Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates

Detalhes bibliográficos
Autor(a) principal: Rodrigues, Goncalo da Cunha
Data de Publicação: 2015
Outros Autores: Zelenovskiy, Pavel, Romanyuk, Konstantin, Luchkin, Sergey, Kopelevich, Yakov, Kholkin, Andrei
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10773/19741
Resumo: Electromechanical response of materials is a key property for various applications ranging from actuators to sophisticated nanoelectromechanical systems. Here electromechanical properties of the single-layer graphene transferred onto SiO2 calibration grating substrates is studied via piezoresponse force microscopy and confocal Raman spectroscopy. The correlation of mechanical strains in graphene layer with the substrate morphology is established via Raman mapping. Apparent vertical piezoresponse from the single-layer graphene supported by underlying SiO2 structure is observed by piezoresponse force microscopy. The calculated vertical piezocoefficient is about 1.4 nm V-1, that is, much higher than that of the conventional piezoelectric materials such as lead zirconate titanate and comparable to that of relaxor single crystals. The observed piezoresponse and achieved strain in graphene are associated with the chemical interaction of graphene's carbon atoms with the oxygen from underlying SiO2. The results provide a basis for future applications of graphene layers for sensing, actuating and energy harvesting.
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spelling Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substratesMONOLAYER GRAPHENESTRAINElectromechanical response of materials is a key property for various applications ranging from actuators to sophisticated nanoelectromechanical systems. Here electromechanical properties of the single-layer graphene transferred onto SiO2 calibration grating substrates is studied via piezoresponse force microscopy and confocal Raman spectroscopy. The correlation of mechanical strains in graphene layer with the substrate morphology is established via Raman mapping. Apparent vertical piezoresponse from the single-layer graphene supported by underlying SiO2 structure is observed by piezoresponse force microscopy. The calculated vertical piezocoefficient is about 1.4 nm V-1, that is, much higher than that of the conventional piezoelectric materials such as lead zirconate titanate and comparable to that of relaxor single crystals. The observed piezoresponse and achieved strain in graphene are associated with the chemical interaction of graphene's carbon atoms with the oxygen from underlying SiO2. The results provide a basis for future applications of graphene layers for sensing, actuating and energy harvesting.NATURE PUBLISHING GROUP2017-12-07T19:23:17Z2015-01-01T00:00:00Z2015info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/19741eng2041-172310.1038/ncomms8572Rodrigues, Goncalo da CunhaZelenovskiy, PavelRomanyuk, KonstantinLuchkin, SergeyKopelevich, YakovKholkin, Andreiinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T11:38:27Zoai:ria.ua.pt:10773/19741Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:54:29.273035Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
title Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
spellingShingle Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
Rodrigues, Goncalo da Cunha
MONOLAYER GRAPHENE
STRAIN
title_short Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
title_full Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
title_fullStr Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
title_full_unstemmed Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
title_sort Strong piezoelectricity in single-layer graphene deposited on SiO2 grating substrates
author Rodrigues, Goncalo da Cunha
author_facet Rodrigues, Goncalo da Cunha
Zelenovskiy, Pavel
Romanyuk, Konstantin
Luchkin, Sergey
Kopelevich, Yakov
Kholkin, Andrei
author_role author
author2 Zelenovskiy, Pavel
Romanyuk, Konstantin
Luchkin, Sergey
Kopelevich, Yakov
Kholkin, Andrei
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Rodrigues, Goncalo da Cunha
Zelenovskiy, Pavel
Romanyuk, Konstantin
Luchkin, Sergey
Kopelevich, Yakov
Kholkin, Andrei
dc.subject.por.fl_str_mv MONOLAYER GRAPHENE
STRAIN
topic MONOLAYER GRAPHENE
STRAIN
description Electromechanical response of materials is a key property for various applications ranging from actuators to sophisticated nanoelectromechanical systems. Here electromechanical properties of the single-layer graphene transferred onto SiO2 calibration grating substrates is studied via piezoresponse force microscopy and confocal Raman spectroscopy. The correlation of mechanical strains in graphene layer with the substrate morphology is established via Raman mapping. Apparent vertical piezoresponse from the single-layer graphene supported by underlying SiO2 structure is observed by piezoresponse force microscopy. The calculated vertical piezocoefficient is about 1.4 nm V-1, that is, much higher than that of the conventional piezoelectric materials such as lead zirconate titanate and comparable to that of relaxor single crystals. The observed piezoresponse and achieved strain in graphene are associated with the chemical interaction of graphene's carbon atoms with the oxygen from underlying SiO2. The results provide a basis for future applications of graphene layers for sensing, actuating and energy harvesting.
publishDate 2015
dc.date.none.fl_str_mv 2015-01-01T00:00:00Z
2015
2017-12-07T19:23:17Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10773/19741
url http://hdl.handle.net/10773/19741
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2041-1723
10.1038/ncomms8572
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv NATURE PUBLISHING GROUP
publisher.none.fl_str_mv NATURE PUBLISHING GROUP
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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