The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
Autor(a) principal: | |
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Data de Publicação: | 2005 |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Polímeros (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007 |
Resumo: | The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium. |
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The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplingsDiels-Alder reactionfuran polymersmaleimidespolycondensationreversible cross-linkingThe furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium.Associação Brasileira de Polímeros2005-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007Polímeros v.15 n.2 2005reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/S0104-14282005000200007info:eu-repo/semantics/openAccessGandini,Alessandroeng2005-11-07T00:00:00Zoai:scielo:S0104-14282005000200007Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2005-11-07T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false |
dc.title.none.fl_str_mv |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
title |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
spellingShingle |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings Gandini,Alessandro Diels-Alder reaction furan polymers maleimides polycondensation reversible cross-linking |
title_short |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
title_full |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
title_fullStr |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
title_full_unstemmed |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
title_sort |
The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings |
author |
Gandini,Alessandro |
author_facet |
Gandini,Alessandro |
author_role |
author |
dc.contributor.author.fl_str_mv |
Gandini,Alessandro |
dc.subject.por.fl_str_mv |
Diels-Alder reaction furan polymers maleimides polycondensation reversible cross-linking |
topic |
Diels-Alder reaction furan polymers maleimides polycondensation reversible cross-linking |
description |
The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium. |
publishDate |
2005 |
dc.date.none.fl_str_mv |
2005-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282005000200007 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0104-14282005000200007 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
dc.source.none.fl_str_mv |
Polímeros v.15 n.2 2005 reponame:Polímeros (São Carlos. Online) instname:Associação Brasileira de Polímeros (ABPol) instacron:ABPO |
instname_str |
Associação Brasileira de Polímeros (ABPol) |
instacron_str |
ABPO |
institution |
ABPO |
reponame_str |
Polímeros (São Carlos. Online) |
collection |
Polímeros (São Carlos. Online) |
repository.name.fl_str_mv |
Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol) |
repository.mail.fl_str_mv |
||revista@abpol.org.br |
_version_ |
1754212584347664384 |