The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings

Detalhes bibliográficos
Autor(a) principal: Gandini,Alessandro
Data de Publicação: 2005
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Polímeros (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007
Resumo: The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium.
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spelling The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplingsDiels-Alder reactionfuran polymersmaleimidespolycondensationreversible cross-linkingThe furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium.Associação Brasileira de Polímeros2005-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007Polímeros v.15 n.2 2005reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/S0104-14282005000200007info:eu-repo/semantics/openAccessGandini,Alessandroeng2005-11-07T00:00:00Zoai:scielo:S0104-14282005000200007Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2005-11-07T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false
dc.title.none.fl_str_mv The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
title The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
spellingShingle The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
Gandini,Alessandro
Diels-Alder reaction
furan polymers
maleimides
polycondensation
reversible cross-linking
title_short The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
title_full The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
title_fullStr The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
title_full_unstemmed The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
title_sort The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
author Gandini,Alessandro
author_facet Gandini,Alessandro
author_role author
dc.contributor.author.fl_str_mv Gandini,Alessandro
dc.subject.por.fl_str_mv Diels-Alder reaction
furan polymers
maleimides
polycondensation
reversible cross-linking
topic Diels-Alder reaction
furan polymers
maleimides
polycondensation
reversible cross-linking
description The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium.
publishDate 2005
dc.date.none.fl_str_mv 2005-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0104-14282005000200007
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Polímeros
publisher.none.fl_str_mv Associação Brasileira de Polímeros
dc.source.none.fl_str_mv Polímeros v.15 n.2 2005
reponame:Polímeros (São Carlos. Online)
instname:Associação Brasileira de Polímeros (ABPol)
instacron:ABPO
instname_str Associação Brasileira de Polímeros (ABPol)
instacron_str ABPO
institution ABPO
reponame_str Polímeros (São Carlos. Online)
collection Polímeros (São Carlos. Online)
repository.name.fl_str_mv Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)
repository.mail.fl_str_mv ||revista@abpol.org.br
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