Alkali-activated binders produced from petrochemical fluid catalytic cracking catalyst waste

• Autor(a) principal: Costa, Carla
• Data de Publicação: 2014
• Outros Autores: Ferreira, Cátia, Ribeiro, Maria Filipa, Fernandes, Auguste
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: http://hdl.handle.net/10400.21/11743
• topic: Alkali-activated binders; Waste FCC catalyst; Mechanical strength; FTIR; XRD

This paper describes research on the viability of producing alkali activated binders using the aluminosilicate catalyst waste-generated by the fluid catalytic cracking (wFCC) unit in the Portuguese oil refinery company-as precursor. For this purpose, alkali-activated wFCC catalyst based mortars and cement pastes were produced. Tests were carried out to evaluate the effect of initial solids composition (wFCC catalyst/Ca(OH) 2 ratio) on mortars workability or mechanical strength. The mineralogy and microstructure of the hardened alkali activated wFCC catalyst pastes were studied by means of Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The results obtained at macroscale showed that the content of Ca(OH) 2 incorporated in the binder has a significant effect on compressive strength of hardened mortars. At microscale, FTIR and XRD results confirmed the occurrence of alkali-activation of the wFCC catalyst which leads to the formation of distinctive amorphous and crystalline products. Moreover, the obtained results also suggest that initial solids composition influences the alkali-activation reaction kinetics and mechanism.