Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii)
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da FURG (RI FURG) |
Texto Completo: | http://repositorio.furg.br/handle/1/1825 |
Resumo: | The reaction of 4-(phenyl)thiosemicarbazide with isatin yielded a new ligand, isatin-3-(N4- benzylthiosemicarbazone). Isatin-3-(N4-benzylthiosemicarbazone) deprotonated in ethanol/KOH reacts with an ethanolic solution of Hg(NO3)2 to give a mercury complex. The compounds were characterized by IR and X-ray single crystal structure determination. The X-ray studies revealed that the complex possesses a tetrahedral geometry with two deprotonated thiosemicarbazone ligands coordenated. The ligand and its mercury complex crystallize in the monoclinic (P21/c) and triclinic (P-1) crystal system, respectively. |
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Fonseca, Alexandra de SouzaPeres, Gisele LouroStorino, Tomás GarciaBresolin, LeandroGervini, Vanessa Carratu2012-03-05T04:52:15Z2012-03-05T04:52:15Z2010FONSECA, Alexandra de Souza et al. Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii). Química Nova, São Paulo, v. 33, n. 7, p.1453-1456, jun. 2010. Disponível em: <www.scielo.br/pdf/qn/v33n7/a06v33n7.pdf>. Acesso em: 30 dez. 2011.1453-1456http://repositorio.furg.br/handle/1/1825The reaction of 4-(phenyl)thiosemicarbazide with isatin yielded a new ligand, isatin-3-(N4- benzylthiosemicarbazone). Isatin-3-(N4-benzylthiosemicarbazone) deprotonated in ethanol/KOH reacts with an ethanolic solution of Hg(NO3)2 to give a mercury complex. The compounds were characterized by IR and X-ray single crystal structure determination. The X-ray studies revealed that the complex possesses a tetrahedral geometry with two deprotonated thiosemicarbazone ligands coordenated. The ligand and its mercury complex crystallize in the monoclinic (P21/c) and triclinic (P-1) crystal system, respectively.porMercury complexThiosemicarbazoneHydrogen bondsSíntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii)Synthesis and structural characterization of the ligand Isatin-3-(n4-benzylthiosemicarbazone) and its Mercury(ii) complex.info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da FURG (RI FURG)instname:Universidade Federal do Rio Grande (FURG)instacron:FURGORIGINALSÍNTESE E CARACTERIZAÇÃO ESTRUTURAL DO LIGANTE ISATINA.pdfSÍNTESE E CARACTERIZAÇÃO ESTRUTURAL DO LIGANTE ISATINA.pdfapplication/pdf420075https://repositorio.furg.br/bitstream/1/1825/1/S%c3%8dNTESE%20E%20CARACTERIZA%c3%87%c3%83O%20ESTRUTURAL%20DO%20LIGANTE%20ISATINA.pdfdb756c07ab3d1cc997430b88d9a76be7MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-81724https://repositorio.furg.br/bitstream/1/1825/2/license.txt5b92b9704b4f13242d70e45ddef35a68MD52open access1/18252019-11-13 21:04:57.277open accessoai:repositorio.furg.br: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Repositório InstitucionalPUBhttps://repositorio.furg.br/oai/request || http://200.19.254.174/oai/requestopendoar:2019-11-14T00:04:57Repositório Institucional da FURG (RI FURG) - Universidade Federal do Rio Grande (FURG)false |
dc.title.pt_BR.fl_str_mv |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
dc.title.alternative.pt_BR.fl_str_mv |
Synthesis and structural characterization of the ligand Isatin-3-(n4-benzylthiosemicarbazone) and its Mercury(ii) complex. |
title |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
spellingShingle |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) Fonseca, Alexandra de Souza Mercury complex Thiosemicarbazone Hydrogen bonds |
title_short |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
title_full |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
title_fullStr |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
title_full_unstemmed |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
title_sort |
Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii) |
author |
Fonseca, Alexandra de Souza |
author_facet |
Fonseca, Alexandra de Souza Peres, Gisele Louro Storino, Tomás Garcia Bresolin, Leandro Gervini, Vanessa Carratu |
author_role |
author |
author2 |
Peres, Gisele Louro Storino, Tomás Garcia Bresolin, Leandro Gervini, Vanessa Carratu |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Fonseca, Alexandra de Souza Peres, Gisele Louro Storino, Tomás Garcia Bresolin, Leandro Gervini, Vanessa Carratu |
dc.subject.por.fl_str_mv |
Mercury complex Thiosemicarbazone Hydrogen bonds |
topic |
Mercury complex Thiosemicarbazone Hydrogen bonds |
description |
The reaction of 4-(phenyl)thiosemicarbazide with isatin yielded a new ligand, isatin-3-(N4- benzylthiosemicarbazone). Isatin-3-(N4-benzylthiosemicarbazone) deprotonated in ethanol/KOH reacts with an ethanolic solution of Hg(NO3)2 to give a mercury complex. The compounds were characterized by IR and X-ray single crystal structure determination. The X-ray studies revealed that the complex possesses a tetrahedral geometry with two deprotonated thiosemicarbazone ligands coordenated. The ligand and its mercury complex crystallize in the monoclinic (P21/c) and triclinic (P-1) crystal system, respectively. |
publishDate |
2010 |
dc.date.issued.fl_str_mv |
2010 |
dc.date.accessioned.fl_str_mv |
2012-03-05T04:52:15Z |
dc.date.available.fl_str_mv |
2012-03-05T04:52:15Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
FONSECA, Alexandra de Souza et al. Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii). Química Nova, São Paulo, v. 33, n. 7, p.1453-1456, jun. 2010. Disponível em: <www.scielo.br/pdf/qn/v33n7/a06v33n7.pdf>. Acesso em: 30 dez. 2011. |
dc.identifier.uri.fl_str_mv |
http://repositorio.furg.br/handle/1/1825 |
dc.identifier.issn.none.fl_str_mv |
1453-1456 |
identifier_str_mv |
FONSECA, Alexandra de Souza et al. Síntese e caracterização estrutural do ligante Isatina-3-(n4-benziltiossemicarbazona) e do seu complexo de Mercúrio(ii). Química Nova, São Paulo, v. 33, n. 7, p.1453-1456, jun. 2010. Disponível em: <www.scielo.br/pdf/qn/v33n7/a06v33n7.pdf>. Acesso em: 30 dez. 2011. 1453-1456 |
url |
http://repositorio.furg.br/handle/1/1825 |
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por |
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por |
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info:eu-repo/semantics/openAccess |
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openAccess |
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reponame:Repositório Institucional da FURG (RI FURG) instname:Universidade Federal do Rio Grande (FURG) instacron:FURG |
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Universidade Federal do Rio Grande (FURG) |
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FURG |
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Repositório Institucional da FURG (RI FURG) |
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