Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4

Detalhes bibliográficos
Autor(a) principal: DURAZZO, M.
Data de Publicação: 2018
Outros Autores: SALIBA-SILVA, A.M., MARTINS, I.C., CARVALHO, E.F.U. de, RIELLA, H.G., EUROPEAN RESEARCH REACTOR CONFERENCE
Tipo de documento: Artigo de conferência
Título da fonte: Repositório Institucional do IPEN
Texto Completo: http://repositorio.ipen.br/handle/123456789/29123
Resumo: This work presents an experimental description of thermal and physical studies to attain a practical manufacturing process of uranium metal enriched to 20% U235 (LEU???Low Enriched Uranium) by metallothermic reduction of UF4, with nuclear purity, for reduced amounts (1000g of uranium). The magnesiothermic reduction is influenced by the thermal conditions for UF4 reduction. These variables are investigated. The physical arrangement of the crucible/reduction reactor/furnace system and the management of the furnace thermal input in the reduction reactor during the heating were studied. Thermal simulation experiments provided delineation for the reactants??? thermal progress before the ignition of the reaction. The heat input to the reduction system has proved to be the main variable that influenced the efficiency of the process. The levels of metallic yield and reproducibility have been improved. The typical yield in the production of uranium metal was above 80%.
id IPEN_61b4d8943c220873a2e89062da2bf217
oai_identifier_str oai:repositorio.ipen.br:123456789/29123
network_acronym_str IPEN
network_name_str Repositório Institucional do IPEN
repository_id_str 4510
spelling 2018-09-13T12:29:23Z2018-09-13T12:29:23ZMarch 11-15, 2018http://repositorio.ipen.br/handle/123456789/29123This work presents an experimental description of thermal and physical studies to attain a practical manufacturing process of uranium metal enriched to 20% U235 (LEU???Low Enriched Uranium) by metallothermic reduction of UF4, with nuclear purity, for reduced amounts (1000g of uranium). The magnesiothermic reduction is influenced by the thermal conditions for UF4 reduction. These variables are investigated. The physical arrangement of the crucible/reduction reactor/furnace system and the management of the furnace thermal input in the reduction reactor during the heating were studied. Thermal simulation experiments provided delineation for the reactants??? thermal progress before the ignition of the reaction. The heat input to the reduction system has proved to be the main variable that influenced the efficiency of the process. The levels of metallic yield and reproducibility have been improved. The typical yield in the production of uranium metal was above 80%.Submitted by Marco Antonio Oliveira da Silva (maosilva@ipen.br) on 2018-09-13T12:29:23Z No. of bitstreams: 1 24939.pdf: 944263 bytes, checksum: f4ad648f13ff89656d8daab2e343ebb3 (MD5)Made available in DSpace on 2018-09-13T12:29:23Z (GMT). No. of bitstreams: 1 24939.pdf: 944263 bytes, checksum: f4ad648f13ff89656d8daab2e343ebb3 (MD5)Conselho Nacional de Desenvolvimento Cient??fico e Tecnol??gico (CNPq)CNPq: 304034/2015-0; 310274/2012-5; 470363/2012-61-12European Nuclear Societyuraniummetalsnuclear fuelsmaterials recoveryenriched uraniumfuelsfabricationManufacturing low enriched uranium metal by magnesiothermic reduction of UF4info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectRRFMIBrussels, BelgiumMunich, GermanyDURAZZO, M.SALIBA-SILVA, A.M.MARTINS, I.C.CARVALHO, E.F.U. deRIELLA, H.G.EUROPEAN RESEARCH REACTOR CONFERENCEinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional do IPENinstname:Instituto de Pesquisas Energéticas e Nucleares (IPEN)instacron:IPEN249392018DURAZZO, M.SALIBA-SILVA, A.M.MARTINS, I.C.CARVALHO, E.F.U. de18-09Proceedings90961720895DURAZZO, M.:90:410:SSALIBA-SILVA, A.M.:961:410:NMARTINS, I.C.:720:410:NCARVALHO, E.F.U. DE:895:410:NORIGINAL24939.pdf24939.pdfapplication/pdf944263http://repositorio.ipen.br/bitstream/123456789/29123/1/24939.pdff4ad648f13ff89656d8daab2e343ebb3MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.ipen.br/bitstream/123456789/29123/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52123456789/291232021-06-29 14:17:11.962oai:repositorio.ipen.br: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Repositório InstitucionalPUBhttp://repositorio.ipen.br/oai/requestbibl@ipen.bropendoar:45102021-06-29T14:17:11Repositório Institucional do IPEN - Instituto de Pesquisas Energéticas e Nucleares (IPEN)false
dc.title.pt_BR.fl_str_mv Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
title Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
spellingShingle Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
DURAZZO, M.
