Reaction mechanisms of alkali-activated materials
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Revista IBRACON de Estruturas e Materiais |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500 |
Resumo: | abstract: The Alkali-Activated Materials (AAM) are defined as materials obtained through the reaction between precursors and activators, and are separated into two classes depending on the products formed in the reaction, those rich in calcium, as the blast furnace slag, whose Ca/(Si+Al) ratio is higher than 1; and poor in calcium, which is the geopolymers subclass. In this review article, some bibliographical aspects were discussed regarding the discovery of these materials, through research conducted by Victor Glukhovsky and through the characterization of historical monuments by Davidovits, which began in the 50s and 60s and persist to the present day. The main products obtained in the alkaline activation reaction were also addressed, using the definition of polysialates and zeolites, in the case of geopolymers, and the tobermorite structure, in the case of materials rich in calcium. The main steps of the alkali-activated reaction, such as dissolution, condensation, polycondensation, crystallization, and hardening, were discussed. Some techniques for characterizing the AA reaction products were also examined, such as X-ray diffraction (XRD), nuclear magnetic resonance spectrometry (NMR), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Finally, the main factors that interfere in the kinetics of AA reactions were explored, in which the type of cure and the activating solution used in the alkali-activated materials production stands out. |
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Reaction mechanisms of alkali-activated materialsalkali-activated materialsgeopolymersprecursorsabstract: The Alkali-Activated Materials (AAM) are defined as materials obtained through the reaction between precursors and activators, and are separated into two classes depending on the products formed in the reaction, those rich in calcium, as the blast furnace slag, whose Ca/(Si+Al) ratio is higher than 1; and poor in calcium, which is the geopolymers subclass. In this review article, some bibliographical aspects were discussed regarding the discovery of these materials, through research conducted by Victor Glukhovsky and through the characterization of historical monuments by Davidovits, which began in the 50s and 60s and persist to the present day. The main products obtained in the alkaline activation reaction were also addressed, using the definition of polysialates and zeolites, in the case of geopolymers, and the tobermorite structure, in the case of materials rich in calcium. The main steps of the alkali-activated reaction, such as dissolution, condensation, polycondensation, crystallization, and hardening, were discussed. Some techniques for characterizing the AA reaction products were also examined, such as X-ray diffraction (XRD), nuclear magnetic resonance spectrometry (NMR), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Finally, the main factors that interfere in the kinetics of AA reactions were explored, in which the type of cure and the activating solution used in the alkali-activated materials production stands out.IBRACON - Instituto Brasileiro do Concreto2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500Revista IBRACON de Estruturas e Materiais v.14 n.3 2021reponame:Revista IBRACON de Estruturas e Materiaisinstname:Instituto Brasileiro do Concreto (IBRACON)instacron:IBRACON10.1590/s1983-41952021000300009info:eu-repo/semantics/openAccessMarvila,Markssuel TeixeiraAzevedo,Afonso Rangel Garcez deVieira,Carlos Maurício Fonteseng2021-04-05T00:00:00Zoai:scielo:S1983-41952021000300500Revistahttp://www.revistas.ibracon.org.br/index.php/riemhttps://old.scielo.br/oai/scielo-oai.phpeditores.riem@gmail.com||arlene@ibracon.org.br1983-41951983-4195opendoar:2021-04-05T00:00Revista IBRACON de Estruturas e Materiais - Instituto Brasileiro do Concreto (IBRACON)false |
dc.title.none.fl_str_mv |
Reaction mechanisms of alkali-activated materials |
title |
Reaction mechanisms of alkali-activated materials |
spellingShingle |
Reaction mechanisms of alkali-activated materials Marvila,Markssuel Teixeira alkali-activated materials geopolymers precursors |
title_short |
Reaction mechanisms of alkali-activated materials |
title_full |
Reaction mechanisms of alkali-activated materials |
title_fullStr |
Reaction mechanisms of alkali-activated materials |
title_full_unstemmed |
Reaction mechanisms of alkali-activated materials |
title_sort |
Reaction mechanisms of alkali-activated materials |
author |
Marvila,Markssuel Teixeira |
author_facet |
Marvila,Markssuel Teixeira Azevedo,Afonso Rangel Garcez de Vieira,Carlos Maurício Fontes |
author_role |
author |
author2 |
Azevedo,Afonso Rangel Garcez de Vieira,Carlos Maurício Fontes |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Marvila,Markssuel Teixeira Azevedo,Afonso Rangel Garcez de Vieira,Carlos Maurício Fontes |
dc.subject.por.fl_str_mv |
alkali-activated materials geopolymers precursors |
topic |
alkali-activated materials geopolymers precursors |
description |
abstract: The Alkali-Activated Materials (AAM) are defined as materials obtained through the reaction between precursors and activators, and are separated into two classes depending on the products formed in the reaction, those rich in calcium, as the blast furnace slag, whose Ca/(Si+Al) ratio is higher than 1; and poor in calcium, which is the geopolymers subclass. In this review article, some bibliographical aspects were discussed regarding the discovery of these materials, through research conducted by Victor Glukhovsky and through the characterization of historical monuments by Davidovits, which began in the 50s and 60s and persist to the present day. The main products obtained in the alkaline activation reaction were also addressed, using the definition of polysialates and zeolites, in the case of geopolymers, and the tobermorite structure, in the case of materials rich in calcium. The main steps of the alkali-activated reaction, such as dissolution, condensation, polycondensation, crystallization, and hardening, were discussed. Some techniques for characterizing the AA reaction products were also examined, such as X-ray diffraction (XRD), nuclear magnetic resonance spectrometry (NMR), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Finally, the main factors that interfere in the kinetics of AA reactions were explored, in which the type of cure and the activating solution used in the alkali-activated materials production stands out. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952021000300500 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/s1983-41952021000300009 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
IBRACON - Instituto Brasileiro do Concreto |
publisher.none.fl_str_mv |
IBRACON - Instituto Brasileiro do Concreto |
dc.source.none.fl_str_mv |
Revista IBRACON de Estruturas e Materiais v.14 n.3 2021 reponame:Revista IBRACON de Estruturas e Materiais instname:Instituto Brasileiro do Concreto (IBRACON) instacron:IBRACON |
instname_str |
Instituto Brasileiro do Concreto (IBRACON) |
instacron_str |
IBRACON |
institution |
IBRACON |
reponame_str |
Revista IBRACON de Estruturas e Materiais |
collection |
Revista IBRACON de Estruturas e Materiais |
repository.name.fl_str_mv |
Revista IBRACON de Estruturas e Materiais - Instituto Brasileiro do Concreto (IBRACON) |
repository.mail.fl_str_mv |
editores.riem@gmail.com||arlene@ibracon.org.br |
_version_ |
1754193606482067456 |