Novel biocompatible ionic liquids based on gluconate anion

Detalhes bibliográficos
Autor(a) principal: Costa, Alexandra
Data de Publicação: 2015
Outros Autores: Forte, Andreia, Zalewska, Karolina, Tiago, Gonçalo, Petrovski, Zeljko, Branco, Luís C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: https://doi.org/10.1080/17518253.2014.951695
Resumo: A sustainable organic synthetic methodology for the preparation of novel biocompatible ionic liquids (ILs) based on gluconate anion has been developed. Four functionalized methylimidazolium cations were efficiently combined with gluconic acid by acid-base neutralization reactions. All salts were obtained as RTILs in high yields (92–98%) and in high purity levels. Proton Nuclear Magnetic Resonance (1H NMR) studies had proved the correct cation/ anion proportion (1:1) and their chemical stability. These novel gluconate ILs can be applied for chemistry, material science, and medicine areas.
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spelling Novel biocompatible ionic liquids based on gluconate anionBiocompatibleGluconateIonic liquidsChemistry(all)Environmental ChemistryA sustainable organic synthetic methodology for the preparation of novel biocompatible ionic liquids (ILs) based on gluconate anion has been developed. Four functionalized methylimidazolium cations were efficiently combined with gluconic acid by acid-base neutralization reactions. All salts were obtained as RTILs in high yields (92–98%) and in high purity levels. Proton Nuclear Magnetic Resonance (1H NMR) studies had proved the correct cation/ anion proportion (1:1) and their chemical stability. These novel gluconate ILs can be applied for chemistry, material science, and medicine areas.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNCosta, AlexandraForte, AndreiaZalewska, KarolinaTiago, GonçaloPetrovski, ZeljkoBranco, Luís C.2017-09-04T22:02:46Z2015-01-012015-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article5application/pdfhttps://doi.org/10.1080/17518253.2014.951695eng1751-8253PURE: 2903674http://www.scopus.com/inward/record.url?scp=84926136426&partnerID=8YFLogxKhttps://doi.org/10.1080/17518253.2014.951695info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T17:27:30Zoai:run.unl.pt:10362/23063Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T17:27:30Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Novel biocompatible ionic liquids based on gluconate anion
title Novel biocompatible ionic liquids based on gluconate anion
spellingShingle Novel biocompatible ionic liquids based on gluconate anion
Costa, Alexandra
Biocompatible
Gluconate
Ionic liquids
Chemistry(all)
Environmental Chemistry
title_short Novel biocompatible ionic liquids based on gluconate anion
title_full Novel biocompatible ionic liquids based on gluconate anion
title_fullStr Novel biocompatible ionic liquids based on gluconate anion
title_full_unstemmed Novel biocompatible ionic liquids based on gluconate anion
title_sort Novel biocompatible ionic liquids based on gluconate anion
author Costa, Alexandra
author_facet Costa, Alexandra
Forte, Andreia
Zalewska, Karolina
Tiago, Gonçalo
Petrovski, Zeljko
Branco, Luís C.
author_role author
author2 Forte, Andreia
Zalewska, Karolina
Tiago, Gonçalo
Petrovski, Zeljko
Branco, Luís C.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Costa, Alexandra
Forte, Andreia
Zalewska, Karolina
Tiago, Gonçalo
Petrovski, Zeljko
Branco, Luís C.
dc.subject.por.fl_str_mv Biocompatible
Gluconate
Ionic liquids
Chemistry(all)
Environmental Chemistry
topic Biocompatible
Gluconate
Ionic liquids
Chemistry(all)
Environmental Chemistry
description A sustainable organic synthetic methodology for the preparation of novel biocompatible ionic liquids (ILs) based on gluconate anion has been developed. Four functionalized methylimidazolium cations were efficiently combined with gluconic acid by acid-base neutralization reactions. All salts were obtained as RTILs in high yields (92–98%) and in high purity levels. Proton Nuclear Magnetic Resonance (1H NMR) studies had proved the correct cation/ anion proportion (1:1) and their chemical stability. These novel gluconate ILs can be applied for chemistry, material science, and medicine areas.
publishDate 2015
dc.date.none.fl_str_mv 2015-01-01
2015-01-01T00:00:00Z
2017-09-04T22:02:46Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://doi.org/10.1080/17518253.2014.951695
url https://doi.org/10.1080/17518253.2014.951695
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1751-8253
PURE: 2903674
http://www.scopus.com/inward/record.url?scp=84926136426&partnerID=8YFLogxK
https://doi.org/10.1080/17518253.2014.951695
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 5
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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