Unexpected seasonality in quantity and composition of Amazon rainforest air reactivity

• Autor(a) principal: Nölscher, Anke C.
• Data de Publicação: 2016
• Outros Autores: Yáñez-Serrano, Ana Maria, Wolff, Stefan, Araüjo, Alessandro Carioca de, Lavric, J. V., Kesselmeier, Jürgen, Williams, Jonathan C.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional do INPA
• Texto Completo: https://repositorio.inpa.gov.br/handle/1/15840
• topic: Isoprene; Air Quality; Atmospheric Pollution; Concentration (composition); Hydroxyl Radical; Isoprene; Photochemistry; Pollutant Removal; Pristine Environment; Quantitative Analysis; Rainforest; Reaction Kinetics; Seasonality; Trace Gas; Turbulent Mixing; Dry Season; Environmental Parameters; Environmental Temperature; Gas; Photochemistry; Rainforest; Rainforest Air Reactivity; Season; Seasonal Variation; Wet Season; Amazonas; Brasil

The hydroxyl radical (OH) removes most atmospheric pollutants from air. The loss frequency of OH radicals due to the combined effect of all gas-phase OH reactive species is a measureable quantity termed total OH reactivity. Here we present total OH reactivity observations in pristine Amazon rainforest air, as a function of season, time-of-day and height (0-80 m). Total OH reactivity is low during wet (10s-1) and high during dry season (62s-1). Comparison to individually measured trace gases reveals strong variation in unaccounted for OH reactivity, from 5 to 15% missing in wet-season afternoons to mostly unknown (average 79%) during dry season. During dry-season afternoons isoprene, considered the dominant reagent with OH in rainforests, only accounts for ∼20% of the total OH reactivity. Vertical profiles of OH reactivity are shaped by biogenic emissions, photochemistry and turbulent mixing. The rainforest floor was identified as a significant but poorly characterized source of OH reactivity.