Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF

Detalhes bibliográficos
Autor(a) principal: Gonzalez, Joselaine C.
Data de Publicação: 2019
Outros Autores: Simões, Grazieli, Bernini, Rafael Berrelho, Coutinho, Lúcia H., Stedile, Fernanda Chiarello, Nunez, C. V., Vicentin, Flávio César, Souza, Gerardo Gerson Bezerra de
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional do INPA
Texto Completo: https://repositorio.inpa.gov.br/handle/1/15317
Resumo: The inorganic composition of the bark and leaf of a plant from the Amazon rainforest, Andira surinamensis, was determined using two non-destructive, multi-element techniques: X-ray fluorescence (XRF) and Rutherford backscattering spectrometry (RBS). XRF measurements were made using both a conventional X-ray source and synchrotron radiation. It was observed that although magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, and potassium are present in higher concentrations in the leaf, calcium is about three times more concentrated in the bark. Manganese, iron, copper, zinc, strontium and barium were also detected, with barium showing a concentration above the minimum toxicity level for plants. Chemical speciation of sulfur, performed using the X-ray absorption near edge structure (XANES) technique, showed that sulfur is present in several oxidation states, with a much larger contribution from the inorganic sulfate in the leaves. The article evidences that the combined use of synchrotron radiation and non-destructive multielement techniques allows for an efficient and accurate determination of the inorganic composition and chemical speciation in plants. © 2019 Sociedade Brasileira de Química.
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spelling Gonzalez, Joselaine C.Simões, GrazieliBernini, Rafael BerrelhoCoutinho, Lúcia H.Stedile, Fernanda ChiarelloNunez, C. V.Vicentin, Flávio CésarSouza, Gerardo Gerson Bezerra de2020-05-07T21:17:26Z2020-05-07T21:17:26Z2019https://repositorio.inpa.gov.br/handle/1/1531710.21577/0103-5053.20190098The inorganic composition of the bark and leaf of a plant from the Amazon rainforest, Andira surinamensis, was determined using two non-destructive, multi-element techniques: X-ray fluorescence (XRF) and Rutherford backscattering spectrometry (RBS). XRF measurements were made using both a conventional X-ray source and synchrotron radiation. It was observed that although magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, and potassium are present in higher concentrations in the leaf, calcium is about three times more concentrated in the bark. Manganese, iron, copper, zinc, strontium and barium were also detected, with barium showing a concentration above the minimum toxicity level for plants. Chemical speciation of sulfur, performed using the X-ray absorption near edge structure (XANES) technique, showed that sulfur is present in several oxidation states, with a much larger contribution from the inorganic sulfate in the leaves. The article evidences that the combined use of synchrotron radiation and non-destructive multielement techniques allows for an efficient and accurate determination of the inorganic composition and chemical speciation in plants. © 2019 Sociedade Brasileira de Química.Volume 30, Número 9, Pags. 1887-1896Attribution-NonCommercial-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nc-nd/3.0/br/info:eu-repo/semantics/openAccessElemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRFinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleJournal of the Brazilian Chemical Societyengreponame:Repositório Institucional do INPAinstname:Instituto Nacional de Pesquisas da Amazônia (INPA)instacron:INPAORIGINALartigo-inpa.pdfartigo-inpa.pdfapplication/pdf575753https://repositorio.inpa.gov.br/bitstream/1/15317/1/artigo-inpa.pdf5daf75739ba415fc42c9f66172326d5bMD511/153172020-07-14 11:08:08.557oai:repositorio:1/15317Repositório de PublicaçõesPUBhttps://repositorio.inpa.gov.br/oai/requestopendoar:2020-07-14T15:08:08Repositório Institucional do INPA - Instituto Nacional de Pesquisas da Amazônia (INPA)false
dc.title.en.fl_str_mv Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
title Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
spellingShingle Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
Gonzalez, Joselaine C.
title_short Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
title_full Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
title_fullStr Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
title_full_unstemmed Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
title_sort Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
author Gonzalez, Joselaine C.
author_facet Gonzalez, Joselaine C.
Simões, Grazieli
Bernini, Rafael Berrelho
Coutinho, Lúcia H.
Stedile, Fernanda Chiarello
Nunez, C. V.
Vicentin, Flávio César
Souza, Gerardo Gerson Bezerra de
author_role author
author2 Simões, Grazieli
Bernini, Rafael Berrelho
Coutinho, Lúcia H.
Stedile, Fernanda Chiarello
Nunez, C. V.
Vicentin, Flávio César
Souza, Gerardo Gerson Bezerra de
author2_role author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Gonzalez, Joselaine C.
Simões, Grazieli
Bernini, Rafael Berrelho
Coutinho, Lúcia H.
Stedile, Fernanda Chiarello
Nunez, C. V.
Vicentin, Flávio César
Souza, Gerardo Gerson Bezerra de
description The inorganic composition of the bark and leaf of a plant from the Amazon rainforest, Andira surinamensis, was determined using two non-destructive, multi-element techniques: X-ray fluorescence (XRF) and Rutherford backscattering spectrometry (RBS). XRF measurements were made using both a conventional X-ray source and synchrotron radiation. It was observed that although magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, and potassium are present in higher concentrations in the leaf, calcium is about three times more concentrated in the bark. Manganese, iron, copper, zinc, strontium and barium were also detected, with barium showing a concentration above the minimum toxicity level for plants. Chemical speciation of sulfur, performed using the X-ray absorption near edge structure (XANES) technique, showed that sulfur is present in several oxidation states, with a much larger contribution from the inorganic sulfate in the leaves. The article evidences that the combined use of synchrotron radiation and non-destructive multielement techniques allows for an efficient and accurate determination of the inorganic composition and chemical speciation in plants. © 2019 Sociedade Brasileira de Química.
publishDate 2019
dc.date.issued.fl_str_mv 2019
dc.date.accessioned.fl_str_mv 2020-05-07T21:17:26Z
dc.date.available.fl_str_mv 2020-05-07T21:17:26Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://repositorio.inpa.gov.br/handle/1/15317
dc.identifier.doi.none.fl_str_mv 10.21577/0103-5053.20190098
url https://repositorio.inpa.gov.br/handle/1/15317
identifier_str_mv 10.21577/0103-5053.20190098
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.pt_BR.fl_str_mv Volume 30, Número 9, Pags. 1887-1896
dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nc-nd/3.0/br/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nc-nd/3.0/br/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Journal of the Brazilian Chemical Society
publisher.none.fl_str_mv Journal of the Brazilian Chemical Society
dc.source.none.fl_str_mv reponame:Repositório Institucional do INPA
instname:Instituto Nacional de Pesquisas da Amazônia (INPA)
instacron:INPA
instname_str Instituto Nacional de Pesquisas da Amazônia (INPA)
instacron_str INPA
institution INPA
reponame_str Repositório Institucional do INPA
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repository.name.fl_str_mv Repositório Institucional do INPA - Instituto Nacional de Pesquisas da Amazônia (INPA)
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