Conductive Composites Based on Polyurethane and Nanostructured Conductive Filler of Montmorillonite/Polypyrrole for Electromagnetic Shielding Applications

• Autor(a) principal: Vargas,Patricia Cristine
• Data de Publicação: 2018
• Outros Autores: Merlini,Claudia, Ramôa,Sílvia Daniela Araújo da Silva, Arenhart,Rafael, Barra,Guilherme Mariz de Oliveira, Soares,Bluma Guenther
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Materials research (São Carlos. Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000500224
• topic: Polypyrrole; montmorillonite; polyurethane derived from castor oil; electromagnetic interference shielding application

In this study, composites based on polyurethane (PU) derived from castor oil and montmorillonite/polypyrrole doped with dodecylbenzenesulfonic acid (MMt-PPy.DBSA) were developed. In order to investigate the potential use of these materials for electromagnetic shielding applications, the electrical and mechanical properties of PU/MMt-PPy.DBSA composites were determined and compared with composites containing neat PPy.DBSA. The electrical conductivity of PU/MMt-PPy.DBSA composites was found to be higher than those for PU/PPy.DBSA with a similar filler content. Additionally, with a higher conductive additive content, significant increases in the tensile stress (σ) and elastic modulus (E) were observed, suggesting that MMt-PPy.DBSA acts as reinforcing agent for the PU matrix. The electromagnetic interference shielding effectiveness (EMI SE) of composites is mainly dependent on the morphology and filler content. The PU/MMt-PPy.DBSA composite containing 25 wt % of MMt-PPy.DBSA showed a maximum EMI SE of -21 dB, which is similar to the value required for commercial applications (-20 dB). The results revealed that PU/MMt-PPy.DBSA composites are promising materials for electromagnetic shielding applications.