Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of Aerospace Technology and Management (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462009000100035 |
Resumo: | Abstract: Synthesis and characterization of energetic ABA-type thermoplastic elastomers for propellant formulations has been carried out. Following the working plan elaborated, the synthesis and characterization of Poly 3-bromomethyl-3-methyl oxetane (PolyBrMMO), Poly 3- azidomethyl-3-methyl oxetane (PolyAMMO), Poly 3,3-bis-azidomethyl oxetane (PolyBAMO) and Copolymer PolyBAMO/AMMO (by TDI end capping) has been successfully performed. The thermoplastic elastomers (TPEs) were synthesized using the chain elongation process PolyAMMO, GAP and PolyBAMO by diisocyanates. In this method 2.4-toluene diisocyanate (TDI) is used to link block A (hardandmono-functional)) to B (soft and di-functional). For the hard A-block we used PolyBAMO and for the soft B-block we used PolyAMMO or GAP. This is ajoint project set up, someyears ago, between the Chemistry Division of the Institute of Aeronautics and Space (IAE) - subordinated to the Brazilian Ministry of Defense - and the Fraunhofer Institut Chemische Technologie (ICT), in Germany. The products were characterized by different techniques as IR- and (1H, 13C) NMR spectroscopies, elemental and thermal analyses. New methodologies based on FT-IR analysis have been developed as an alternative for the determination of the molecular weight and CHNO content of the energetic polymers. |
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Synthesis and characterization of energetic thermoplastic elastomers for propellant formulationsEnergetic thermoplastic elastomersPolyAMMOPolyBAMOCopolymer PolyBAMO/AMMOPropellantsAbstract: Synthesis and characterization of energetic ABA-type thermoplastic elastomers for propellant formulations has been carried out. Following the working plan elaborated, the synthesis and characterization of Poly 3-bromomethyl-3-methyl oxetane (PolyBrMMO), Poly 3- azidomethyl-3-methyl oxetane (PolyAMMO), Poly 3,3-bis-azidomethyl oxetane (PolyBAMO) and Copolymer PolyBAMO/AMMO (by TDI end capping) has been successfully performed. The thermoplastic elastomers (TPEs) were synthesized using the chain elongation process PolyAMMO, GAP and PolyBAMO by diisocyanates. In this method 2.4-toluene diisocyanate (TDI) is used to link block A (hardandmono-functional)) to B (soft and di-functional). For the hard A-block we used PolyBAMO and for the soft B-block we used PolyAMMO or GAP. This is ajoint project set up, someyears ago, between the Chemistry Division of the Institute of Aeronautics and Space (IAE) - subordinated to the Brazilian Ministry of Defense - and the Fraunhofer Institut Chemische Technologie (ICT), in Germany. The products were characterized by different techniques as IR- and (1H, 13C) NMR spectroscopies, elemental and thermal analyses. New methodologies based on FT-IR analysis have been developed as an alternative for the determination of the molecular weight and CHNO content of the energetic polymers.Departamento de Ciência e Tecnologia Aeroespacial2009-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462009000100035Journal of Aerospace Technology and Management v.1 n.1 2009reponame:Journal of Aerospace Technology and Management (Online)instname:Departamento de Ciência e Tecnologia Aeroespacial (DCTA)instacron:DCTA10.5028/jatm.2009.01013542info:eu-repo/semantics/openAccessKawamoto,Aparecida M.Oliveira,José Irineu S.Dutra,Rita de Cássia L.Rezende,Luis CláudioKeicher,ThomasKrause,Horsteng2017-05-29T00:00:00Zoai:scielo:S2175-91462009000100035Revistahttp://www.jatm.com.br/ONGhttps://old.scielo.br/oai/scielo-oai.php||secretary@jatm.com.br2175-91461984-9648opendoar:2017-05-29T00:00Journal of Aerospace Technology and Management (Online) - Departamento de Ciência e Tecnologia Aeroespacial (DCTA)false |
dc.title.none.fl_str_mv |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations |
title |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations |
spellingShingle |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations Kawamoto,Aparecida M. Energetic thermoplastic elastomers PolyAMMO PolyBAMO Copolymer PolyBAMO/AMMO Propellants |
title_short |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations |
title_full |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations |
title_fullStr |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations |
title_full_unstemmed |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations |
title_sort |
Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations |
author |
Kawamoto,Aparecida M. |
author_facet |
Kawamoto,Aparecida M. Oliveira,José Irineu S. Dutra,Rita de Cássia L. Rezende,Luis Cláudio Keicher,Thomas Krause,Horst |
author_role |
author |
author2 |
Oliveira,José Irineu S. Dutra,Rita de Cássia L. Rezende,Luis Cláudio Keicher,Thomas Krause,Horst |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Kawamoto,Aparecida M. Oliveira,José Irineu S. Dutra,Rita de Cássia L. Rezende,Luis Cláudio Keicher,Thomas Krause,Horst |
dc.subject.por.fl_str_mv |
Energetic thermoplastic elastomers PolyAMMO PolyBAMO Copolymer PolyBAMO/AMMO Propellants |
topic |
Energetic thermoplastic elastomers PolyAMMO PolyBAMO Copolymer PolyBAMO/AMMO Propellants |
description |
Abstract: Synthesis and characterization of energetic ABA-type thermoplastic elastomers for propellant formulations has been carried out. Following the working plan elaborated, the synthesis and characterization of Poly 3-bromomethyl-3-methyl oxetane (PolyBrMMO), Poly 3- azidomethyl-3-methyl oxetane (PolyAMMO), Poly 3,3-bis-azidomethyl oxetane (PolyBAMO) and Copolymer PolyBAMO/AMMO (by TDI end capping) has been successfully performed. The thermoplastic elastomers (TPEs) were synthesized using the chain elongation process PolyAMMO, GAP and PolyBAMO by diisocyanates. In this method 2.4-toluene diisocyanate (TDI) is used to link block A (hardandmono-functional)) to B (soft and di-functional). For the hard A-block we used PolyBAMO and for the soft B-block we used PolyAMMO or GAP. This is ajoint project set up, someyears ago, between the Chemistry Division of the Institute of Aeronautics and Space (IAE) - subordinated to the Brazilian Ministry of Defense - and the Fraunhofer Institut Chemische Technologie (ICT), in Germany. The products were characterized by different techniques as IR- and (1H, 13C) NMR spectroscopies, elemental and thermal analyses. New methodologies based on FT-IR analysis have been developed as an alternative for the determination of the molecular weight and CHNO content of the energetic polymers. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462009000100035 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462009000100035 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5028/jatm.2009.01013542 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Departamento de Ciência e Tecnologia Aeroespacial |
publisher.none.fl_str_mv |
Departamento de Ciência e Tecnologia Aeroespacial |
dc.source.none.fl_str_mv |
Journal of Aerospace Technology and Management v.1 n.1 2009 reponame:Journal of Aerospace Technology and Management (Online) instname:Departamento de Ciência e Tecnologia Aeroespacial (DCTA) instacron:DCTA |
instname_str |
Departamento de Ciência e Tecnologia Aeroespacial (DCTA) |
instacron_str |
DCTA |
institution |
DCTA |
reponame_str |
Journal of Aerospace Technology and Management (Online) |
collection |
Journal of Aerospace Technology and Management (Online) |
repository.name.fl_str_mv |
Journal of Aerospace Technology and Management (Online) - Departamento de Ciência e Tecnologia Aeroespacial (DCTA) |
repository.mail.fl_str_mv |
||secretary@jatm.com.br |
_version_ |
1754732530346491904 |