Effects of polypropylene methyl polyhedral oligomeric silsesquioxanes and polypropylene-grafted maleic anhydride compatibilizers on the properties of palm kernel shell reinforced polypropylene biocomposites

• Autor(a) principal: Mohaiyiddin,Muhammad Safwan
• Data de Publicação: 2016
• Outros Autores: Lin,Ong Hui, Akil,Hazizan Md, Yee,Toh Guat, Adik,Nik Nur Azza Nik, Villagracia,Al Rey
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Polímeros (São Carlos. Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282016000300228
• topic: biocomposites; palm kernel shell; polypropylene-methyl-polyhedral oligomeric silsesquioxane; mechanical properties; thermal behavior

Abstract The effects of the polypropylene-grafted maleic anhydride (PP-g-MAH) and polypropylene methyl polyhedral oligomeric silsesquioxane (PP-POSS) compatibilizers on the mechanical, thermal and physical properties of palm kernel shell (PKS) reinforced polypropylene (PP) were investigated. The production of PP/PKS biocomposites was performed by melt mixing using Brabender Internal Mixer. Mechanical test results showed that the biocomposites with PP-g-MAH have better tensile strength compared to biocomposites with or without PP-POSS. The results also showed an increase in the tensile strength and elongation at break when compatibilizers were added. Polypropylene-grafted maleic anhydride improved the Young’s modulus of the biocomposites, but PP-POSS reduced it. Moreoever, adding compatibilizers in biocomposites reduced the water absorption of the biocomposites. The compatibilizers improved the nucleating ability of filler in the composites. The PP-g-MAH compatibilizer provided better performance in improving nucleating ability to biocomposites compared to PP-POSS.