Gasification of carbon deposited on supported Ni-Cu catalysts

Detalhes bibliográficos
Autor(a) principal: Tavares, M. T.
Data de Publicação: 1986
Outros Autores: Bernardo, C. A., Figueiredo, J. L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/5534
Resumo: The activity of supported Ni-Cu alloy catalysts in the gasification of carbon was studied for a range of copper concentrations. Deposits formed from the decomposition of methane under constant and well-defined conditions were gasified by hydrogen and hydrogen-steam mixtures. The kinetics of hydrogasification were determined under such conditions that the reaction rates did not depend on the extent of carbon burn-off. Comparison of the different catalysts indicates that, similarly to previous results for the decomposition, an ensemble of surface nickel atoms plays a role in the gasification.
id RCAP_070ac9120706172ba49fb19f6db0238a
oai_identifier_str oai:repositorium.sdum.uminho.pt:1822/5534
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling Gasification of carbon deposited on supported Ni-Cu catalystsGasification of carbonCatalystSurface depositionScience & TechnologyThe activity of supported Ni-Cu alloy catalysts in the gasification of carbon was studied for a range of copper concentrations. Deposits formed from the decomposition of methane under constant and well-defined conditions were gasified by hydrogen and hydrogen-steam mixtures. The kinetics of hydrogasification were determined under such conditions that the reaction rates did not depend on the extent of carbon burn-off. Comparison of the different catalysts indicates that, similarly to previous results for the decomposition, an ensemble of surface nickel atoms plays a role in the gasification.North Atlantic Treaty Organization (NATO) - Research Grant.ElsevierUniversidade do MinhoTavares, M. T.Bernardo, C. A.Figueiredo, J. L.1986-101986-10-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/5534eng"Fuel". ISSN 0016-2361. 65:10 (1986) 1392-1395.0016-236110.1016/0016-2361(86)90111-0http://www.elsevier.com/wps/find/journaldescription.cws_home/30420/description#descriptioninfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:27:29Zoai:repositorium.sdum.uminho.pt:1822/5534Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:22:05.197728Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Gasification of carbon deposited on supported Ni-Cu catalysts
title Gasification of carbon deposited on supported Ni-Cu catalysts
spellingShingle Gasification of carbon deposited on supported Ni-Cu catalysts
Tavares, M. T.
Gasification of carbon
Catalyst
Surface deposition
Science & Technology
title_short Gasification of carbon deposited on supported Ni-Cu catalysts
title_full Gasification of carbon deposited on supported Ni-Cu catalysts
title_fullStr Gasification of carbon deposited on supported Ni-Cu catalysts
title_full_unstemmed Gasification of carbon deposited on supported Ni-Cu catalysts
title_sort Gasification of carbon deposited on supported Ni-Cu catalysts
author Tavares, M. T.
author_facet Tavares, M. T.
Bernardo, C. A.
Figueiredo, J. L.
author_role author
author2 Bernardo, C. A.
Figueiredo, J. L.
author2_role author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Tavares, M. T.
Bernardo, C. A.
Figueiredo, J. L.
dc.subject.por.fl_str_mv Gasification of carbon
Catalyst
Surface deposition
Science & Technology
topic Gasification of carbon
Catalyst
Surface deposition
Science & Technology
description The activity of supported Ni-Cu alloy catalysts in the gasification of carbon was studied for a range of copper concentrations. Deposits formed from the decomposition of methane under constant and well-defined conditions were gasified by hydrogen and hydrogen-steam mixtures. The kinetics of hydrogasification were determined under such conditions that the reaction rates did not depend on the extent of carbon burn-off. Comparison of the different catalysts indicates that, similarly to previous results for the decomposition, an ensemble of surface nickel atoms plays a role in the gasification.
publishDate 1986
dc.date.none.fl_str_mv 1986-10
1986-10-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/5534
url http://hdl.handle.net/1822/5534
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv "Fuel". ISSN 0016-2361. 65:10 (1986) 1392-1395.
0016-2361
10.1016/0016-2361(86)90111-0
http://www.elsevier.com/wps/find/journaldescription.cws_home/30420/description#description
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799132689990680576