Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.

Detalhes bibliográficos
Autor(a) principal: GUIOTOKU, M.
Data de Publicação: 2012
Outros Autores: HANSEL, F. A., NOVOTNY, E. H., MAIA, C. M. B. de F.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
Texto Completo: http://www.alice.cnptia.embrapa.br/alice/handle/doc/931117
Resumo: The objective of this work was to characterize the morphology and molecular composition of the hydrochar produced by microwave‑assisted hydrothermal carbonization of cellulose. The produced hydrochar consists mainly of aggregate microspheres with about 2.0 μm in diameter, with aliphatic and aromatic structures and the presence of carbonyl functional groups. The aromatic groups are formed mainly by benzofuran‑like structures, being chemically different from common cellulose char. Microwave‑assisted hydrothermal carbonization yields a functionalized carbon‑rich material similar to that produced by the conventional hydrothermal process.
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spelling Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.Anthropogenic dark earth of AmazoniaNuclear magnetic resonancebiocharcharcoalgas chromatographymass spectrometryThe objective of this work was to characterize the morphology and molecular composition of the hydrochar produced by microwave‑assisted hydrothermal carbonization of cellulose. The produced hydrochar consists mainly of aggregate microspheres with about 2.0 μm in diameter, with aliphatic and aromatic structures and the presence of carbonyl functional groups. The aromatic groups are formed mainly by benzofuran‑like structures, being chemically different from common cellulose char. Microwave‑assisted hydrothermal carbonization yields a functionalized carbon‑rich material similar to that produced by the conventional hydrothermal process.MARCELA GUIOTOKU, CNPF; FABRICIO AUGUSTO HANSEL, CNPF; ETELVINO HENRIQUE NOVOTNY, CNPS; CLAUDIA MARIA BRANCO DE F MAIA, CNPF.GUIOTOKU, M.HANSEL, F. A.NOVOTNY, E. H.MAIA, C. M. B. de F.2012-08-13T11:11:11Z2012-08-13T11:11:11Z2012-08-1320122012-08-13T11:11:11Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlePesquisa Agropecuária Brasileira, Brasília, DF, v. 47, n. 5, p. 687-692, maio 2012.http://www.alice.cnptia.embrapa.br/alice/handle/doc/931117enginfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)instname:Empresa Brasileira de Pesquisa Agropecuária (Embrapa)instacron:EMBRAPA2017-08-15T23:04:49Zoai:www.alice.cnptia.embrapa.br:doc/931117Repositório InstitucionalPUBhttps://www.alice.cnptia.embrapa.br/oai/requestopendoar:21542017-08-15T23:04:49falseRepositório InstitucionalPUBhttps://www.alice.cnptia.embrapa.br/oai/requestcg-riaa@embrapa.bropendoar:21542017-08-15T23:04:49Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice) - Empresa Brasileira de Pesquisa Agropecuária (Embrapa)false
dc.title.none.fl_str_mv Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
title Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
spellingShingle Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
GUIOTOKU, M.
Anthropogenic dark earth of Amazonia
Nuclear magnetic resonance
biochar
charcoal
gas chromatography
mass spectrometry
title_short Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
title_full Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
title_fullStr Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
title_full_unstemmed Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
title_sort Molecular and morphological characterization of hydrochar produced by microwave-assisted hydrothermal carbonization of cellulose.
author GUIOTOKU, M.
author_facet GUIOTOKU, M.
HANSEL, F. A.
NOVOTNY, E. H.
MAIA, C. M. B. de F.
author_role author
author2 HANSEL, F. A.
NOVOTNY, E. H.
MAIA, C. M. B. de F.
author2_role author
author
author
dc.contributor.none.fl_str_mv MARCELA GUIOTOKU, CNPF; FABRICIO AUGUSTO HANSEL, CNPF; ETELVINO HENRIQUE NOVOTNY, CNPS; CLAUDIA MARIA BRANCO DE F MAIA, CNPF.
dc.contributor.author.fl_str_mv GUIOTOKU, M.
HANSEL, F. A.
NOVOTNY, E. H.
MAIA, C. M. B. de F.
dc.subject.por.fl_str_mv Anthropogenic dark earth of Amazonia
Nuclear magnetic resonance
biochar
charcoal
gas chromatography
mass spectrometry
topic Anthropogenic dark earth of Amazonia
Nuclear magnetic resonance
biochar
charcoal
gas chromatography
mass spectrometry
description The objective of this work was to characterize the morphology and molecular composition of the hydrochar produced by microwave‑assisted hydrothermal carbonization of cellulose. The produced hydrochar consists mainly of aggregate microspheres with about 2.0 μm in diameter, with aliphatic and aromatic structures and the presence of carbonyl functional groups. The aromatic groups are formed mainly by benzofuran‑like structures, being chemically different from common cellulose char. Microwave‑assisted hydrothermal carbonization yields a functionalized carbon‑rich material similar to that produced by the conventional hydrothermal process.
publishDate 2012
dc.date.none.fl_str_mv 2012-08-13T11:11:11Z
2012-08-13T11:11:11Z
2012-08-13
2012
2012-08-13T11:11:11Z
dc.type.driver.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv Pesquisa Agropecuária Brasileira, Brasília, DF, v. 47, n. 5, p. 687-692, maio 2012.
http://www.alice.cnptia.embrapa.br/alice/handle/doc/931117
identifier_str_mv Pesquisa Agropecuária Brasileira, Brasília, DF, v. 47, n. 5, p. 687-692, maio 2012.
url http://www.alice.cnptia.embrapa.br/alice/handle/doc/931117
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
instname:Empresa Brasileira de Pesquisa Agropecuária (Embrapa)
instacron:EMBRAPA
instname_str Empresa Brasileira de Pesquisa Agropecuária (Embrapa)
instacron_str EMBRAPA
institution EMBRAPA
reponame_str Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
collection Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice)
repository.name.fl_str_mv Repositório Institucional da EMBRAPA (Repository Open Access to Scientific Information from EMBRAPA - Alice) - Empresa Brasileira de Pesquisa Agropecuária (Embrapa)
repository.mail.fl_str_mv cg-riaa@embrapa.br
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