Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate
Autor(a) principal: | |
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Data de Publicação: | 2011 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.26/21982 |
Resumo: | The title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4'-di-tert-butyl-2,2'-bipyridine). A -oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and -oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C-HO and C-HCl interactions are present. |
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7160 |
spelling |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrateThe title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4'-di-tert-butyl-2,2'-bipyridine). A -oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and -oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C-HO and C-HCl interactions are present.Repositório ComumGomes, A. C.Fernandes, J. A.Gamelas ou Carla A. Gamelas, CarlaGonçalves, I. S.Almeida-Paz, F. A.2018-03-13T14:54:57Z20112011-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.26/21982engGomes, A., Fernandes, J., Gamelas, C., Gonçalves, I. & Almeida-Paz, F. (2011). Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate. Acta Crystallographica Section E: Structure Reports Online, 67 (12), m1738-m1739. doi: 10.1107/S160053681104695210.1107/S1600536811046952info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-21T09:53:30Zoai:comum.rcaap.pt:10400.26/21982Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T23:09:22.979503Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate |
title |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate |
spellingShingle |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate Gomes, A. C. |
title_short |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate |
title_full |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate |
title_fullStr |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate |
title_full_unstemmed |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate |
title_sort |
Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate |
author |
Gomes, A. C. |
author_facet |
Gomes, A. C. Fernandes, J. A. Gamelas ou Carla A. Gamelas, Carla Gonçalves, I. S. Almeida-Paz, F. A. |
author_role |
author |
author2 |
Fernandes, J. A. Gamelas ou Carla A. Gamelas, Carla Gonçalves, I. S. Almeida-Paz, F. A. |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Repositório Comum |
dc.contributor.author.fl_str_mv |
Gomes, A. C. Fernandes, J. A. Gamelas ou Carla A. Gamelas, Carla Gonçalves, I. S. Almeida-Paz, F. A. |
description |
The title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4'-di-tert-butyl-2,2'-bipyridine). A -oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and -oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C-HO and C-HCl interactions are present. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011 2011-01-01T00:00:00Z 2018-03-13T14:54:57Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.26/21982 |
url |
http://hdl.handle.net/10400.26/21982 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Gomes, A., Fernandes, J., Gamelas, C., Gonçalves, I. & Almeida-Paz, F. (2011). Oxido-bis¬[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-2N,N')dioxido¬molybdenum(VI)] 0.2-hydrate. Acta Crystallographica Section E: Structure Reports Online, 67 (12), m1738-m1739. doi: 10.1107/S1600536811046952 10.1107/S1600536811046952 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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