Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.1/13692 |
Resumo: | In this work, non-derivatized cellulose pulp was dissolved in a cold alkali solution (LiOH/urea) and chemically cross-linked with methylenebisacrylamide (MBA) to form a robust hydrogel with superior water absorption properties. Different cellulose concentrations (i.e., 2, 3 and 4 wt%) and MBA/glucose molar ratios (i.e., 0.26, 0.53 and 1.05) were tested. The cellulose hydrogel cured at 60 °C for 30 min, with a MBA/glucose molar ratio of 1.05, exhibited the highest water swelling capacity absorbing ca. 220 g H2O/g dry hydrogel. Moreover, the data suggest that the cross-linking occurs via a basic Michael addition mechanism. This innovative procedure based on the direct dissolution of unmodified cellulose in LiOH/urea followed by MBA cross-linking provides a simple and fast approach to prepare chemically cross-linked non-derivatized high-molecular-weight cellulose hydrogels with superior water uptake capacity. |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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7160 |
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Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/ureaLiOH/ureaMichael additionMethylenebisacrylamideCellulose hydrogelIn this work, non-derivatized cellulose pulp was dissolved in a cold alkali solution (LiOH/urea) and chemically cross-linked with methylenebisacrylamide (MBA) to form a robust hydrogel with superior water absorption properties. Different cellulose concentrations (i.e., 2, 3 and 4 wt%) and MBA/glucose molar ratios (i.e., 0.26, 0.53 and 1.05) were tested. The cellulose hydrogel cured at 60 °C for 30 min, with a MBA/glucose molar ratio of 1.05, exhibited the highest water swelling capacity absorbing ca. 220 g H2O/g dry hydrogel. Moreover, the data suggest that the cross-linking occurs via a basic Michael addition mechanism. This innovative procedure based on the direct dissolution of unmodified cellulose in LiOH/urea followed by MBA cross-linking provides a simple and fast approach to prepare chemically cross-linked non-derivatized high-molecular-weight cellulose hydrogels with superior water uptake capacity.Portuguese Foundation for Science and Technology, FCT, via the projects PTDC/AGR-TEC/4814/2014, PTDC/ASP-SIL/30619/2017 and UIDB/05183/2020, and the research grant IF/01005/2014.MDPISapientiaYang, JiayiMedronho, BrunoLindman, BjörnNorgren, Magnus2020-04-06T09:59:35Z2020-022020-02-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.1/13692eng2073-436010.3390/polym12020373info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-24T10:25:52Zoai:sapientia.ualg.pt:10400.1/13692Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:04:49.738984Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea |
title |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea |
spellingShingle |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea Yang, Jiayi LiOH/urea Michael addition Methylenebisacrylamide Cellulose hydrogel |
title_short |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea |
title_full |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea |
title_fullStr |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea |
title_full_unstemmed |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea |
title_sort |
Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea |
author |
Yang, Jiayi |
author_facet |
Yang, Jiayi Medronho, Bruno Lindman, Björn Norgren, Magnus |
author_role |
author |
author2 |
Medronho, Bruno Lindman, Björn Norgren, Magnus |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Sapientia |
dc.contributor.author.fl_str_mv |
Yang, Jiayi Medronho, Bruno Lindman, Björn Norgren, Magnus |
dc.subject.por.fl_str_mv |
LiOH/urea Michael addition Methylenebisacrylamide Cellulose hydrogel |
topic |
LiOH/urea Michael addition Methylenebisacrylamide Cellulose hydrogel |
description |
In this work, non-derivatized cellulose pulp was dissolved in a cold alkali solution (LiOH/urea) and chemically cross-linked with methylenebisacrylamide (MBA) to form a robust hydrogel with superior water absorption properties. Different cellulose concentrations (i.e., 2, 3 and 4 wt%) and MBA/glucose molar ratios (i.e., 0.26, 0.53 and 1.05) were tested. The cellulose hydrogel cured at 60 °C for 30 min, with a MBA/glucose molar ratio of 1.05, exhibited the highest water swelling capacity absorbing ca. 220 g H2O/g dry hydrogel. Moreover, the data suggest that the cross-linking occurs via a basic Michael addition mechanism. This innovative procedure based on the direct dissolution of unmodified cellulose in LiOH/urea followed by MBA cross-linking provides a simple and fast approach to prepare chemically cross-linked non-derivatized high-molecular-weight cellulose hydrogels with superior water uptake capacity. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-04-06T09:59:35Z 2020-02 2020-02-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.1/13692 |
url |
http://hdl.handle.net/10400.1/13692 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2073-4360 10.3390/polym12020373 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799133286529761280 |