Methodology for DSC calibration in high heating rates
Autor(a) principal: | |
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Data de Publicação: | 2011 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of Aerospace Technology and Management (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462011000200179 |
Resumo: | Abstract Despite the large use of differential scanning calorimetry (DSC) technique in advanced polymer materials characterization, the new methodology called DSC in high heating rates was developed. The heating rate during conventional DSC experiments varying from 10 to 20ºC.min-1, sample mass from 10 to 15mg and standard aluminum sample pan weighting, approximately, 27mg. In order to contribute to a better comprehension of DSC behavior in different heating rates, this work correlates as high heating rate influences to the thermal events in DSC experiments. Samples of metallic standard (In, Pb, Sn and Zn) with masses varying from 0.570mg to 20.9mg were analyzed in multiples sample heating rate from 4 to 324ºC. min-1. In order to make properly all those experiments, a precise and careful temperature and enthalpy calibrations were performed and deeply discussed. Thus, this work shows a DSC methodology able to generate good and reliable results on experiments under any researcher choice heating rates to characterize the advanced materials used, for example, for aerospace industry. Also it helps the DSC users to find in their available instruments, already installed, a better and more accurate DSC test results, improving in just one shot the analysis sensitivity and resolution. Polypropylene melting and enthalpy thermal events are also studied using both the conventional DSC method and high heating rate method. |
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Methodology for DSC calibration in high heating ratesDSCHigh heating rateCalibrationThermal analysisPolymersAbstract Despite the large use of differential scanning calorimetry (DSC) technique in advanced polymer materials characterization, the new methodology called DSC in high heating rates was developed. The heating rate during conventional DSC experiments varying from 10 to 20ºC.min-1, sample mass from 10 to 15mg and standard aluminum sample pan weighting, approximately, 27mg. In order to contribute to a better comprehension of DSC behavior in different heating rates, this work correlates as high heating rate influences to the thermal events in DSC experiments. Samples of metallic standard (In, Pb, Sn and Zn) with masses varying from 0.570mg to 20.9mg were analyzed in multiples sample heating rate from 4 to 324ºC. min-1. In order to make properly all those experiments, a precise and careful temperature and enthalpy calibrations were performed and deeply discussed. Thus, this work shows a DSC methodology able to generate good and reliable results on experiments under any researcher choice heating rates to characterize the advanced materials used, for example, for aerospace industry. Also it helps the DSC users to find in their available instruments, already installed, a better and more accurate DSC test results, improving in just one shot the analysis sensitivity and resolution. Polypropylene melting and enthalpy thermal events are also studied using both the conventional DSC method and high heating rate method.Departamento de Ciência e Tecnologia Aeroespacial2011-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462011000200179Journal of Aerospace Technology and Management v.3 n.2 2011reponame:Journal of Aerospace Technology and Management (Online)instname:Departamento de Ciência e Tecnologia Aeroespacial (DCTA)instacron:DCTA10.5028/jatm.2011.03021911info:eu-repo/semantics/openAccessBraga,Carlos IsidoroRezende,Mirabel CerqueiraCosta,Michelle Lealieng2017-05-24T00:00:00Zoai:scielo:S2175-91462011000200179Revistahttp://www.jatm.com.br/ONGhttps://old.scielo.br/oai/scielo-oai.php||secretary@jatm.com.br2175-91461984-9648opendoar:2017-05-24T00:00Journal of Aerospace Technology and Management (Online) - Departamento de Ciência e Tecnologia Aeroespacial (DCTA)false |
dc.title.none.fl_str_mv |
Methodology for DSC calibration in high heating rates |
title |
Methodology for DSC calibration in high heating rates |
spellingShingle |
Methodology for DSC calibration in high heating rates Braga,Carlos Isidoro DSC High heating rate Calibration Thermal analysis Polymers |
title_short |
Methodology for DSC calibration in high heating rates |
title_full |
Methodology for DSC calibration in high heating rates |
title_fullStr |
Methodology for DSC calibration in high heating rates |
title_full_unstemmed |
Methodology for DSC calibration in high heating rates |
title_sort |
Methodology for DSC calibration in high heating rates |
author |
Braga,Carlos Isidoro |
author_facet |
Braga,Carlos Isidoro Rezende,Mirabel Cerqueira Costa,Michelle Leali |
author_role |
author |
author2 |
Rezende,Mirabel Cerqueira Costa,Michelle Leali |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Braga,Carlos Isidoro Rezende,Mirabel Cerqueira Costa,Michelle Leali |
dc.subject.por.fl_str_mv |
DSC High heating rate Calibration Thermal analysis Polymers |
topic |
DSC High heating rate Calibration Thermal analysis Polymers |
description |
Abstract Despite the large use of differential scanning calorimetry (DSC) technique in advanced polymer materials characterization, the new methodology called DSC in high heating rates was developed. The heating rate during conventional DSC experiments varying from 10 to 20ºC.min-1, sample mass from 10 to 15mg and standard aluminum sample pan weighting, approximately, 27mg. In order to contribute to a better comprehension of DSC behavior in different heating rates, this work correlates as high heating rate influences to the thermal events in DSC experiments. Samples of metallic standard (In, Pb, Sn and Zn) with masses varying from 0.570mg to 20.9mg were analyzed in multiples sample heating rate from 4 to 324ºC. min-1. In order to make properly all those experiments, a precise and careful temperature and enthalpy calibrations were performed and deeply discussed. Thus, this work shows a DSC methodology able to generate good and reliable results on experiments under any researcher choice heating rates to characterize the advanced materials used, for example, for aerospace industry. Also it helps the DSC users to find in their available instruments, already installed, a better and more accurate DSC test results, improving in just one shot the analysis sensitivity and resolution. Polypropylene melting and enthalpy thermal events are also studied using both the conventional DSC method and high heating rate method. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-08-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462011000200179 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S2175-91462011000200179 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5028/jatm.2011.03021911 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Departamento de Ciência e Tecnologia Aeroespacial |
publisher.none.fl_str_mv |
Departamento de Ciência e Tecnologia Aeroespacial |
dc.source.none.fl_str_mv |
Journal of Aerospace Technology and Management v.3 n.2 2011 reponame:Journal of Aerospace Technology and Management (Online) instname:Departamento de Ciência e Tecnologia Aeroespacial (DCTA) instacron:DCTA |
instname_str |
Departamento de Ciência e Tecnologia Aeroespacial (DCTA) |
instacron_str |
DCTA |
institution |
DCTA |
reponame_str |
Journal of Aerospace Technology and Management (Online) |
collection |
Journal of Aerospace Technology and Management (Online) |
repository.name.fl_str_mv |
Journal of Aerospace Technology and Management (Online) - Departamento de Ciência e Tecnologia Aeroespacial (DCTA) |
repository.mail.fl_str_mv |
||secretary@jatm.com.br |
_version_ |
1754732530464980992 |