Reaction mechanisms of alkali-activated materials

Detalhes bibliográficos
Autor(a) principal: Marvila,Markssuel Teixeira
Data de Publicação: 2021
Outros Autores: Azevedo,Afonso Rangel Garcez de, Vieira,Carlos Maurício Fontes
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Revista IBRACON de Estruturas e Materiais
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500
Resumo: abstract: The Alkali-Activated Materials (AAM) are defined as materials obtained through the reaction between precursors and activators, and are separated into two classes depending on the products formed in the reaction, those rich in calcium, as the blast furnace slag, whose Ca/(Si+Al) ratio is higher than 1; and poor in calcium, which is the geopolymers subclass. In this review article, some bibliographical aspects were discussed regarding the discovery of these materials, through research conducted by Victor Glukhovsky and through the characterization of historical monuments by Davidovits, which began in the 50s and 60s and persist to the present day. The main products obtained in the alkaline activation reaction were also addressed, using the definition of polysialates and zeolites, in the case of geopolymers, and the tobermorite structure, in the case of materials rich in calcium. The main steps of the alkali-activated reaction, such as dissolution, condensation, polycondensation, crystallization, and hardening, were discussed. Some techniques for characterizing the AA reaction products were also examined, such as X-ray diffraction (XRD), nuclear magnetic resonance spectrometry (NMR), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Finally, the main factors that interfere in the kinetics of AA reactions were explored, in which the type of cure and the activating solution used in the alkali-activated materials production stands out.
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spelling Reaction mechanisms of alkali-activated materialsalkali-activated materialsgeopolymersprecursorsabstract: The Alkali-Activated Materials (AAM) are defined as materials obtained through the reaction between precursors and activators, and are separated into two classes depending on the products formed in the reaction, those rich in calcium, as the blast furnace slag, whose Ca/(Si+Al) ratio is higher than 1; and poor in calcium, which is the geopolymers subclass. In this review article, some bibliographical aspects were discussed regarding the discovery of these materials, through research conducted by Victor Glukhovsky and through the characterization of historical monuments by Davidovits, which began in the 50s and 60s and persist to the present day. The main products obtained in the alkaline activation reaction were also addressed, using the definition of polysialates and zeolites, in the case of geopolymers, and the tobermorite structure, in the case of materials rich in calcium. The main steps of the alkali-activated reaction, such as dissolution, condensation, polycondensation, crystallization, and hardening, were discussed. Some techniques for characterizing the AA reaction products were also examined, such as X-ray diffraction (XRD), nuclear magnetic resonance spectrometry (NMR), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Finally, the main factors that interfere in the kinetics of AA reactions were explored, in which the type of cure and the activating solution used in the alkali-activated materials production stands out.IBRACON - Instituto Brasileiro do Concreto2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500Revista IBRACON de Estruturas e Materiais v.14 n.3 2021reponame:Revista IBRACON de Estruturas e Materiaisinstname:Instituto Brasileiro do Concreto (IBRACON)instacron:IBRACON10.1590/s1983-41952021000300009info:eu-repo/semantics/openAccessMarvila,Markssuel TeixeiraAzevedo,Afonso Rangel Garcez deVieira,Carlos Maurício Fonteseng2021-04-05T00:00:00Zoai:scielo:S1983-41952021000300500Revistahttp://www.revistas.ibracon.org.br/index.php/riemhttps://old.scielo.br/oai/scielo-oai.phpeditores.riem@gmail.com||arlene@ibracon.org.br1983-41951983-4195opendoar:2021-04-05T00:00Revista IBRACON de Estruturas e Materiais - Instituto Brasileiro do Concreto (IBRACON)false
dc.title.none.fl_str_mv Reaction mechanisms of alkali-activated materials
title Reaction mechanisms of alkali-activated materials
spellingShingle Reaction mechanisms of alkali-activated materials
Marvila,Markssuel Teixeira
alkali-activated materials
geopolymers
precursors
title_short Reaction mechanisms of alkali-activated materials
title_full Reaction mechanisms of alkali-activated materials
title_fullStr Reaction mechanisms of alkali-activated materials
title_full_unstemmed Reaction mechanisms of alkali-activated materials
title_sort Reaction mechanisms of alkali-activated materials
author Marvila,Markssuel Teixeira
author_facet Marvila,Markssuel Teixeira
Azevedo,Afonso Rangel Garcez de
Vieira,Carlos Maurício Fontes
author_role author
author2 Azevedo,Afonso Rangel Garcez de
Vieira,Carlos Maurício Fontes
author2_role author
author
dc.contributor.author.fl_str_mv Marvila,Markssuel Teixeira
Azevedo,Afonso Rangel Garcez de
Vieira,Carlos Maurício Fontes
dc.subject.por.fl_str_mv alkali-activated materials
geopolymers
precursors
topic alkali-activated materials
geopolymers
precursors
description abstract: The Alkali-Activated Materials (AAM) are defined as materials obtained through the reaction between precursors and activators, and are separated into two classes depending on the products formed in the reaction, those rich in calcium, as the blast furnace slag, whose Ca/(Si+Al) ratio is higher than 1; and poor in calcium, which is the geopolymers subclass. In this review article, some bibliographical aspects were discussed regarding the discovery of these materials, through research conducted by Victor Glukhovsky and through the characterization of historical monuments by Davidovits, which began in the 50s and 60s and persist to the present day. The main products obtained in the alkaline activation reaction were also addressed, using the definition of polysialates and zeolites, in the case of geopolymers, and the tobermorite structure, in the case of materials rich in calcium. The main steps of the alkali-activated reaction, such as dissolution, condensation, polycondensation, crystallization, and hardening, were discussed. Some techniques for characterizing the AA reaction products were also examined, such as X-ray diffraction (XRD), nuclear magnetic resonance spectrometry (NMR), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Finally, the main factors that interfere in the kinetics of AA reactions were explored, in which the type of cure and the activating solution used in the alkali-activated materials production stands out.
publishDate 2021
dc.date.none.fl_str_mv 2021-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/s1983-41952021000300009
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv IBRACON - Instituto Brasileiro do Concreto
publisher.none.fl_str_mv IBRACON - Instituto Brasileiro do Concreto
dc.source.none.fl_str_mv Revista IBRACON de Estruturas e Materiais v.14 n.3 2021
reponame:Revista IBRACON de Estruturas e Materiais
instname:Instituto Brasileiro do Concreto (IBRACON)
instacron:IBRACON
instname_str Instituto Brasileiro do Concreto (IBRACON)
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institution IBRACON
reponame_str Revista IBRACON de Estruturas e Materiais
collection Revista IBRACON de Estruturas e Materiais
repository.name.fl_str_mv Revista IBRACON de Estruturas e Materiais - Instituto Brasileiro do Concreto (IBRACON)
repository.mail.fl_str_mv editores.riem@gmail.com||arlene@ibracon.org.br
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