Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , |
Tipo de documento: | Artigo de conferência |
Idioma: | eng |
Título da fonte: | Repositório Institucional do IEN |
Texto Completo: | http://carpedien.ien.gov.br:8080/handle/ien/2383 |
Resumo: | The occurrence of Thorium in ores is normally associated to other elements such as Uranium and Cerium, as well as some Rare-Earths (RE). The separation of these elements by traditional analytic chemistry techniques is both time and reagent consuming, thus increasing the analysis cost. The hereby proposed method consists in the direct determination of Thorium in rare earths ores and compounds by X-ray fluorescence spectroscopy without any prior chemical separation from other matrix elements. This non-destructive technique is used to determine which elements are present in solid and liquid samples, as well as their concentrations. The studied matrix contains Lanthanum, Cerium, Praseodymium, Neodymium, Samarium, Gadolinium and Yttrium. This study evaluated the analytical lines of radiation emission for each rare earth contained in the matrix, comparing it to the Thorium main analytical line. The Thorium quantification was measured through the Th L line, where there is no influence or interference from the rare earths analytical lines. The studied samples are certified standards and the obtained results have been compared to Ethylenediaminetetraacetic acid (EDTA) titration results, an already well-established and widely trusted method. We also measured the matrix effect thus using complex rare earths liquor. This liquor contains also elements commonly found in monazites sands: phosphates, aluminum, iron. Obtained results state the efficience of X-ray Fluorescence to determine Thorium in the presence of rare earths without any prior chemical separation. |
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Jesus, CamilaTaam, IsabelVianna, CláudioInstituto de Engenharia Nuclear2018-06-07T13:52:27Z2018-06-07T13:52:27Z2013-11http://carpedien.ien.gov.br:8080/handle/ien/2383Submitted by Marcele Costal de Castro (costalcastro@gmail.com) on 2018-06-07T13:52:27Z No. of bitstreams: 1 quantitative-analysis-of-thorium-in-the-presence-of-rare-earth-by-x-ray-fluorescence-spectrometry.pdf: 150510 bytes, checksum: 7367e3c71f71a8ef4d68057f83b0b875 (MD5)Made available in DSpace on 2018-06-07T13:52:27Z (GMT). No. of bitstreams: 1 quantitative-analysis-of-thorium-in-the-presence-of-rare-earth-by-x-ray-fluorescence-spectrometry.pdf: 150510 bytes, checksum: 7367e3c71f71a8ef4d68057f83b0b875 (MD5) Previous issue date: 2013-11The occurrence of Thorium in ores is normally associated to other elements such as Uranium and Cerium, as well as some Rare-Earths (RE). The separation of these elements by traditional analytic chemistry techniques is both time and reagent consuming, thus increasing the analysis cost. The hereby proposed method consists in the direct determination of Thorium in rare earths ores and compounds by X-ray fluorescence spectroscopy without any prior chemical separation from other matrix elements. This non-destructive technique is used to determine which elements are present in solid and liquid samples, as well as their concentrations. The studied matrix contains Lanthanum, Cerium, Praseodymium, Neodymium, Samarium, Gadolinium and Yttrium. This study evaluated the analytical lines of radiation emission for each rare earth contained in the matrix, comparing it to the Thorium main analytical line. The Thorium quantification was measured through the Th L line, where there is no influence or interference from the rare earths analytical lines. The studied samples are certified standards and the obtained results have been compared to Ethylenediaminetetraacetic acid (EDTA) titration results, an already well-established and widely trusted method. We also measured the matrix effect thus using complex rare earths liquor. This liquor contains also elements commonly found in monazites sands: phosphates, aluminum, iron. Obtained results state the efficience of X-ray Fluorescence to determine Thorium in the presence of rare earths without any prior chemical separation.engInstituto de Engenharia NuclearIENBrasilINAC 2013Analytic ChemistryX-rayThoriumSpectrometryRare-EarthsQuantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometryinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectVI INACinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional do IENinstname:Instituto de Engenharia Nuclearinstacron:IENLICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://carpedien.ien.gov.br:8080/xmlui/bitstream/ien/2383/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52ORIGINALquantitative-analysis-of-thorium-in-the-presence-of-rare-earth-by-x-ray-fluorescence-spectrometry.pdfquantitative-analysis-of-thorium-in-the-presence-of-rare-earth-by-x-ray-fluorescence-spectrometry.pdfapplication/pdf150510http://carpedien.ien.gov.br:8080/xmlui/bitstream/ien/2383/1/quantitative-analysis-of-thorium-in-the-presence-of-rare-earth-by-x-ray-fluorescence-spectrometry.pdf7367e3c71f71a8ef4d68057f83b0b875MD51ien/2383oai:carpedien.ien.gov.br:ien/23832018-06-07 10:52:27.991Dspace IENlsales@ien.gov.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 |
dc.title.pt_BR.fl_str_mv |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry |
