Characterization of phosphate structures in biochar from swine bones
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng por |
Título da fonte: | Pesquisa Agropecuária Brasileira (Online) |
Texto Completo: | https://seer.sct.embrapa.br/index.php/pab/article/view/10029 |
Resumo: | The objective of this work was to develop an alternative methodology to study and characterize the phosphate crystalline properties, directly associated with solubility and plant availability, in biochar from swine bones. Some phosphate symmetry properties of pyrolyzed swine bones were established, using solid state nuclear magnetic resonance spectroscopy, principal component analysis, and multivariate curve resolution analysis, on four pyrolyzed samples at different carbonization intensities. Increasing carbonization parameters (temperature or residence time) generates diverse phosphate structures, increasing their symmetry and decreasing the crossed polarizability of the pair 1H‑31P, producing phosphates with, probably, lower solubility than the ones produced at lower carbonization intensity. Additionally, a new methodology is being developed to study and characterize phosphate crystalline properties directly associated with phosphate solubility and availability to plants. |
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Characterization of phosphate structures in biochar from swine bonesCharacterization of phosphate structures in biochar from swine bonesbone phosphate; phosphate availability; principal component analysis; pyrolysis; multivariedade curve resolution analysis; soil fertilityfosfato de ossos; disponibilidade de fósforo; análise de componentes principais; pirólise; análise de resolução de curvas multivariadas; fertilidade do soloThe objective of this work was to develop an alternative methodology to study and characterize the phosphate crystalline properties, directly associated with solubility and plant availability, in biochar from swine bones. Some phosphate symmetry properties of pyrolyzed swine bones were established, using solid state nuclear magnetic resonance spectroscopy, principal component analysis, and multivariate curve resolution analysis, on four pyrolyzed samples at different carbonization intensities. Increasing carbonization parameters (temperature or residence time) generates diverse phosphate structures, increasing their symmetry and decreasing the crossed polarizability of the pair 1H‑31P, producing phosphates with, probably, lower solubility than the ones produced at lower carbonization intensity. Additionally, a new methodology is being developed to study and characterize phosphate crystalline properties directly associated with phosphate solubility and availability to plants.The objective of this work was to develop an alternative methodology to study and characterize the phosphate crystalline properties, directly associated with solubility and plant availability, in biochar from swine bones. Some phosphate symmetry properties of pyrolyzed swine bones were established, using solid state nuclear magnetic resonance spectroscopy, principal component analysis, and multivariate curve resolution analysis, on four pyrolyzed samples at different carbonization intensities. Increasing carbonization parameters (temperature or residence time) generates diverse phosphate structures, increasing their symmetry and decreasing the crossed polarizability of the pair 1H‑31P, producing phosphates with, probably, lower solubility than the ones produced at lower carbonization intensity. Additionally, a new methodology is being developed to study and characterize phosphate crystalline properties directly associated with phosphate solubility and availability to plants.Pesquisa Agropecuaria BrasileiraPesquisa Agropecuária BrasileiraFAPERJ, CNPq, CAPESNovotny, Etelvino HenriqueAuccaise, RubenVelloso, Marcia Helena RodriguesCorrêa, Juliano CorulliHigarashi, Martha MayumiAbreu, Valéria Maria NascimentoRocha, José DilcioKwapinski, Witold2012-06-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://seer.sct.embrapa.br/index.php/pab/article/view/10029Pesquisa Agropecuaria Brasileira; v.47, n.5, maio 2012: 3rd International Biochar Conference; 672-676Pesquisa Agropecuária Brasileira; v.47, n.5, maio 2012: 3rd International Biochar Conference; 672-6761678-39210100-104xreponame:Pesquisa Agropecuária Brasileira (Online)instname:Empresa Brasileira de Pesquisa Agropecuária (Embrapa)instacron:EMBRAPAengporhttps://seer.sct.embrapa.br/index.php/pab/article/view/10029/6914https://seer.sct.embrapa.br/index.php/pab/article/view/10029/7433https://seer.sct.embrapa.br/index.php/pab/article/downloadSuppFile/10029/5351info:eu-repo/semantics/openAccess2012-08-02T13:50:44Zoai:ojs.seer.sct.embrapa.br:article/10029Revistahttp://seer.sct.embrapa.br/index.php/pabPRIhttps://old.scielo.br/oai/scielo-oai.phppab@sct.embrapa.br || sct.pab@embrapa.br1678-39210100-204Xopendoar:2012-08-02T13:50:44Pesquisa Agropecuária Brasileira (Online) - Empresa Brasileira de Pesquisa Agropecuária (Embrapa)false |
dc.title.none.fl_str_mv |
