Chemical constituents from the stem of Brosimum potabile (Moraceae)

Detalhes bibliográficos
Autor(a) principal: Abreu,Viviane Gomes da Costa
Data de Publicação: 2010
Outros Autores: Silva,Marilda Conceição da, Magalhães,Rozângela Manfrini, Piló-Veloso,Dorila, Xavier,Izelene Felício da Silva, Oliveira,Patrícia Machado, Alcântra,Antônio Flávio de Carvalho
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Acta Amazonica
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0044-59672010000400011
Resumo: Three coumarins, 5-methoxypsoralene, xanthyletin, and (-)-marmesin, have been isolated from the ethanolic extract of the stem of the Amazonian plant Brosimum potabile. The structures were determined on the basis of NMR analyses and by comparison with spectroscopic data in the literature. The analysis of the hexane fractions by GC-MS in EIMS mode suggested the presence of (1-methylpentyl)-benzene; α,α-dimethyl-4-(1-methylethyl)-benzenemethanol; 1-methyl-3,5-bis(1-methylethyl)-benzene; urs-12-ene; chola-5,22-dien-3β-ol; cholesta-4,6-dien-3β-ol; sitosteryl 9(Z)-octadecenoate; cholesta-5,22-dien-3β-ol; cholesta-4,6,22-trien-3-one; and cholesta-4,22-dien-3-one. NMR data of other hexane fractions indicated the presence of 3β-acetoxy-lup-12,20(29)-diene; 3β-acetoxy-olean-12-ene; 3β-acetoxy-urs-12-ene; and adian-5-ene. All these compounds are first described in B. potabile.
id INPA-3_03218d977378d4f1622131fe584a5300
oai_identifier_str oai:scielo:S0044-59672010000400011
network_acronym_str INPA-3
network_name_str Acta Amazonica
repository_id_str
spelling Chemical constituents from the stem of Brosimum potabile (Moraceae)Brosimum potabilecoumarinspentacyclic triterpenesstructural characterization by NMR and GC/MSThree coumarins, 5-methoxypsoralene, xanthyletin, and (-)-marmesin, have been isolated from the ethanolic extract of the stem of the Amazonian plant Brosimum potabile. The structures were determined on the basis of NMR analyses and by comparison with spectroscopic data in the literature. The analysis of the hexane fractions by GC-MS in EIMS mode suggested the presence of (1-methylpentyl)-benzene; α,α-dimethyl-4-(1-methylethyl)-benzenemethanol; 1-methyl-3,5-bis(1-methylethyl)-benzene; urs-12-ene; chola-5,22-dien-3β-ol; cholesta-4,6-dien-3β-ol; sitosteryl 9(Z)-octadecenoate; cholesta-5,22-dien-3β-ol; cholesta-4,6,22-trien-3-one; and cholesta-4,22-dien-3-one. NMR data of other hexane fractions indicated the presence of 3β-acetoxy-lup-12,20(29)-diene; 3β-acetoxy-olean-12-ene; 3β-acetoxy-urs-12-ene; and adian-5-ene. All these compounds are first described in B. potabile.Instituto Nacional de Pesquisas da Amazônia2010-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0044-59672010000400011Acta Amazonica v.40 n.4 2010reponame:Acta Amazonicainstname:Instituto Nacional de Pesquisas da Amazônia (INPA)instacron:INPA10.1590/S0044-59672010000400011info:eu-repo/semantics/openAccessAbreu,Viviane Gomes da CostaSilva,Marilda Conceição daMagalhães,Rozângela ManfriniPiló-Veloso,DorilaXavier,Izelene Felício da SilvaOliveira,Patrícia MachadoAlcântra,Antônio Flávio de Carvalhoeng2011-01-03T00:00:00Zoai:scielo:S0044-59672010000400011Revistahttps://acta.inpa.gov.br/PUBhttps://old.scielo.br/oai/scielo-oai.phpacta@inpa.gov.br||acta@inpa.gov.br1809-43920044-5967opendoar:2011-01-03T00:00Acta Amazonica - Instituto Nacional de Pesquisas da Amazônia (INPA)false
dc.title.none.fl_str_mv Chemical constituents from the stem of Brosimum potabile (Moraceae)