title |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry |
spellingShingle |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry Jesus, Camila INAC 2013 Analytic Chemistry X-ray Thorium Spectrometry Rare-Earths |
title_short |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry |
title_full |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry |
title_fullStr |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry |
title_full_unstemmed |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry |
title_sort |
Quantitative analysis of thorium in the presence of rare earth by x-ray fluorescence spectrometry |
author |
Jesus, Camila |
author_facet |
Jesus, Camila Taam, Isabel Vianna, Cláudio Instituto de Engenharia Nuclear |
author_role |
author |
author2 |
Taam, Isabel Vianna, Cláudio Instituto de Engenharia Nuclear |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Jesus, Camila Taam, Isabel Vianna, Cláudio Instituto de Engenharia Nuclear |
dc.subject.por.fl_str_mv |
INAC 2013 Analytic Chemistry X-ray Thorium Spectrometry Rare-Earths |
topic |
INAC 2013 Analytic Chemistry X-ray Thorium Spectrometry Rare-Earths |
dc.description.abstract.por.fl_txt_mv |
The occurrence of Thorium in ores is normally associated to other elements such as Uranium and Cerium, as well as some Rare-Earths (RE). The separation of these elements by traditional analytic chemistry techniques is both time and reagent consuming, thus increasing the analysis cost. The hereby proposed method consists in the direct determination of Thorium in rare earths ores and compounds by X-ray fluorescence spectroscopy without any prior chemical separation from other matrix elements. This non-destructive technique is used to determine which elements are present in solid and liquid samples, as well as their concentrations. The studied matrix contains Lanthanum, Cerium, Praseodymium, Neodymium, Samarium, Gadolinium and Yttrium. This study evaluated the analytical lines of radiation emission for each rare earth contained in the matrix, comparing it to the Thorium main analytical line. The Thorium quantification was measured through the Th L line, where there is no influence or interference from the rare earths analytical lines. The studied samples are certified standards and the obtained results have been compared to Ethylenediaminetetraacetic acid (EDTA) titration results, an already well-established and widely trusted method. We also measured the matrix effect thus using complex rare earths liquor. This liquor contains also elements commonly found in monazites sands: phosphates, aluminum, iron. Obtained results state the efficience of X-ray Fluorescence to determine Thorium in the presence of rare earths without any prior chemical separation. |
description |
The occurrence of Thorium in ores is normally associated to other elements such as Uranium and Cerium, as well as some Rare-Earths (RE). The separation of these elements by traditional analytic chemistry techniques is both time and reagent consuming, thus increasing the analysis cost. The hereby proposed method consists in the direct determination of Thorium in rare earths ores and compounds by X-ray fluorescence spectroscopy without any prior chemical separation from other matrix elements. This non-destructive technique is used to determine which elements are present in solid and liquid samples, as well as their concentrations. The studied matrix contains Lanthanum, Cerium, Praseodymium, Neodymium, Samarium, Gadolinium and Yttrium. This study evaluated the analytical lines of radiation emission for each rare earth contained in the matrix, comparing it to the Thorium main analytical line. The Thorium quantification was measured through the Th L line, where there is no influence or interference from the rare earths analytical lines. The studied samples are certified standards and the obtained results have been compared to Ethylenediaminetetraacetic acid (EDTA) titration results, an already well-established and widely trusted method. We also measured the matrix effect thus using complex rare earths liquor. This liquor contains also elements commonly found in monazites sands: phosphates, aluminum, iron. Obtained results state the efficience of X-ray Fluorescence to determine Thorium in the presence of rare earths without any prior chemical separation. |
publishDate |
2013 |
dc.date.issued.fl_str_mv |
2013-11 |
dc.date.accessioned.fl_str_mv |
2018-06-07T13:52:27Z |
dc.date.available.fl_str_mv |
2018-06-07T13:52:27Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/conferenceObject |
status_str |
publishedVersion |
format |
conferenceObject |
dc.identifier.uri.fl_str_mv |
http://carpedien.ien.gov.br:8080/handle/ien/2383 |
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http://carpedien.ien.gov.br:8080/handle/ien/2383 |
dc.language.iso.fl_str_mv |
eng |
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eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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dc.publisher.none.fl_str_mv |
Instituto de Engenharia Nuclear |
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IEN |
dc.publisher.country.fl_str_mv |
Brasil |
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Instituto de Engenharia Nuclear |
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