AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)

Detalhes bibliográficos
Autor(a) principal: Testoni, Samara
Data de Publicação: 2023
Outros Autores: Scorsatto Ortiz, Rafael, de Cássia Mariotti, Kristiane, Anastácio de Oliveira Camargo, Flávio
Tipo de documento: Artigo
Idioma: por
Título da fonte: Revista Eletrônica Debates em Educação Científica e Tecnológica
Texto Completo: https://ojs.ifes.edu.br/index.php/ric/article/view/2250
Resumo: Forensic assessments may involve sampling textile fibers when examining crime scenes. The need to characterize and identify these fibers is of great importance, as they can provide comprehensive information about a crime, linking a suspect to a location, based on characteristics such as length, diameter and, particularly, the composition of the fibers. Fourier transform infrared micro spectroscopy in attenuated total reflectance mode (micro FTIR-ATR) is considered a non-destructive, fast and practical method for fiber identification. In this study we performed a forensic evaluation of sixty textile fibers recovered from twenty fabrics, all with white color, via micro FTIR-ATR analysis. Fiber collection was based on the tape lifting method, in order to simulate a collection in a real crime scene. The data were plotted in a two-dimensional analysis of principal components and in a radar chart to favor the comparison of the composition of the materials. The results of the infrared spectra revealed that the technique allows the discrimination of textile fibers according to their spectral composition (cellulose, ester, polyester or a mixture of these compounds) and some characteristics, such as number and width of peaks, position of the peak according to the wave number, absorbance index related to peak sharpness. It was concluded that the technique was useful and practical in the forensic evaluation of the fibers, presenting quick and enlightening results.
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spelling AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR) ciências forensescena de crime;microvestígiosespectroscopiapoliésterforensic sciencecrime scenetrace evidencespectroscopypolyesterForensic assessments may involve sampling textile fibers when examining crime scenes. The need to characterize and identify these fibers is of great importance, as they can provide comprehensive information about a crime, linking a suspect to a location, based on characteristics such as length, diameter and, particularly, the composition of the fibers. Fourier transform infrared micro spectroscopy in attenuated total reflectance mode (micro FTIR-ATR) is considered a non-destructive, fast and practical method for fiber identification. In this study we performed a forensic evaluation of sixty textile fibers recovered from twenty fabrics, all with white color, via micro FTIR-ATR analysis. Fiber collection was based on the tape lifting method, in order to simulate a collection in a real crime scene. The data were plotted in a two-dimensional analysis of principal components and in a radar chart to favor the comparison of the composition of the materials. The results of the infrared spectra revealed that the technique allows the discrimination of textile fibers according to their spectral composition (cellulose, ester, polyester or a mixture of these compounds) and some characteristics, such as number and width of peaks, position of the peak according to the wave number, absorbance index related to peak sharpness. It was concluded that the technique was useful and practical in the forensic evaluation of the fibers, presenting quick and enlightening results.As avaliações forenses podem envolver a amostragem de fibras têxteis ao examinar cenas de crime. A necessidade de caracterizar e identificar essas fibras é de grande importância, pois elas podem fornecer informações abrangentes sobre um crime, ligando um suspeito a um local, com base em características como comprimento, diâmetro e, particularmente, a composição das fibras. A micro espectroscopia de infravermelho com transformada de Fourier em modo de refletância total atenuada (micro FTIR-ATR) é considerada um método não-destrutivo, rápido e prático na identificação de fibras. Neste estudo realizamos uma avaliação forense de sessenta fibras têxteis recuperadas de vinte tecidos, todos com coloração branca, via análise de micro FTIR-ATR. A coleta das fibras foi feita com base no método de levantamento de fita, a fim de simular uma coleta em cena real de crime. Os dados foram plotados em uma análise bidimensional de componentes principais e em gráfico de radar para favorecer a comparação da composição dos materiais. Os resultados dos espectros de infravermelho revelaram que a técnica permite a discriminação de fibras têxteis de acordo com sua composição espectral (celulose, éster, poliéster ou mistura desses compostos) e algumas características, como número e largura de picos, posição do pico de acordo com o número de onda, índice de absorbância relacionado à nitidez do pico. Concluiu-se que a técnica foi útil e prática na avaliação forense das fibras, apresentando resultados rápidos e esclarecedores.Instituto Federal do Espírito Santo2023-10-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://ojs.ifes.edu.br/index.php/ric/article/view/225010.36524/ric.v9i3.2250Revista Ifes Ciência ; v. 9 n. 3 (2023): Edição Especial: Ciências Forenses ; 01-162359-479910.36524/ric.v9i3reponame:Revista Eletrônica Debates em Educação Científica e Tecnológicainstname:Instituto Federal de Educação, Ciência e Tecnologia do Espírito Santo (IFES)instacron:IFESporhttps://ojs.ifes.edu.br/index.php/ric/article/view/2250/1076Copyright (c) 2023 Revista Ifes Ciência https://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessTestoni, SamaraScorsatto Ortiz, Rafaelde Cássia Mariotti, KristianeAnastácio de Oliveira Camargo, Flávio2024-03-25T14:39:22Zoai::article/2250Revistahttps://ojs.ifes.edu.br/index.php/indexPUBhttps://ojs.ifes.edu.br/index.php/index/oairevistadect@gmail.com||sidneiquezada@gmail.com2236-21502179-6955opendoar:2024-03-25T14:39:22Revista Eletrônica Debates em Educação Científica e Tecnológica - Instituto Federal de Educação, Ciência e Tecnologia do Espírito Santo (IFES)false