Characterization of phosphate structures in biochar from swine bones Characterization of phosphate structures in biochar from swine bones |
title |
Characterization of phosphate structures in biochar from swine bones |
spellingShingle |
Characterization of phosphate structures in biochar from swine bones Novotny, Etelvino Henrique bone phosphate; phosphate availability; principal component analysis; pyrolysis; multivariedade curve resolution analysis; soil fertility fosfato de ossos; disponibilidade de fósforo; análise de componentes principais; pirólise; análise de resolução de curvas multivariadas; fertilidade do solo |
title_short |
Characterization of phosphate structures in biochar from swine bones |
title_full |
Characterization of phosphate structures in biochar from swine bones |
title_fullStr |
Characterization of phosphate structures in biochar from swine bones |
title_full_unstemmed |
Characterization of phosphate structures in biochar from swine bones |
title_sort |
Characterization of phosphate structures in biochar from swine bones |
author |
Novotny, Etelvino Henrique |
author_facet |
Novotny, Etelvino Henrique Auccaise, Ruben Velloso, Marcia Helena Rodrigues Corrêa, Juliano Corulli Higarashi, Martha Mayumi Abreu, Valéria Maria Nascimento Rocha, José Dilcio Kwapinski, Witold |
author_role |
author |
author2 |
Auccaise, Ruben Velloso, Marcia Helena Rodrigues Corrêa, Juliano Corulli Higarashi, Martha Mayumi Abreu, Valéria Maria Nascimento Rocha, José Dilcio Kwapinski, Witold |
author2_role |
author author author author author author author |
dc.contributor.none.fl_str_mv |
FAPERJ, CNPq, CAPES |
dc.contributor.author.fl_str_mv |
Novotny, Etelvino Henrique Auccaise, Ruben Velloso, Marcia Helena Rodrigues Corrêa, Juliano Corulli Higarashi, Martha Mayumi Abreu, Valéria Maria Nascimento Rocha, José Dilcio Kwapinski, Witold |
dc.subject.por.fl_str_mv |
bone phosphate; phosphate availability; principal component analysis; pyrolysis; multivariedade curve resolution analysis; soil fertility fosfato de ossos; disponibilidade de fósforo; análise de componentes principais; pirólise; análise de resolução de curvas multivariadas; fertilidade do solo |
topic |
bone phosphate; phosphate availability; principal component analysis; pyrolysis; multivariedade curve resolution analysis; soil fertility fosfato de ossos; disponibilidade de fósforo; análise de componentes principais; pirólise; análise de resolução de curvas multivariadas; fertilidade do solo |
description |
The objective of this work was to develop an alternative methodology to study and characterize the phosphate crystalline properties, directly associated with solubility and plant availability, in biochar from swine bones. Some phosphate symmetry properties of pyrolyzed swine bones were established, using solid state nuclear magnetic resonance spectroscopy, principal component analysis, and multivariate curve resolution analysis, on four pyrolyzed samples at different carbonization intensities. Increasing carbonization parameters (temperature or residence time) generates diverse phosphate structures, increasing their symmetry and decreasing the crossed polarizability of the pair 1H‑31P, producing phosphates with, probably, lower solubility than the ones produced at lower carbonization intensity. Additionally, a new methodology is being developed to study and characterize phosphate crystalline properties directly associated with phosphate solubility and availability to plants. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-06-15 |
dc.type.none.fl_str_mv |
|
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://seer.sct.embrapa.br/index.php/pab/article/view/10029 |
url |
https://seer.sct.embrapa.br/index.php/pab/article/view/10029 |
dc.language.iso.fl_str_mv |
eng por |
language |
eng por |
dc.relation.none.fl_str_mv |
https://seer.sct.embrapa.br/index.php/pab/article/view/10029/6914 https://seer.sct.embrapa.br/index.php/pab/article/view/10029/7433 https://seer.sct.embrapa.br/index.php/pab/article/downloadSuppFile/10029/5351 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Pesquisa Agropecuaria Brasileira Pesquisa Agropecuária Brasileira |
publisher.none.fl_str_mv |
Pesquisa Agropecuaria Brasileira Pesquisa Agropecuária Brasileira |
dc.source.none.fl_str_mv |
Pesquisa Agropecuaria Brasileira; v.47, n.5, maio 2012: 3rd International Biochar Conference; 672-676 Pesquisa Agropecuária Brasileira; v.47, n.5, maio 2012: 3rd International Biochar Conference; 672-676 1678-3921 0100-104x reponame:Pesquisa Agropecuária Brasileira (Online) instname:Empresa Brasileira de Pesquisa Agropecuária (Embrapa) instacron:EMBRAPA |
instname_str |
Empresa Brasileira de Pesquisa Agropecuária (Embrapa) |
instacron_str |
EMBRAPA |
institution |
EMBRAPA |
reponame_str |
Pesquisa Agropecuária Brasileira (Online) |
collection |
Pesquisa Agropecuária Brasileira (Online) |
repository.name.fl_str_mv |
Pesquisa Agropecuária Brasileira (Online) - Empresa Brasileira de Pesquisa Agropecuária (Embrapa) |
repository.mail.fl_str_mv |
pab@sct.embrapa.br || sct.pab@embrapa.br |
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1793416703209635840 |