisocyanate (IPDI) were investigated. HTPB and IPDI were in-situ cured in the presence of two different hyperbranched polyesters, stearic acid ester-terminated hyperbranched polyester (SHPE) and acetate-terminated hyperbranched polyester (AHPE). The curing processes were monitored by quantitative Fourier transform infrared (FTIR) spectroscopy. The results showed the stearic acid ester-terminated hyperbranched polyester had catalytic effects on the reaction between HTPB and IPDI, while acetate-terminated hyperbranched polyester did not have an influence on the reaction between HTPB and IPDI.ABM, ABC, ABPol2014-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000100011Materials Research v.17 n.1 2014reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392013005000193info:eu-repo/semantics/openAccessSong,XuejingYunjun,Luoeng2014-03-13T00:00:00Zoai:scielo:S1516-14392014000100011Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2014-03-13T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic |
title |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic |
spellingShingle |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic Song,Xuejing polyurethane curing kinetics hyperbranched polyester catalysis effect FTIR end-group |
title_short |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic |
title_full |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic |
title_fullStr |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic |
title_full_unstemmed |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic |
title_sort |
Effect of hyperbranched polyesters on HTPB polyurethane curing kinetic |
author |
Song,Xuejing |
author_facet |
Song,Xuejing Yunjun,Luo |
author_role |
author |
author2 |
Yunjun,Luo |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Song,Xuejing Yunjun,Luo |
dc.subject.por.fl_str_mv |
polyurethane curing kinetics hyperbranched polyester catalysis effect FTIR end-group |
topic |
polyurethane curing kinetics hyperbranched polyester catalysis effect FTIR end-group |
description |
Effects of hyperbranched polyesters on kinetics of the reaction between hydroxyl-terminated polybutadiene (HTPB) and isophorone diisocyanate (IPDI) were investigated. HTPB and IPDI were in-situ cured in the presence of two different hyperbranched polyesters, stearic acid ester-terminated hyperbranched polyester (SHPE) and acetate-terminated hyperbranched polyester (AHPE). The curing processes were monitored by quantitative Fourier transform infrared (FTIR) spectroscopy. The results showed the stearic acid ester-terminated hyperbranched polyester had catalytic effects on the reaction between HTPB and IPDI, while acetate-terminated hyperbranched polyester did not have an influence on the reaction between HTPB and IPDI. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-02-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000100011 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000100011 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1516-14392013005000193 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.17 n.1 2014 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212663675584512 |