dc.title.none.fl_str_mv AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
title AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
spellingShingle AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
Testoni, Samara
ciências forenses
cena de crime;
microvestígios
espectroscopia
poliéster
forensic science
crime scene
trace evidence
spectroscopy
polyester
title_short AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
title_full AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
title_fullStr AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
title_full_unstemmed AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
title_sort AVALIAÇÃO FORENSE DE FIBRAS VIA MICRO ESPECTROSCOPIA (FTIR-ATR)
author Testoni, Samara
author_facet Testoni, Samara
Scorsatto Ortiz, Rafael
de Cássia Mariotti, Kristiane
Anastácio de Oliveira Camargo, Flávio
author_role author
author2 Scorsatto Ortiz, Rafael
de Cássia Mariotti, Kristiane
Anastácio de Oliveira Camargo, Flávio
author2_role author
author
author
dc.contributor.author.fl_str_mv Testoni, Samara
Scorsatto Ortiz, Rafael
de Cássia Mariotti, Kristiane
Anastácio de Oliveira Camargo, Flávio
dc.subject.por.fl_str_mv ciências forenses
cena de crime;
microvestígios
espectroscopia
poliéster
forensic science
crime scene
trace evidence
spectroscopy
polyester
topic ciências forenses
cena de crime;
microvestígios
espectroscopia
poliéster
forensic science
crime scene
trace evidence
spectroscopy
polyester
description Forensic assessments may involve sampling textile fibers when examining crime scenes. The need to characterize and identify these fibers is of great importance, as they can provide comprehensive information about a crime, linking a suspect to a location, based on characteristics such as length, diameter and, particularly, the composition of the fibers. Fourier transform infrared micro spectroscopy in attenuated total reflectance mode (micro FTIR-ATR) is considered a non-destructive, fast and practical method for fiber identification. In this study we performed a forensic evaluation of sixty textile fibers recovered from twenty fabrics, all with white color, via micro FTIR-ATR analysis. Fiber collection was based on the tape lifting method, in order to simulate a collection in a real crime scene. The data were plotted in a two-dimensional analysis of principal components and in a radar chart to favor the comparison of the composition of the materials. The results of the infrared spectra revealed that the technique allows the discrimination of textile fibers according to their spectral composition (cellulose, ester, polyester or a mixture of these compounds) and some characteristics, such as number and width of peaks, position of the peak according to the wave number, absorbance index related to peak sharpness. It was concluded that the technique was useful and practical in the forensic evaluation of the fibers, presenting quick and enlightening results.
publishDate 2023
dc.date.none.fl_str_mv 2023-10-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://ojs.ifes.edu.br/index.php/ric/article/view/2250
10.36524/ric.v9i3.2250
url https://ojs.ifes.edu.br/index.php/ric/article/view/2250
identifier_str_mv 10.36524/ric.v9i3.2250
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://ojs.ifes.edu.br/index.php/ric/article/view/2250/1076
dc.rights.driver.fl_str_mv Copyright (c) 2023 Revista Ifes Ciência
https://creativecommons.org/licenses/by-nc-nd/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Copyright (c) 2023 Revista Ifes Ciência
https://creativecommons.org/licenses/by-nc-nd/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Instituto Federal do Espírito Santo
publisher.none.fl_str_mv Instituto Federal do Espírito Santo
dc.source.none.fl_str_mv Revista Ifes Ciência ; v. 9 n. 3 (2023): Edição Especial: Ciências Forenses ; 01-16
2359-4799
10.36524/ric.v9i3
reponame:Revista Eletrônica Debates em Educação Científica e Tecnológica
instname:Instituto Federal de Educação, Ciência e Tecnologia do Espírito Santo (IFES)
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instname_str Instituto Federal de Educação, Ciência e Tecnologia do Espírito Santo (IFES)
instacron_str IFES
institution IFES
reponame_str Revista Eletrônica Debates em Educação Científica e Tecnológica
collection Revista Eletrônica Debates em Educação Científica e Tecnológica
repository.name.fl_str_mv Revista Eletrônica Debates em Educação Científica e Tecnológica - Instituto Federal de Educação, Ciência e Tecnologia do Espírito Santo (IFES)
repository.mail.fl_str_mv revistadect@gmail.com||sidneiquezada@gmail.com
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