Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents

Detalhes bibliográficos
Autor(a) principal: Vladić, Jelena
Data de Publicação: 2023
Outros Autores: Kovačević, Strahinja, Aladić, Krunoslav, Rebocho, Sílvia, Jokić, Stela, Podunavac-Kuzmanović, Sanja, Duarte, Ana Rita C., Jerković, Igor
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/164440
Resumo: Funding Information: Open access funding provided by FCT|FCCN (b-on). This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 101003396. Publisher Copyright: © 2023, The Author(s).
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spelling Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green SolventsAroma stabilizationGreen solventsNatural deep eutectic solventsSupercritical COVolatile aroma compoundsFood ScienceSafety, Risk, Reliability and QualityProcess Chemistry and TechnologyIndustrial and Manufacturing EngineeringFunding Information: Open access funding provided by FCT|FCCN (b-on). This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 101003396. Publisher Copyright: © 2023, The Author(s).In this study, the integrated application of supercritical CO2 and natural deep eutectic solvents (NADES) was investigated in order to establish a green procedure that enables obtaining and stabilizing the aroma volatile constituents of Rosmarinus officinalis L. Supercritical CO2 was used to obtain rosemary extracts that possessed an abundance of terpenes, particularly monoterpenes 68.97–88.08% and sesquiterpenes 5.38–21.22%. The obtained extracts were further dispersed in different NADES (betaine/glycerol (Bet/Gly), betaine/ethylene glycol (Bet/EG), and betaine/glycerol/sucrose/water (Bet/Gly/Suc/W) and their stability was assessed at room temperature. The headspace profile of the samples and their antioxidant activity were monitored for 6 months. Changes in the chemical profile of the extract were detected, which corresponded to terpene transformation reactions. In the control (CO2 extract), the development of non-terpene components such as acetic acid was detected, which make the product unsuitable for use. Conversely, the accumulation of acetic acid was not observed in the NADES samples. The antioxidant activity of the control was the most significantly decreased during 6 months, while among the NADES samples, the reduction of activity occurred only in Bet/Gly sample. In Bet/EG and Bet/Gly/Suc/W samples, activity remained the same during the same period. The results suggest that the NADES could serve as stabilization media for CO2-extracted rosemary volatile components. Furthermore, this represents a simple, green process of obtaining readily applicable products with extended stability at room temperature.DQ - Departamento de QuímicaRUNVladić, JelenaKovačević, StrahinjaAladić, KrunoslavRebocho, SílviaJokić, StelaPodunavac-Kuzmanović, SanjaDuarte, Ana Rita C.Jerković, Igor2024-03-05T00:18:32Z2023-09-302023-09-30T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article16application/pdfhttp://hdl.handle.net/10362/164440eng1935-5130PURE: 84483795https://doi.org/10.1007/s11947-023-03188-winfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-18T01:43:59Zoai:run.unl.pt:10362/164440Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T04:00:10.712224Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
title Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
spellingShingle Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
Vladić, Jelena
Aroma stabilization
Green solvents
Natural deep eutectic solvents
Supercritical CO
Volatile aroma compounds
Food Science
Safety, Risk, Reliability and Quality
Process Chemistry and Technology
Industrial and Manufacturing Engineering
title_short Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
title_full Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
title_fullStr Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
title_full_unstemmed Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
title_sort Novel Insights Into the Recovery and Stabilization of Rosmarinus officinalis Volatile Aroma Compounds Using Green Solvents
author Vladić, Jelena
author_facet Vladić, Jelena
Kovačević, Strahinja
Aladić, Krunoslav
Rebocho, Sílvia
Jokić, Stela
Podunavac-Kuzmanović, Sanja
Duarte, Ana Rita C.
Jerković, Igor
author_role author
author2 Kovačević, Strahinja
Aladić, Krunoslav
Rebocho, Sílvia
Jokić, Stela
Podunavac-Kuzmanović, Sanja
Duarte, Ana Rita C.
Jerković, Igor
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Vladić, Jelena
Kovačević, Strahinja
Aladić, Krunoslav
Rebocho, Sílvia
Jokić, Stela
Podunavac-Kuzmanović, Sanja
Duarte, Ana Rita C.
Jerković, Igor
dc.subject.por.fl_str_mv Aroma stabilization
Green solvents
Natural deep eutectic solvents
Supercritical CO
Volatile aroma compounds
Food Science
Safety, Risk, Reliability and Quality
Process Chemistry and Technology
Industrial and Manufacturing Engineering
topic Aroma stabilization
Green solvents
Natural deep eutectic solvents
Supercritical CO
Volatile aroma compounds
Food Science
Safety, Risk, Reliability and Quality
Process Chemistry and Technology
Industrial and Manufacturing Engineering
description Funding Information: Open access funding provided by FCT|FCCN (b-on). This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 101003396. Publisher Copyright: © 2023, The Author(s).
publishDate 2023
dc.date.none.fl_str_mv 2023-09-30
2023-09-30T00:00:00Z
2024-03-05T00:18:32Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/164440
url http://hdl.handle.net/10362/164440
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1935-5130
PURE: 84483795
https://doi.org/10.1007/s11947-023-03188-w
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 16
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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