Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | https://hdl.handle.net/1822/59955 |
Resumo: | A cost-effective solution to provide asphalt pavements with the photocatalytic property was addressed for the first time, based on the combination of low percentages of two semiconductors, TiO2and ZnO. Two photocatalytic techniques – spray deposition and bitumen modification – were used. With the former, the chemical properties were evaluated by FTIR after spraying the bitumen samples with two aqueous solutions, one with acid PH and another alkaline, of nano-TiO2. The solution with less chemical impact was the alkaline one. With the latter, Penetration, Softening Point, Mass Loss, Dynamic Viscosity, Complex moduli and Performance Grade, after the modification by TiO2nano/microparticles and ZnO microparticles, were analysed with two levels of ageing produced by the RTFOT. TiO2nano/microparticles and ZnO microparticles conducted to softer bitumens and better results of short-term ageing resistance and did not cause any deterioration to the bitumen before or after either short- or long-term ageing. |
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Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumenbitumen modificationfunctionalisationnanomaterialsphotocatalysisTiO 2ZnOScience & TechnologyA cost-effective solution to provide asphalt pavements with the photocatalytic property was addressed for the first time, based on the combination of low percentages of two semiconductors, TiO2and ZnO. Two photocatalytic techniques – spray deposition and bitumen modification – were used. With the former, the chemical properties were evaluated by FTIR after spraying the bitumen samples with two aqueous solutions, one with acid PH and another alkaline, of nano-TiO2. The solution with less chemical impact was the alkaline one. With the latter, Penetration, Softening Point, Mass Loss, Dynamic Viscosity, Complex moduli and Performance Grade, after the modification by TiO2nano/microparticles and ZnO microparticles, were analysed with two levels of ageing produced by the RTFOT. TiO2nano/microparticles and ZnO microparticles conducted to softer bitumens and better results of short-term ageing resistance and did not cause any deterioration to the bitumen before or after either short- or long-term ageing.This work was partially financed by FCT – Fundação para a Ciência e a Tecnologia – under the project PTDC/FIS/120412/2010: ‘Nanobased concepts for Innovative & Eco-sustainable constructive material’s surfaces’ and project PEst-OE/ECI/UI4047/2014.Taylor & FrancisUniversidade do MinhoRocha Segundo, Iran Gomes daDias, Elisa Alexandra LagesFernandes, Filipa Daniela PereiraFreitas, E. F.Costa, Manuel F. M.Carneiro, Joaquim A. O.20192019-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/59955eng1468-062910.1080/14680629.2018.1453371info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-12-30T01:28:05Zoai:repositorium.sdum.uminho.pt:1822/59955Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:47:43.946263Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen |
title |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen |
spellingShingle |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen Rocha Segundo, Iran Gomes da bitumen modification functionalisation nanomaterials photocatalysis TiO 2 ZnO Science & Technology |
title_short |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen |
title_full |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen |
title_fullStr |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen |
title_full_unstemmed |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen |
title_sort |
Photocatalytic asphalt pavement: the physicochemical and rheological impact of TiO2 nano/microparticles and ZnO microparticles onto the bitumen |
author |
Rocha Segundo, Iran Gomes da |
author_facet |
Rocha Segundo, Iran Gomes da Dias, Elisa Alexandra Lages Fernandes, Filipa Daniela Pereira Freitas, E. F. Costa, Manuel F. M. Carneiro, Joaquim A. O. |
author_role |
author |
author2 |
Dias, Elisa Alexandra Lages Fernandes, Filipa Daniela Pereira Freitas, E. F. Costa, Manuel F. M. Carneiro, Joaquim A. O. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Rocha Segundo, Iran Gomes da Dias, Elisa Alexandra Lages Fernandes, Filipa Daniela Pereira Freitas, E. F. Costa, Manuel F. M. Carneiro, Joaquim A. O. |
dc.subject.por.fl_str_mv |
bitumen modification functionalisation nanomaterials photocatalysis TiO 2 ZnO Science & Technology |
topic |
bitumen modification functionalisation nanomaterials photocatalysis TiO 2 ZnO Science & Technology |
description |
A cost-effective solution to provide asphalt pavements with the photocatalytic property was addressed for the first time, based on the combination of low percentages of two semiconductors, TiO2and ZnO. Two photocatalytic techniques – spray deposition and bitumen modification – were used. With the former, the chemical properties were evaluated by FTIR after spraying the bitumen samples with two aqueous solutions, one with acid PH and another alkaline, of nano-TiO2. The solution with less chemical impact was the alkaline one. With the latter, Penetration, Softening Point, Mass Loss, Dynamic Viscosity, Complex moduli and Performance Grade, after the modification by TiO2nano/microparticles and ZnO microparticles, were analysed with two levels of ageing produced by the RTFOT. TiO2nano/microparticles and ZnO microparticles conducted to softer bitumens and better results of short-term ageing resistance and did not cause any deterioration to the bitumen before or after either short- or long-term ageing. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019 2019-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/1822/59955 |
url |
https://hdl.handle.net/1822/59955 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1468-0629 10.1080/14680629.2018.1453371 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Taylor & Francis |
publisher.none.fl_str_mv |
Taylor & Francis |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799133052083896320 |