Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392003000400006 |
Resumo: | The objective of this work has been to compare the reliability of two Si3N4 ceramics, with Y2O3/Al2O3 or CTR2O3/Al2O3 mixtures as additives, in regard to their 4-point bending strength and to confirm the potential of the rare earth oxide mixture, CTR2O3, produced at FAENQUIL, as an alternative, low cost sinter additive for pure Y2O3 in the sintering of Si3N4 ceramics. The oxide mixture CTR2O3 is a solid solution formed mainly by Y2O3, Er2O3, Yb2O3 and Dy2O3 with other minor constituents and is obtained at a cost of only 20% of pure Y2O3. Samples were sintered by a gas pressure sintering process at 1900 °C under a nitrogen pressure of 1.5 MPa and an isothermal holding time of 2 h. The obtained materials were characterized by their relative density, phase composition and bending strength. The Weibull analysis was used to describe the reliability of these materials. Both materials produced presented relative densities higher than 99.5%t.d., b-Si3N4 and Y3Al5O12 (YAG) as cristalline phases and bending strengths higher than 650 MPa, thus demonstrating similar behaviors regarding their physical, chemical and mechanical characteristics. The statistical analysis of their strength also showed similar results for both materials, with Weibull moduli m of about 15 and characteristic stress values s o of about 700 MPa. These results confirmed the possibility of using the rare earth oxide mixture, CTR2O3, as sinter additive for high performance Si3N4 ceramics, without prejudice of the mechanical properties when compared to Si3N4 ceramics sintered with pure Y2O3. |
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Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysisSi3N4rare earth oxidesmechanical propertiesWeibull analysisThe objective of this work has been to compare the reliability of two Si3N4 ceramics, with Y2O3/Al2O3 or CTR2O3/Al2O3 mixtures as additives, in regard to their 4-point bending strength and to confirm the potential of the rare earth oxide mixture, CTR2O3, produced at FAENQUIL, as an alternative, low cost sinter additive for pure Y2O3 in the sintering of Si3N4 ceramics. The oxide mixture CTR2O3 is a solid solution formed mainly by Y2O3, Er2O3, Yb2O3 and Dy2O3 with other minor constituents and is obtained at a cost of only 20% of pure Y2O3. Samples were sintered by a gas pressure sintering process at 1900 °C under a nitrogen pressure of 1.5 MPa and an isothermal holding time of 2 h. The obtained materials were characterized by their relative density, phase composition and bending strength. The Weibull analysis was used to describe the reliability of these materials. Both materials produced presented relative densities higher than 99.5%t.d., b-Si3N4 and Y3Al5O12 (YAG) as cristalline phases and bending strengths higher than 650 MPa, thus demonstrating similar behaviors regarding their physical, chemical and mechanical characteristics. The statistical analysis of their strength also showed similar results for both materials, with Weibull moduli m of about 15 and characteristic stress values s o of about 700 MPa. These results confirmed the possibility of using the rare earth oxide mixture, CTR2O3, as sinter additive for high performance Si3N4 ceramics, without prejudice of the mechanical properties when compared to Si3N4 ceramics sintered with pure Y2O3.ABM, ABC, ABPol2003-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392003000400006Materials Research v.6 n.4 2003reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392003000400006info:eu-repo/semantics/openAccessSantos,Claudinei dosStrecker,KurtPiorino Neto,FranciscoSilva,Olivério Moreira de MacedoBaldacim,Sandro AparecidoSilva,Cosme Roberto Moreira daeng2004-01-19T00:00:00Zoai:scielo:S1516-14392003000400006Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2004-01-19T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis |
title |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis |
spellingShingle |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis Santos,Claudinei dos Si3N4 rare earth oxides mechanical properties Weibull analysis |
title_short |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis |
title_full |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis |
title_fullStr |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis |
title_full_unstemmed |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis |
title_sort |
Evaluation of the reliability of Si3N4-Al2O3 -CTR2O3 ceramics through Weibull analysis |
author |
Santos,Claudinei dos |
author_facet |
Santos,Claudinei dos Strecker,Kurt Piorino Neto,Francisco Silva,Olivério Moreira de Macedo Baldacim,Sandro Aparecido Silva,Cosme Roberto Moreira da |
author_role |
author |
author2 |
Strecker,Kurt Piorino Neto,Francisco Silva,Olivério Moreira de Macedo Baldacim,Sandro Aparecido Silva,Cosme Roberto Moreira da |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Santos,Claudinei dos Strecker,Kurt Piorino Neto,Francisco Silva,Olivério Moreira de Macedo Baldacim,Sandro Aparecido Silva,Cosme Roberto Moreira da |
dc.subject.por.fl_str_mv |
Si3N4 rare earth oxides mechanical properties Weibull analysis |
topic |
Si3N4 rare earth oxides mechanical properties Weibull analysis |
description |
The objective of this work has been to compare the reliability of two Si3N4 ceramics, with Y2O3/Al2O3 or CTR2O3/Al2O3 mixtures as additives, in regard to their 4-point bending strength and to confirm the potential of the rare earth oxide mixture, CTR2O3, produced at FAENQUIL, as an alternative, low cost sinter additive for pure Y2O3 in the sintering of Si3N4 ceramics. The oxide mixture CTR2O3 is a solid solution formed mainly by Y2O3, Er2O3, Yb2O3 and Dy2O3 with other minor constituents and is obtained at a cost of only 20% of pure Y2O3. Samples were sintered by a gas pressure sintering process at 1900 °C under a nitrogen pressure of 1.5 MPa and an isothermal holding time of 2 h. The obtained materials were characterized by their relative density, phase composition and bending strength. The Weibull analysis was used to describe the reliability of these materials. Both materials produced presented relative densities higher than 99.5%t.d., b-Si3N4 and Y3Al5O12 (YAG) as cristalline phases and bending strengths higher than 650 MPa, thus demonstrating similar behaviors regarding their physical, chemical and mechanical characteristics. The statistical analysis of their strength also showed similar results for both materials, with Weibull moduli m of about 15 and characteristic stress values s o of about 700 MPa. These results confirmed the possibility of using the rare earth oxide mixture, CTR2O3, as sinter additive for high performance Si3N4 ceramics, without prejudice of the mechanical properties when compared to Si3N4 ceramics sintered with pure Y2O3. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392003000400006 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392003000400006 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S1516-14392003000400006 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.6 n.4 2003 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212657374691328 |