uranium
metals
nuclear fuels
materials recovery
enriched uranium
fuels
fabrication
title_short Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
title_full Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
title_fullStr Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
title_full_unstemmed Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
title_sort Manufacturing low enriched uranium metal by magnesiothermic reduction of UF4
author DURAZZO, M.
author_facet DURAZZO, M.
SALIBA-SILVA, A.M.
MARTINS, I.C.
CARVALHO, E.F.U. de
RIELLA, H.G.
EUROPEAN RESEARCH REACTOR CONFERENCE
author_role author
author2 SALIBA-SILVA, A.M.
MARTINS, I.C.
CARVALHO, E.F.U. de
RIELLA, H.G.
EUROPEAN RESEARCH REACTOR CONFERENCE
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv DURAZZO, M.
SALIBA-SILVA, A.M.
MARTINS, I.C.
CARVALHO, E.F.U. de
RIELLA, H.G.
EUROPEAN RESEARCH REACTOR CONFERENCE
dc.subject.por.fl_str_mv uranium
metals
nuclear fuels
materials recovery
enriched uranium
fuels
fabrication
topic uranium
metals
nuclear fuels
materials recovery
enriched uranium
fuels
fabrication
description This work presents an experimental description of thermal and physical studies to attain a practical manufacturing process of uranium metal enriched to 20% U235 (LEU???Low Enriched Uranium) by metallothermic reduction of UF4, with nuclear purity, for reduced amounts (1000g of uranium). The magnesiothermic reduction is influenced by the thermal conditions for UF4 reduction. These variables are investigated. The physical arrangement of the crucible/reduction reactor/furnace system and the management of the furnace thermal input in the reduction reactor during the heating were studied. Thermal simulation experiments provided delineation for the reactants??? thermal progress before the ignition of the reaction. The heat input to the reduction system has proved to be the main variable that influenced the efficiency of the process. The levels of metallic yield and reproducibility have been improved. The typical yield in the production of uranium metal was above 80%.
publishDate 2018
dc.date.evento.pt_BR.fl_str_mv March 11-15, 2018
dc.date.accessioned.fl_str_mv 2018-09-13T12:29:23Z
dc.date.available.fl_str_mv 2018-09-13T12:29:23Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/conferenceObject
format conferenceObject
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://repositorio.ipen.br/handle/123456789/29123
url http://repositorio.ipen.br/handle/123456789/29123
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1-12
dc.coverage.pt_BR.fl_str_mv I
dc.publisher.none.fl_str_mv European Nuclear Society
publisher.none.fl_str_mv European Nuclear Society
dc.source.none.fl_str_mv reponame:Repositório Institucional do IPEN
instname:Instituto de Pesquisas Energéticas e Nucleares (IPEN)
instacron:IPEN
instname_str Instituto de Pesquisas Energéticas e Nucleares (IPEN)
instacron_str IPEN
institution IPEN
reponame_str Repositório Institucional do IPEN
collection Repositório Institucional do IPEN
bitstream.url.fl_str_mv http://repositorio.ipen.br/bitstream/123456789/29123/1/24939.pdf
http://repositorio.ipen.br/bitstream/123456789/29123/2/license.txt
bitstream.checksum.fl_str_mv f4ad648f13ff89656d8daab2e343ebb3
8a4605be74aa9ea9d79846c1fba20a33
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
repository.name.fl_str_mv Repositório Institucional do IPEN - Instituto de Pesquisas Energéticas e Nucleares (IPEN)
repository.mail.fl_str_mv bibl@ipen.br
_version_ 1767254245880365056