Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes

Detalhes bibliográficos
Autor(a) principal: Alves, M. José
Data de Publicação: 2005
Outros Autores: Fortes, A. Gil, Lemos, Américo, Martins, Cristina I.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/3419
Resumo: Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate, the first example of an 3-heteroamatic-2H-azirine, was prepared and its reaction with conjugated 1,3-dienes, under mild conditions and in the absence of Lewis acid catalyst, produced cycloadducts in good yield and high stereoselectivity.
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spelling Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes3-heteroaromatic-2H-azirineHetero Diels-AlderNeber reaction3-heteroaromatic-2H-azirineshetero Diels-Alder reactionScience & TechnologyEthyl 3-(2-pyridyl)-2H-azirine-2-carboxylate, the first example of an 3-heteroamatic-2H-azirine, was prepared and its reaction with conjugated 1,3-dienes, under mild conditions and in the absence of Lewis acid catalyst, produced cycloadducts in good yield and high stereoselectivity.Fundação para a Ciência e Tecnologia. FEDER - POCTI/QUI/32723/2000.Thieme Medical PublishersUniversidade do MinhoAlves, M. JoséFortes, A. GilLemos, AméricoMartins, Cristina I.20052005-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/3419eng"Synthesis". ISSN 0039-7881. 4 (2005) 555-558.0039-78811437-210x10.1055/s-2004-837296http://www.thieme-connect.com/ejournals/toc/synthesis/3912info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:03:12Zoai:repositorium.sdum.uminho.pt:1822/3419Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:53:17.550291Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
title Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
spellingShingle Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
Alves, M. José
3-heteroaromatic-2H-azirine
Hetero Diels-Alder
Neber reaction
3-heteroaromatic-2H-azirines
hetero Diels-Alder reaction
Science & Technology
title_short Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
title_full Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
title_fullStr Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
title_full_unstemmed Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
title_sort Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate : synthesis and reactivity with dienes
author Alves, M. José
author_facet Alves, M. José
Fortes, A. Gil
Lemos, Américo
Martins, Cristina I.
author_role author
author2 Fortes, A. Gil
Lemos, Américo
Martins, Cristina I.
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Alves, M. José
Fortes, A. Gil
Lemos, Américo
Martins, Cristina I.
dc.subject.por.fl_str_mv 3-heteroaromatic-2H-azirine
Hetero Diels-Alder
Neber reaction
3-heteroaromatic-2H-azirines
hetero Diels-Alder reaction
Science & Technology
topic 3-heteroaromatic-2H-azirine
Hetero Diels-Alder
Neber reaction
3-heteroaromatic-2H-azirines
hetero Diels-Alder reaction
Science & Technology
description Ethyl 3-(2-pyridyl)-2H-azirine-2-carboxylate, the first example of an 3-heteroamatic-2H-azirine, was prepared and its reaction with conjugated 1,3-dienes, under mild conditions and in the absence of Lewis acid catalyst, produced cycloadducts in good yield and high stereoselectivity.
publishDate 2005
dc.date.none.fl_str_mv 2005
2005-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/3419
url http://hdl.handle.net/1822/3419
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv "Synthesis". ISSN 0039-7881. 4 (2005) 555-558.
0039-7881
1437-210x
10.1055/s-2004-837296
http://www.thieme-connect.com/ejournals/toc/synthesis/3912
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Thieme Medical Publishers
publisher.none.fl_str_mv Thieme Medical Publishers
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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