Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo de conferência |
Título da fonte: | Repositório Institucional do IPEN |
Texto Completo: | http://repositorio.ipen.br/handle/123456789/27229 |
Resumo: | This work concerns the study of the effect of discarded bond paper on the thermal behavior of the polypropylene/organophilic clay nanocomposite. A brown polycationic bentonite from state of Para??ba, Brazil, was treated industrially with sodium carbonate to transform it into a bentonite which swells in water and then treated with ammonium chloride hexadecyltrimethylammonium to turn it into a swellable organoclay in organic liquids. Polypropylene with 3% polypropylene graft compatibilizer (PP-g-AM) was mixed with 1% and 2% by weight of discarded bond paper and with 1%, 2% e 5% by weight of organophilic clay using a twin-screw extruder. The specimens were prepared by the injection process. The nanocomposite specimens were characterized by XRD, SEM, and thermal analysis (ATG and DSC). The nanocomposites showed improved thermal properties compared with the polymer without filler. |
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IKHMAYIES, SHADIA J.LI, BOWENCARPENTER, JOHN S.HWANG, JIANN-YANGMONTEIRO, SERGIO N.LI, JIANFIRRAO, DONATOZHANG, MINGMINGPENG, ZHIWEIESCOBEDO-DIAZ, JUAN P.BAI, CHENGUANGFERMINO, DANILO M.ANDRADE, CHRISTIANO G.B.PARRA, DUCLERC F.LUGAO, ADEMAR B.VALENZUELA DIAZ, FRANCISCO R.TMS ANNUAL MEETING & EXHIBITION, 145th; CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS2017-03-21T10:57:59Z2017-03-21T10:57:59ZFebruary 14-18, 2016http://repositorio.ipen.br/handle/123456789/27229This work concerns the study of the effect of discarded bond paper on the thermal behavior of the polypropylene/organophilic clay nanocomposite. A brown polycationic bentonite from state of Para??ba, Brazil, was treated industrially with sodium carbonate to transform it into a bentonite which swells in water and then treated with ammonium chloride hexadecyltrimethylammonium to turn it into a swellable organoclay in organic liquids. Polypropylene with 3% polypropylene graft compatibilizer (PP-g-AM) was mixed with 1% and 2% by weight of discarded bond paper and with 1%, 2% e 5% by weight of organophilic clay using a twin-screw extruder. The specimens were prepared by the injection process. The nanocomposite specimens were characterized by XRD, SEM, and thermal analysis (ATG and DSC). The nanocomposites showed improved thermal properties compared with the polymer without filler.Submitted by Marco Antonio Oliveira da Silva (maosilva@ipen.br) on 2017-03-21T10:57:59Z No. of bitstreams: 1 23648.pdf: 1955750 bytes, checksum: 6080a4eb687ade83cfdd34d0c6f0bd4b (MD5)Made available in DSpace on 2017-03-21T10:57:59Z (GMT). No. of bitstreams: 1 23648.pdf: 1955750 bytes, checksum: 6080a4eb687ade83cfdd34d0c6f0bd4b (MD5)241-248Hoboken, New Jersey: John Wiley & Sons, Inc.Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paperinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectINashville, Tennessee, USAinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional do IPENinstname:Instituto de Pesquisas Energéticas e Nucleares (IPEN)instacron:IPEN236482016PARRA, DUCLERC F.LUGAO, ADEMAR B.17-03Proceedings562339PARRA, DUCLERC F.:562:-1:NLUGAO, ADEMAR B.:339:-1:NORIGINAL23648.pdf23648.pdfapplication/pdf1955750http://repositorio.ipen.br/bitstream/123456789/27229/1/23648.pdf6080a4eb687ade83cfdd34d0c6f0bd4bMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.ipen.br/bitstream/123456789/27229/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52123456789/272292020-08-20 19:12:41.42oai:repositorio.ipen.br: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Repositório InstitucionalPUBhttp://repositorio.ipen.br/oai/requestbibl@ipen.bropendoar:45102020-08-20T19:12:41Repositório Institucional do IPEN - Instituto de Pesquisas Energéticas e Nucleares (IPEN)false |
