Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds

Detalhes bibliográficos
Autor(a) principal: Vega,Rebeca
Data de Publicação: 1997
Outros Autores: Rieumont,Jacques
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Polímeros (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14281997000400005
Resumo: The inhibited radical polymerization of vinyl acetate initiated by 2,2-azobisisobutyronitrile was studied in the presence of some furan derivatives bearing a double bond on the side group. The modelling of such systems has permitted to estimate the values of the kinetic parameters for these inhibitors. A sensitivity analysis was performed to obtain a better insight into the mechanism; it appears that macroradical degradative transfer reaction to furan compounds is the most important reaction in comparison with propagation or primary radical degradative transfer.
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spelling Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compoundsModellingsensitivity analysisinhibited polymerizationfuran derivativesThe inhibited radical polymerization of vinyl acetate initiated by 2,2-azobisisobutyronitrile was studied in the presence of some furan derivatives bearing a double bond on the side group. The modelling of such systems has permitted to estimate the values of the kinetic parameters for these inhibitors. A sensitivity analysis was performed to obtain a better insight into the mechanism; it appears that macroradical degradative transfer reaction to furan compounds is the most important reaction in comparison with propagation or primary radical degradative transfer.Associação Brasileira de Polímeros1997-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14281997000400005Polímeros v.7 n.4 1997reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/S0104-14281997000400005info:eu-repo/semantics/openAccessVega,RebecaRieumont,Jacqueseng2010-10-08T00:00:00Zoai:scielo:S0104-14281997000400005Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2010-10-08T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false
dc.title.none.fl_str_mv Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
title Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
spellingShingle Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
Vega,Rebeca
Modelling
sensitivity analysis
inhibited polymerization
furan derivatives
title_short Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
title_full Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
title_fullStr Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
title_full_unstemmed Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
title_sort Kinetic and sensitivity approach to the mechanism of inhibited polymerization of vinyl acetate in the presence of furan compounds
author Vega,Rebeca
author_facet Vega,Rebeca
Rieumont,Jacques
author_role author
author2 Rieumont,Jacques
author2_role author
dc.contributor.author.fl_str_mv Vega,Rebeca
Rieumont,Jacques
dc.subject.por.fl_str_mv Modelling
sensitivity analysis
inhibited polymerization
furan derivatives
topic Modelling
sensitivity analysis
inhibited polymerization
furan derivatives
description The inhibited radical polymerization of vinyl acetate initiated by 2,2-azobisisobutyronitrile was studied in the presence of some furan derivatives bearing a double bond on the side group. The modelling of such systems has permitted to estimate the values of the kinetic parameters for these inhibitors. A sensitivity analysis was performed to obtain a better insight into the mechanism; it appears that macroradical degradative transfer reaction to furan compounds is the most important reaction in comparison with propagation or primary radical degradative transfer.
publishDate 1997
dc.date.none.fl_str_mv 1997-12-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14281997000400005
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14281997000400005
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0104-14281997000400005
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Polímeros
publisher.none.fl_str_mv Associação Brasileira de Polímeros
dc.source.none.fl_str_mv Polímeros v.7 n.4 1997
reponame:Polímeros (São Carlos. Online)
instname:Associação Brasileira de Polímeros (ABPol)
instacron:ABPO
instname_str Associação Brasileira de Polímeros (ABPol)
instacron_str ABPO
institution ABPO
reponame_str Polímeros (São Carlos. Online)
collection Polímeros (São Carlos. Online)
repository.name.fl_str_mv Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)
repository.mail.fl_str_mv ||revista@abpol.org.br
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