Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study
Autor(a) principal: | |
---|---|
Data de Publicação: | 2017 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000601492 |
Resumo: | The corrosion inhibition of nanoparticulates zinc ferrite (NZF) pigment was studied. The steel samples were immersed in the NZF pigment extract in 3.5 wt. % NaCl. Electrochemical tests such as electrochemical impedance spectroscopy (EIS) and polarization as well as surface analysis were employed to evaluate the effect of NZF on the steel corrosion. The concentration of Zn and Fe in the pigment extracts before and after immersion of mild steel samples was evaluated by inductively coupled plasma-optical emission spectrometry (ICP-OES). EIS results in total agreement with results of polarization test demonstrated superiority of NZF as an anticorrosion pigment. In the case of samples exposed to NZF extract, the higher resistance and lower double layer capacitance extracted from impedance spectra as well as lower current density from polarization results might be attributed to precipitation of an inhibitive layer on the surface. This was also supported by SEM/EDS and ICP-OES results. |
id |
ABMABCABPOL-1_e965ee538c1e9247391143e208d65700 |
---|---|
oai_identifier_str |
oai:scielo:S1516-14392017000601492 |
network_acronym_str |
ABMABCABPOL-1 |
network_name_str |
Materials research (São Carlos. Online) |
repository_id_str |
|
spelling |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract StudyCorrosion inhibitorZinc ferrite pigmentPigment extractEISICP-OESThe corrosion inhibition of nanoparticulates zinc ferrite (NZF) pigment was studied. The steel samples were immersed in the NZF pigment extract in 3.5 wt. % NaCl. Electrochemical tests such as electrochemical impedance spectroscopy (EIS) and polarization as well as surface analysis were employed to evaluate the effect of NZF on the steel corrosion. The concentration of Zn and Fe in the pigment extracts before and after immersion of mild steel samples was evaluated by inductively coupled plasma-optical emission spectrometry (ICP-OES). EIS results in total agreement with results of polarization test demonstrated superiority of NZF as an anticorrosion pigment. In the case of samples exposed to NZF extract, the higher resistance and lower double layer capacitance extracted from impedance spectra as well as lower current density from polarization results might be attributed to precipitation of an inhibitive layer on the surface. This was also supported by SEM/EDS and ICP-OES results.ABM, ABC, ABPol2017-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000601492Materials Research v.20 n.6 2017reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2016-0772info:eu-repo/semantics/openAccessMahvidi,SadeghGharagozlou,MehrnazMahdavian,MohammadNaghibi,Sanazeng2018-05-18T00:00:00Zoai:scielo:S1516-14392017000601492Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2018-05-18T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study |
title |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study |
spellingShingle |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study Mahvidi,Sadegh Corrosion inhibitor Zinc ferrite pigment Pigment extract EIS ICP-OES |
title_short |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study |
title_full |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study |
title_fullStr |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study |
title_full_unstemmed |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study |
title_sort |
Potency of ZnFe2O4 Nanoparticles as Corrosion Inhibitor for Stainless Steel; the Pigment Extract Study |
author |
Mahvidi,Sadegh |
author_facet |
Mahvidi,Sadegh Gharagozlou,Mehrnaz Mahdavian,Mohammad Naghibi,Sanaz |
author_role |
author |
author2 |
Gharagozlou,Mehrnaz Mahdavian,Mohammad Naghibi,Sanaz |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Mahvidi,Sadegh Gharagozlou,Mehrnaz Mahdavian,Mohammad Naghibi,Sanaz |
dc.subject.por.fl_str_mv |
Corrosion inhibitor Zinc ferrite pigment Pigment extract EIS ICP-OES |
topic |
Corrosion inhibitor Zinc ferrite pigment Pigment extract EIS ICP-OES |
description |
The corrosion inhibition of nanoparticulates zinc ferrite (NZF) pigment was studied. The steel samples were immersed in the NZF pigment extract in 3.5 wt. % NaCl. Electrochemical tests such as electrochemical impedance spectroscopy (EIS) and polarization as well as surface analysis were employed to evaluate the effect of NZF on the steel corrosion. The concentration of Zn and Fe in the pigment extracts before and after immersion of mild steel samples was evaluated by inductively coupled plasma-optical emission spectrometry (ICP-OES). EIS results in total agreement with results of polarization test demonstrated superiority of NZF as an anticorrosion pigment. In the case of samples exposed to NZF extract, the higher resistance and lower double layer capacitance extracted from impedance spectra as well as lower current density from polarization results might be attributed to precipitation of an inhibitive layer on the surface. This was also supported by SEM/EDS and ICP-OES results. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000601492 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000601492 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2016-0772 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.20 n.6 2017 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212671422464000 |