Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites

Detalhes bibliográficos
Autor(a) principal: Nunes,Janis Schutte
Data de Publicação: 2022
Outros Autores: Ito,Edson Noriyuki, Gabriel,Cléverson Fernandes Senra, Lopes,Thiago Castro, Nunes,Regina Célia Reis
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Polímeros (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282022000200406
Resumo: Abstract Nitrile rubber (NBR) nanocomposites with different contents of synthetic Somasif ME-100 mica (sodium-fluorohectorite) were obtained by melt compounding using a Semi Efficient curing system. The effect of curing on the nanocomposties was evaluated through rheometric properties, crosslink density (CLD) and mechanical properties. The ME-100 mica dispersion in NBR was assessed by transmission electron microscopy (TEM), the Payne effect and thermodynamic properties (ΔS and ΔG). Both the curing parameters and CLD pointd out that the addition of ME-100 directly affects crosslinks formation. It could also be observed that the nanofiller dispersion state is complex, exhibiting exfoliated and agglomerated structures (TEM); besides, agglomerations rose linearly as the nanofiller was added (the Payne effect). Notwithstanding these findings, and on the basis of unfilled formulations, NBR20 nanocomposite showed improvement in mechanical properties (tensile and tear strengths) which suggests that ME-100 might be considered a semi-reinforcing filler.
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spelling Physical-mechanical behavior of nitrile rubber-synthetic mica nanocompositescrosslink densityfluoromicamechanical propertiesnitrile rubbersynthetic micaAbstract Nitrile rubber (NBR) nanocomposites with different contents of synthetic Somasif ME-100 mica (sodium-fluorohectorite) were obtained by melt compounding using a Semi Efficient curing system. The effect of curing on the nanocomposties was evaluated through rheometric properties, crosslink density (CLD) and mechanical properties. The ME-100 mica dispersion in NBR was assessed by transmission electron microscopy (TEM), the Payne effect and thermodynamic properties (ΔS and ΔG). Both the curing parameters and CLD pointd out that the addition of ME-100 directly affects crosslinks formation. It could also be observed that the nanofiller dispersion state is complex, exhibiting exfoliated and agglomerated structures (TEM); besides, agglomerations rose linearly as the nanofiller was added (the Payne effect). Notwithstanding these findings, and on the basis of unfilled formulations, NBR20 nanocomposite showed improvement in mechanical properties (tensile and tear strengths) which suggests that ME-100 might be considered a semi-reinforcing filler.Associação Brasileira de Polímeros2022-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282022000200406Polímeros v.32 n.2 2022reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/0104-1428.20210102info:eu-repo/semantics/openAccessNunes,Janis SchutteIto,Edson NoriyukiGabriel,Cléverson Fernandes SenraLopes,Thiago CastroNunes,Regina Célia Reiseng2022-09-20T00:00:00Zoai:scielo:S0104-14282022000200406Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2022-09-20T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false
dc.title.none.fl_str_mv Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
title Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
spellingShingle Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
Nunes,Janis Schutte
crosslink density
fluoromica
mechanical properties
nitrile rubber
synthetic mica
title_short Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
title_full Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
title_fullStr Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
title_full_unstemmed Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
title_sort Physical-mechanical behavior of nitrile rubber-synthetic mica nanocomposites
author Nunes,Janis Schutte
author_facet Nunes,Janis Schutte
Ito,Edson Noriyuki
Gabriel,Cléverson Fernandes Senra
Lopes,Thiago Castro
Nunes,Regina Célia Reis
author_role author
author2 Ito,Edson Noriyuki
Gabriel,Cléverson Fernandes Senra
Lopes,Thiago Castro
Nunes,Regina Célia Reis
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Nunes,Janis Schutte
Ito,Edson Noriyuki
Gabriel,Cléverson Fernandes Senra
Lopes,Thiago Castro
Nunes,Regina Célia Reis
dc.subject.por.fl_str_mv crosslink density
fluoromica
mechanical properties
nitrile rubber
synthetic mica
topic crosslink density
fluoromica
mechanical properties
nitrile rubber
synthetic mica
description Abstract Nitrile rubber (NBR) nanocomposites with different contents of synthetic Somasif ME-100 mica (sodium-fluorohectorite) were obtained by melt compounding using a Semi Efficient curing system. The effect of curing on the nanocomposties was evaluated through rheometric properties, crosslink density (CLD) and mechanical properties. The ME-100 mica dispersion in NBR was assessed by transmission electron microscopy (TEM), the Payne effect and thermodynamic properties (ΔS and ΔG). Both the curing parameters and CLD pointd out that the addition of ME-100 directly affects crosslinks formation. It could also be observed that the nanofiller dispersion state is complex, exhibiting exfoliated and agglomerated structures (TEM); besides, agglomerations rose linearly as the nanofiller was added (the Payne effect). Notwithstanding these findings, and on the basis of unfilled formulations, NBR20 nanocomposite showed improvement in mechanical properties (tensile and tear strengths) which suggests that ME-100 might be considered a semi-reinforcing filler.
publishDate 2022
dc.date.none.fl_str_mv 2022-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282022000200406
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282022000200406
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-1428.20210102
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Polímeros
publisher.none.fl_str_mv Associação Brasileira de Polímeros
dc.source.none.fl_str_mv Polímeros v.32 n.2 2022
reponame:Polímeros (São Carlos. Online)
instname:Associação Brasileira de Polímeros (ABPol)
instacron:ABPO
instname_str Associação Brasileira de Polímeros (ABPol)
instacron_str ABPO
institution ABPO
reponame_str Polímeros (São Carlos. Online)
collection Polímeros (São Carlos. Online)
repository.name.fl_str_mv Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)
repository.mail.fl_str_mv ||revista@abpol.org.br
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