Crystal structure of bis{l-4-methyl-N0-[3- (oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato} bis[(dimethyl sulfoxide-jO)copper(II)]

• Autor(a) principal: Siqueira, Diego Pereira
• Data de Publicação: 2014
• Outros Autores: Siqueira, Maria Carolina Bulhosa, Gervini, Vanessa Carratu, Bresolin, Leandro, Oliveira, Adriano Bof de
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da FURG (RI FURG)
• Texto Completo: http://repositorio.furg.br/handle/1/4618
• topic: Crystal structure; Hydroxyimino-tosylhydrazone derivative; CuI''dimer; – stacking

In the title compound, [Cu2(C11H13N3O3S)2(C2H6OS)2], the CuII cation is N,N',O-chelated by a deprotonated hy­droxy­imino-tosyl­hydrazone ligand and coordinated by a dimethyl sulfoxide mol­ecule. One O atom from the adjacent hy­droxy­imino-tosyl­hydrazone ligand bridges the CuII cation, forming the centrosymmetric dimeric complex. The cation is in an overall distorted N2O3 square-pyramidal coordination environment. The methyl­benzene ring is twisted with respect to the hydrazine fragment, with a dihedral angle of 89.54 (9)° between the planes. An intra­molecular C-H...O hydrogen bond occurs. In the crystal, mol­ecules are linked by weak C-H...O and C-H...S inter­actions. Weak [pi]-[pi] stacking is also observed between parallel benzene rings of adjacent mol­ecules, the centroid-centroid distance being 3.9592 (17) Å.