dc.title.pt_BR.fl_str_mv |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper |
title |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper |
spellingShingle |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper FERMINO, DANILO M. |
title_short |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper |
title_full |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper |
title_fullStr |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper |
title_full_unstemmed |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper |
title_sort |
Thermal properties of polypropylene nanocomposites with organoclay and discarded bond paper |
author |
FERMINO, DANILO M. |
author_facet |
FERMINO, DANILO M. ANDRADE, CHRISTIANO G.B. PARRA, DUCLERC F. LUGAO, ADEMAR B. VALENZUELA DIAZ, FRANCISCO R. TMS ANNUAL MEETING & EXHIBITION, 145th; CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS |
author_role |
author |
author2 |
ANDRADE, CHRISTIANO G.B. PARRA, DUCLERC F. LUGAO, ADEMAR B. VALENZUELA DIAZ, FRANCISCO R. TMS ANNUAL MEETING & EXHIBITION, 145th; CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS |
author2_role |
author author author author author |
dc.contributor.editor.none.fl_str_mv |
IKHMAYIES, SHADIA J. LI, BOWEN CARPENTER, JOHN S. HWANG, JIANN-YANG MONTEIRO, SERGIO N. LI, JIAN FIRRAO, DONATO ZHANG, MINGMING PENG, ZHIWEI ESCOBEDO-DIAZ, JUAN P. BAI, CHENGUANG |
dc.contributor.author.fl_str_mv |
FERMINO, DANILO M. ANDRADE, CHRISTIANO G.B. PARRA, DUCLERC F. LUGAO, ADEMAR B. VALENZUELA DIAZ, FRANCISCO R. TMS ANNUAL MEETING & EXHIBITION, 145th; CHARACTERIZATION OF MINERALS, METALS, AND MATERIALS |
description |
This work concerns the study of the effect of discarded bond paper on the thermal behavior of the polypropylene/organophilic clay nanocomposite. A brown polycationic bentonite from state of Para??ba, Brazil, was treated industrially with sodium carbonate to transform it into a bentonite which swells in water and then treated with ammonium chloride hexadecyltrimethylammonium to turn it into a swellable organoclay in organic liquids. Polypropylene with 3% polypropylene graft compatibilizer (PP-g-AM) was mixed with 1% and 2% by weight of discarded bond paper and with 1%, 2% e 5% by weight of organophilic clay using a twin-screw extruder. The specimens were prepared by the injection process. The nanocomposite specimens were characterized by XRD, SEM, and thermal analysis (ATG and DSC). The nanocomposites showed improved thermal properties compared with the polymer without filler. |
publishDate |
2017 |
dc.date.evento.pt_BR.fl_str_mv |
February 14-18, 2016 |
dc.date.accessioned.fl_str_mv |
2017-03-21T10:57:59Z |
dc.date.available.fl_str_mv |
2017-03-21T10:57:59Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/conferenceObject |
format |
conferenceObject |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://repositorio.ipen.br/handle/123456789/27229 |
url |
http://repositorio.ipen.br/handle/123456789/27229 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
241-248 |
dc.coverage.pt_BR.fl_str_mv |
I |
dc.publisher.none.fl_str_mv |
Hoboken, New Jersey: John Wiley & Sons, Inc. |
publisher.none.fl_str_mv |
Hoboken, New Jersey: John Wiley & Sons, Inc. |
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reponame:Repositório Institucional do IPEN instname:Instituto de Pesquisas Energéticas e Nucleares (IPEN) instacron:IPEN |
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IPEN |
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Repositório Institucional do IPEN |
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Repositório Institucional do IPEN - Instituto de Pesquisas Energéticas e Nucleares (IPEN) |
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