Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000600209 |
Resumo: | Abstract Phase diagram of the Bi-Ce-Ge ternary system has been investigated experimentally and thermodynamically extrapolated by using Pandat software. Experimental results were obtained using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Examined ternary samples belong to two isothermal sections at 400 and 600 °C as well as three vertical sections Bi-CuGe, Cu-BiGe, and Ge-BiCu. No ternary compound has been detected in the equilibrated samples from the selected isothermal sections. Based on the presented experimental data and available literature data, description of the ternary system has been developed. A reasonable agreement between the experimental data and the calculated phase equilibria was obtained. As an example, ternary Cu80Bi10Ge10 alloy was selected for solidification simulations according to Scheil and Lever Rule assumptions as well as for simulation of the total fraction of each solid at different temperatures, latent heat, and total heat. |
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Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge Systemphase equilibriaternary Bi-Cu-Ge systemexperimental testsAbstract Phase diagram of the Bi-Ce-Ge ternary system has been investigated experimentally and thermodynamically extrapolated by using Pandat software. Experimental results were obtained using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Examined ternary samples belong to two isothermal sections at 400 and 600 °C as well as three vertical sections Bi-CuGe, Cu-BiGe, and Ge-BiCu. No ternary compound has been detected in the equilibrated samples from the selected isothermal sections. Based on the presented experimental data and available literature data, description of the ternary system has been developed. A reasonable agreement between the experimental data and the calculated phase equilibria was obtained. As an example, ternary Cu80Bi10Ge10 alloy was selected for solidification simulations according to Scheil and Lever Rule assumptions as well as for simulation of the total fraction of each solid at different temperatures, latent heat, and total heat.ABM, ABC, ABPol2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000600209Materials Research v.24 n.6 2021reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2021-0201info:eu-repo/semantics/openAccessMilosavljevic,MilanPremovic,MilenaMinic,DuskoCosovic,VladanDjordjevic,AleksandarTomovic,Milicaeng2021-09-16T00:00:00Zoai:scielo:S1516-14392021000600209Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2021-09-16T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System |
title |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System |
spellingShingle |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System Milosavljevic,Milan phase equilibria ternary Bi-Cu-Ge system experimental tests |
title_short |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System |
title_full |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System |
title_fullStr |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System |
title_full_unstemmed |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System |
title_sort |
Experimental Investigation of Phase Equilibria in the Bi-Cu-Ge System |
author |
Milosavljevic,Milan |
author_facet |
Milosavljevic,Milan Premovic,Milena Minic,Dusko Cosovic,Vladan Djordjevic,Aleksandar Tomovic,Milica |
author_role |
author |
author2 |
Premovic,Milena Minic,Dusko Cosovic,Vladan Djordjevic,Aleksandar Tomovic,Milica |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Milosavljevic,Milan Premovic,Milena Minic,Dusko Cosovic,Vladan Djordjevic,Aleksandar Tomovic,Milica |
dc.subject.por.fl_str_mv |
phase equilibria ternary Bi-Cu-Ge system experimental tests |
topic |
phase equilibria ternary Bi-Cu-Ge system experimental tests |
description |
Abstract Phase diagram of the Bi-Ce-Ge ternary system has been investigated experimentally and thermodynamically extrapolated by using Pandat software. Experimental results were obtained using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Examined ternary samples belong to two isothermal sections at 400 and 600 °C as well as three vertical sections Bi-CuGe, Cu-BiGe, and Ge-BiCu. No ternary compound has been detected in the equilibrated samples from the selected isothermal sections. Based on the presented experimental data and available literature data, description of the ternary system has been developed. A reasonable agreement between the experimental data and the calculated phase equilibria was obtained. As an example, ternary Cu80Bi10Ge10 alloy was selected for solidification simulations according to Scheil and Lever Rule assumptions as well as for simulation of the total fraction of each solid at different temperatures, latent heat, and total heat. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000600209 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392021000600209 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2021-0201 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.24 n.6 2021 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212679501742080 |