title Chemical constituents from the stem of Brosimum potabile (Moraceae)
spellingShingle Chemical constituents from the stem of Brosimum potabile (Moraceae)
Abreu,Viviane Gomes da Costa
Brosimum potabile
coumarins
pentacyclic triterpenes
structural characterization by NMR and GC/MS
title_short Chemical constituents from the stem of Brosimum potabile (Moraceae)
title_full Chemical constituents from the stem of Brosimum potabile (Moraceae)
title_fullStr Chemical constituents from the stem of Brosimum potabile (Moraceae)
title_full_unstemmed Chemical constituents from the stem of Brosimum potabile (Moraceae)
title_sort Chemical constituents from the stem of Brosimum potabile (Moraceae)
author Abreu,Viviane Gomes da Costa
author_facet Abreu,Viviane Gomes da Costa
Silva,Marilda Conceição da
Magalhães,Rozângela Manfrini
Piló-Veloso,Dorila
Xavier,Izelene Felício da Silva
Oliveira,Patrícia Machado
Alcântra,Antônio Flávio de Carvalho
author_role author
author2 Silva,Marilda Conceição da
Magalhães,Rozângela Manfrini
Piló-Veloso,Dorila
Xavier,Izelene Felício da Silva
Oliveira,Patrícia Machado
Alcântra,Antônio Flávio de Carvalho
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Abreu,Viviane Gomes da Costa
Silva,Marilda Conceição da
Magalhães,Rozângela Manfrini
Piló-Veloso,Dorila
Xavier,Izelene Felício da Silva
Oliveira,Patrícia Machado
Alcântra,Antônio Flávio de Carvalho
dc.subject.por.fl_str_mv Brosimum potabile
coumarins
pentacyclic triterpenes
structural characterization by NMR and GC/MS
topic Brosimum potabile
coumarins
pentacyclic triterpenes
structural characterization by NMR and GC/MS
description Three coumarins, 5-methoxypsoralene, xanthyletin, and (-)-marmesin, have been isolated from the ethanolic extract of the stem of the Amazonian plant Brosimum potabile. The structures were determined on the basis of NMR analyses and by comparison with spectroscopic data in the literature. The analysis of the hexane fractions by GC-MS in EIMS mode suggested the presence of (1-methylpentyl)-benzene; α,α-dimethyl-4-(1-methylethyl)-benzenemethanol; 1-methyl-3,5-bis(1-methylethyl)-benzene; urs-12-ene; chola-5,22-dien-3β-ol; cholesta-4,6-dien-3β-ol; sitosteryl 9(Z)-octadecenoate; cholesta-5,22-dien-3β-ol; cholesta-4,6,22-trien-3-one; and cholesta-4,22-dien-3-one. NMR data of other hexane fractions indicated the presence of 3β-acetoxy-lup-12,20(29)-diene; 3β-acetoxy-olean-12-ene; 3β-acetoxy-urs-12-ene; and adian-5-ene. All these compounds are first described in B. potabile.
publishDate 2010
dc.date.none.fl_str_mv 2010-12-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0044-59672010000400011
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0044-59672010000400011
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0044-59672010000400011
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Instituto Nacional de Pesquisas da Amazônia
publisher.none.fl_str_mv Instituto Nacional de Pesquisas da Amazônia
dc.source.none.fl_str_mv Acta Amazonica v.40 n.4 2010
reponame:Acta Amazonica
instname:Instituto Nacional de Pesquisas da Amazônia (INPA)
instacron:INPA
instname_str Instituto Nacional de Pesquisas da Amazônia (INPA)
instacron_str INPA
institution INPA
reponame_str Acta Amazonica
collection Acta Amazonica
repository.name.fl_str_mv Acta Amazonica - Instituto Nacional de Pesquisas da Amazônia (INPA)
repository.mail.fl_str_mv acta@inpa.gov.br||acta@inpa.gov.br
_version_ 1752129838990229504