Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional do INPA |
Texto Completo: | https://repositorio.inpa.gov.br/handle/1/15317 |
Resumo: | The inorganic composition of the bark and leaf of a plant from the Amazon rainforest, Andira surinamensis, was determined using two non-destructive, multi-element techniques: X-ray fluorescence (XRF) and Rutherford backscattering spectrometry (RBS). XRF measurements were made using both a conventional X-ray source and synchrotron radiation. It was observed that although magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, and potassium are present in higher concentrations in the leaf, calcium is about three times more concentrated in the bark. Manganese, iron, copper, zinc, strontium and barium were also detected, with barium showing a concentration above the minimum toxicity level for plants. Chemical speciation of sulfur, performed using the X-ray absorption near edge structure (XANES) technique, showed that sulfur is present in several oxidation states, with a much larger contribution from the inorganic sulfate in the leaves. The article evidences that the combined use of synchrotron radiation and non-destructive multielement techniques allows for an efficient and accurate determination of the inorganic composition and chemical speciation in plants. © 2019 Sociedade Brasileira de Química. |
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Gonzalez, Joselaine C.Simões, GrazieliBernini, Rafael BerrelhoCoutinho, Lúcia H.Stedile, Fernanda ChiarelloNunez, C. V.Vicentin, Flávio CésarSouza, Gerardo Gerson Bezerra de2020-05-07T21:17:26Z2020-05-07T21:17:26Z2019https://repositorio.inpa.gov.br/handle/1/1531710.21577/0103-5053.20190098The inorganic composition of the bark and leaf of a plant from the Amazon rainforest, Andira surinamensis, was determined using two non-destructive, multi-element techniques: X-ray fluorescence (XRF) and Rutherford backscattering spectrometry (RBS). XRF measurements were made using both a conventional X-ray source and synchrotron radiation. It was observed that although magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, and potassium are present in higher concentrations in the leaf, calcium is about three times more concentrated in the bark. Manganese, iron, copper, zinc, strontium and barium were also detected, with barium showing a concentration above the minimum toxicity level for plants. Chemical speciation of sulfur, performed using the X-ray absorption near edge structure (XANES) technique, showed that sulfur is present in several oxidation states, with a much larger contribution from the inorganic sulfate in the leaves. The article evidences that the combined use of synchrotron radiation and non-destructive multielement techniques allows for an efficient and accurate determination of the inorganic composition and chemical speciation in plants. © 2019 Sociedade Brasileira de Química.Volume 30, Número 9, Pags. 1887-1896Attribution-NonCommercial-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nc-nd/3.0/br/info:eu-repo/semantics/openAccessElemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRFinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleJournal of the Brazilian Chemical Societyengreponame:Repositório Institucional do INPAinstname:Instituto Nacional de Pesquisas da Amazônia (INPA)instacron:INPAORIGINALartigo-inpa.pdfartigo-inpa.pdfapplication/pdf575753https://repositorio.inpa.gov.br/bitstream/1/15317/1/artigo-inpa.pdf5daf75739ba415fc42c9f66172326d5bMD511/153172020-07-14 11:08:08.557oai:repositorio:1/15317Repositório de PublicaçõesPUBhttps://repositorio.inpa.gov.br/oai/requestopendoar:2020-07-14T15:08:08Repositório Institucional do INPA - Instituto Nacional de Pesquisas da Amazônia (INPA)false |
dc.title.en.fl_str_mv |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF |
title |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF |
spellingShingle |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF Gonzalez, Joselaine C. |
title_short |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF |
title_full |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF |
title_fullStr |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF |
title_full_unstemmed |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF |
title_sort |
Elemental concentration and sulfur chemical speciation in the amazonian plant andira surinamensis using synchrotron radiation techniques (SR-XRF, XANES), RBS and WD-XRF |
author |
Gonzalez, Joselaine C. |
author_facet |
Gonzalez, Joselaine C. Simões, Grazieli Bernini, Rafael Berrelho Coutinho, Lúcia H. Stedile, Fernanda Chiarello Nunez, C. V. Vicentin, Flávio César Souza, Gerardo Gerson Bezerra de |
author_role |
author |
author2 |
Simões, Grazieli Bernini, Rafael Berrelho Coutinho, Lúcia H. Stedile, Fernanda Chiarello Nunez, C. V. Vicentin, Flávio César Souza, Gerardo Gerson Bezerra de |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Gonzalez, Joselaine C. Simões, Grazieli Bernini, Rafael Berrelho Coutinho, Lúcia H. Stedile, Fernanda Chiarello Nunez, C. V. Vicentin, Flávio César Souza, Gerardo Gerson Bezerra de |
description |
The inorganic composition of the bark and leaf of a plant from the Amazon rainforest, Andira surinamensis, was determined using two non-destructive, multi-element techniques: X-ray fluorescence (XRF) and Rutherford backscattering spectrometry (RBS). XRF measurements were made using both a conventional X-ray source and synchrotron radiation. It was observed that although magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, and potassium are present in higher concentrations in the leaf, calcium is about three times more concentrated in the bark. Manganese, iron, copper, zinc, strontium and barium were also detected, with barium showing a concentration above the minimum toxicity level for plants. Chemical speciation of sulfur, performed using the X-ray absorption near edge structure (XANES) technique, showed that sulfur is present in several oxidation states, with a much larger contribution from the inorganic sulfate in the leaves. The article evidences that the combined use of synchrotron radiation and non-destructive multielement techniques allows for an efficient and accurate determination of the inorganic composition and chemical speciation in plants. © 2019 Sociedade Brasileira de Química. |
publishDate |
2019 |
dc.date.issued.fl_str_mv |
2019 |
dc.date.accessioned.fl_str_mv |
2020-05-07T21:17:26Z |
dc.date.available.fl_str_mv |
2020-05-07T21:17:26Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://repositorio.inpa.gov.br/handle/1/15317 |
dc.identifier.doi.none.fl_str_mv |
10.21577/0103-5053.20190098 |
url |
https://repositorio.inpa.gov.br/handle/1/15317 |
identifier_str_mv |
10.21577/0103-5053.20190098 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.pt_BR.fl_str_mv |
Volume 30, Número 9, Pags. 1887-1896 |
dc.rights.driver.fl_str_mv |
Attribution-NonCommercial-NoDerivs 3.0 Brazil http://creativecommons.org/licenses/by-nc-nd/3.0/br/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Attribution-NonCommercial-NoDerivs 3.0 Brazil http://creativecommons.org/licenses/by-nc-nd/3.0/br/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Journal of the Brazilian Chemical Society |
publisher.none.fl_str_mv |
Journal of the Brazilian Chemical Society |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional do INPA instname:Instituto Nacional de Pesquisas da Amazônia (INPA) instacron:INPA |
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INPA |
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Repositório Institucional do INPA |
collection |
Repositório Institucional do INPA |
bitstream.url.fl_str_mv |
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