Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation

Detalhes bibliográficos
Autor(a) principal: Kurz, Márcia Helena Scherer
Data de Publicação: 2009
Outros Autores: Gonçalves, Fábio Ferreira, Martel, Samile, Adaime, Martha Bohrer, Zanella, Renato, Machado, Sérgio Luiz de Oliveira, Primel, Ednei Gilberto
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da FURG (RI FURG)
Texto Completo: http://repositorio.furg.br/handle/1/4413
Resumo: A new method is described for the determination of the herbicide bispyribac-sodium in surface water, especially from river and irrigated rice water samples. The method involves extraction in solid phase and quantification by high performance liquid chromatography with diode array detection (HPLC-DAD). After optimization of the extraction and separation parameters, the method was validated. The method presented average recoveries of 101.3 and 97.7%, under repeatability and intermediate precision conditions, respectively, with adequate precision (RSD from 0.9 to 7.5%). The method was applied for the determination of bispyribac-sodium in surface water samples with a limit of detection of 0.1 μg L-1.
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spelling Kurz, Márcia Helena SchererGonçalves, Fábio FerreiraMartel, SamileAdaime, Martha BohrerZanella, RenatoMachado, Sérgio Luiz de OliveiraPrimel, Ednei Gilberto2014-07-22T16:40:02Z2014-07-22T16:40:02Z2009KURZ, Márcia Helena Scherer. et al. Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation. Quimica Nova, v. 32, n. 6, p. 1457-1460, 2009. Disponível em: <http://quimicanova.sbq.org.br/qn/qnol/2009/vol32n6/17-AR08351.pdf>. Acesso em: 26 fev. 2014.0100-4042http://repositorio.furg.br/handle/1/4413A new method is described for the determination of the herbicide bispyribac-sodium in surface water, especially from river and irrigated rice water samples. The method involves extraction in solid phase and quantification by high performance liquid chromatography with diode array detection (HPLC-DAD). After optimization of the extraction and separation parameters, the method was validated. The method presented average recoveries of 101.3 and 97.7%, under repeatability and intermediate precision conditions, respectively, with adequate precision (RSD from 0.9 to 7.5%). The method was applied for the determination of bispyribac-sodium in surface water samples with a limit of detection of 0.1 μg L-1.engpesticideriver waterirrigation waterRapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validationinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da FURG (RI FURG)instname:Universidade Federal do Rio Grande (FURG)instacron:FURGORIGINALRapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation.pdfRapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation.pdfapplication/pdf141425https://repositorio.furg.br/bitstream/1/4413/1/Rapid%20and%20accurate%20HPLC-DAD%20method%20for%20the%20determination%20of%20the%20herbicide%20bispyribac-sodium%20in%20surface%20water%2c%20and%20its%20validation.pdf008fda98238b4471de1dadfbea4369b5MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.furg.br/bitstream/1/4413/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52open access1/44132014-07-22 13:40:02.242open accessoai:repositorio.furg.br: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Repositório InstitucionalPUBhttps://repositorio.furg.br/oai/request || http://200.19.254.174/oai/requestopendoar:2014-07-22T16:40:02Repositório Institucional da FURG (RI FURG) - Universidade Federal do Rio Grande (FURG)false
dc.title.pt_BR.fl_str_mv Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
title Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
spellingShingle Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
Kurz, Márcia Helena Scherer
pesticide
river water
irrigation water
title_short Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
title_full Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
title_fullStr Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
title_full_unstemmed Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
title_sort Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation
author Kurz, Márcia Helena Scherer
author_facet Kurz, Márcia Helena Scherer
Gonçalves, Fábio Ferreira
Martel, Samile
Adaime, Martha Bohrer
Zanella, Renato
Machado, Sérgio Luiz de Oliveira
Primel, Ednei Gilberto
author_role author
author2 Gonçalves, Fábio Ferreira
Martel, Samile
Adaime, Martha Bohrer
Zanella, Renato
Machado, Sérgio Luiz de Oliveira
Primel, Ednei Gilberto
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Kurz, Márcia Helena Scherer
Gonçalves, Fábio Ferreira
Martel, Samile
Adaime, Martha Bohrer
Zanella, Renato
Machado, Sérgio Luiz de Oliveira
Primel, Ednei Gilberto
dc.subject.por.fl_str_mv pesticide
river water
irrigation water
topic pesticide
river water
irrigation water
description A new method is described for the determination of the herbicide bispyribac-sodium in surface water, especially from river and irrigated rice water samples. The method involves extraction in solid phase and quantification by high performance liquid chromatography with diode array detection (HPLC-DAD). After optimization of the extraction and separation parameters, the method was validated. The method presented average recoveries of 101.3 and 97.7%, under repeatability and intermediate precision conditions, respectively, with adequate precision (RSD from 0.9 to 7.5%). The method was applied for the determination of bispyribac-sodium in surface water samples with a limit of detection of 0.1 μg L-1.
publishDate 2009
dc.date.issued.fl_str_mv 2009
dc.date.accessioned.fl_str_mv 2014-07-22T16:40:02Z
dc.date.available.fl_str_mv 2014-07-22T16:40:02Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv KURZ, Márcia Helena Scherer. et al. Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation. Quimica Nova, v. 32, n. 6, p. 1457-1460, 2009. Disponível em: <http://quimicanova.sbq.org.br/qn/qnol/2009/vol32n6/17-AR08351.pdf>. Acesso em: 26 fev. 2014.
dc.identifier.uri.fl_str_mv http://repositorio.furg.br/handle/1/4413
dc.identifier.issn.none.fl_str_mv 0100-4042
identifier_str_mv KURZ, Márcia Helena Scherer. et al. Rapid and accurate HPLC-DAD method for the determination of the herbicide bispyribac-sodium in surface water, and its validation. Quimica Nova, v. 32, n. 6, p. 1457-1460, 2009. Disponível em: <http://quimicanova.sbq.org.br/qn/qnol/2009/vol32n6/17-AR08351.pdf>. Acesso em: 26 fev. 2014.
0100-4042
url http://repositorio.furg.br/handle/1/4413
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Repositório Institucional da FURG (RI FURG)
instname:Universidade Federal do Rio Grande (FURG)
instacron:FURG
instname_str Universidade Federal do Rio Grande (FURG)
instacron_str FURG
institution FURG
reponame_str Repositório Institucional da FURG (RI FURG)
collection Repositório Institucional da FURG (RI FURG)
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