Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 1991 |
| Outros Autores: | |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Memórias do Instituto Oswaldo Cruz |
| Texto Completo: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0074-02761991000600027 |
Resumo: | An efficient (12 steps, 12% overallyield) and stereoselective total synthesis of (±)-serricornine (1) the sex pheromone of the cigarette beetle (Lasioderma serricornine F) is described. The preparation of intermediate 5, which encompasses the proper relative configuration of three contiguous chiral centers of (±)-invictolide, (3), is discussed. |
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Memórias do Instituto Oswaldo Cruz |
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Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolidetotal synthesis(±)-serricornine(±)-invictolidepheromonesAn efficient (12 steps, 12% overallyield) and stereoselective total synthesis of (±)-serricornine (1) the sex pheromone of the cigarette beetle (Lasioderma serricornine F) is described. The preparation of intermediate 5, which encompasses the proper relative configuration of three contiguous chiral centers of (±)-invictolide, (3), is discussed.Instituto Oswaldo Cruz, Ministério da Saúde1991-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://www.scielo.br/scielo.php?script=sci_arttext&pid=S0074-02761991000600027Memórias do Instituto Oswaldo Cruz v.86 suppl.2 1991reponame:Memórias do Instituto Oswaldo Cruzinstname:Fundação Oswaldo Cruzinstacron:FIOCRUZ10.1590/S0074-02761991000600027info:eu-repo/semantics/openAccessPilli,R. A.Murta,M. M.eng2020-04-25T17:46:38Zhttp://www.scielo.br/oai/scielo-oai.php0074-02761678-8060opendoar:null2020-04-26 02:04:17.765Memórias do Instituto Oswaldo Cruz - Fundação Oswaldo Cruztrue |
| dc.title.none.fl_str_mv |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide |
| title |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide |
| spellingShingle |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide Pilli,R. A. total synthesis (±)-serricornine (±)-invictolide pheromones |
| title_short |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide |
| title_full |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide |
| title_fullStr |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide |
| title_full_unstemmed |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide |
| title_sort |
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide |
| author |
Pilli,R. A. |
| author_facet |
Pilli,R. A. Murta,M. M. |
| author_role |
author |
| author2 |
Murta,M. M. |
| author2_role |
author |
| dc.contributor.author.fl_str_mv |
Pilli,R. A. Murta,M. M. |
| dc.subject.por.fl_str_mv |
total synthesis (±)-serricornine (±)-invictolide pheromones |
| topic |
total synthesis (±)-serricornine (±)-invictolide pheromones |
| dc.description.none.fl_txt_mv |
An efficient (12 steps, 12% overallyield) and stereoselective total synthesis of (±)-serricornine (1) the sex pheromone of the cigarette beetle (Lasioderma serricornine F) is described. The preparation of intermediate 5, which encompasses the proper relative configuration of three contiguous chiral centers of (±)-invictolide, (3), is discussed. |
| description |
An efficient (12 steps, 12% overallyield) and stereoselective total synthesis of (±)-serricornine (1) the sex pheromone of the cigarette beetle (Lasioderma serricornine F) is described. The preparation of intermediate 5, which encompasses the proper relative configuration of three contiguous chiral centers of (±)-invictolide, (3), is discussed. |
| publishDate |
1991 |
| dc.date.none.fl_str_mv |
1991-01-01 |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0074-02761991000600027 |
| url |
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0074-02761991000600027 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
10.1590/S0074-02761991000600027 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
text/html |
| dc.publisher.none.fl_str_mv |
Instituto Oswaldo Cruz, Ministério da Saúde |
| publisher.none.fl_str_mv |
Instituto Oswaldo Cruz, Ministério da Saúde |
| dc.source.none.fl_str_mv |
Memórias do Instituto Oswaldo Cruz v.86 suppl.2 1991 reponame:Memórias do Instituto Oswaldo Cruz instname:Fundação Oswaldo Cruz instacron:FIOCRUZ |
| reponame_str |
Memórias do Instituto Oswaldo Cruz |
| collection |
Memórias do Instituto Oswaldo Cruz |
| instname_str |
Fundação Oswaldo Cruz |
| instacron_str |
FIOCRUZ |
| institution |
FIOCRUZ |
| repository.name.fl_str_mv |
Memórias do Instituto Oswaldo Cruz - Fundação Oswaldo Cruz |
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|
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1669937657388466176 |