Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/143504 |
Resumo: | This work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under Grant Agreement No. 823989 “IONBIKE”. The financial supports received from CONICET and ANPCyT (Argentina) are also gratefully acknowledged. ). Publisher Copyright: © 2022 American Chemical Society. All rights reserved. |
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7160 |
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Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion ProtectorsCatechol chemistryCorrosion inhibitorsEutectic mixturesMetal-ligand coordinationPolyphenolsTissue adhesivesChemistry(all)Environmental ChemistryChemical Engineering(all)Renewable Energy, Sustainability and the EnvironmentSDG 7 - Affordable and Clean EnergyThis work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under Grant Agreement No. 823989 “IONBIKE”. The financial supports received from CONICET and ANPCyT (Argentina) are also gratefully acknowledged. ). Publisher Copyright: © 2022 American Chemical Society. All rights reserved.Natural deep eutectics solvents (NADES), owing to their high solvation capacity and nontoxicity, are actively being sought for many technological applications. Herein, we report a series of novel NADES based on choline chloride and plant-derived polyphenols. Most of the obtained phenolic NADES have a wide liquid range and high thermal stability above 150 °C. Among them, small-sized polyphenols, like pyrogallol, vanillyl alcohol, or gentisic acid, lead to low-viscosity liquids with ionic conductivities in the order of 10-3S cm-1at room temperature. Interestingly, polyphenols possess valuable properties as therapeutic agents, antioxidants, adhesives, or redox-active compounds, among others. Thus, we evaluated the potential of these novel NADES for two applications: bioadhesives and corrosion protection. The mixture of choline chloride-vanillyl alcohol (2:3 mol ratio) and gelatin resulted in a highly adhesive viscoelastic liquid (adhesive stress ≈ 135 kPa), affording shear thinning behavior. Furthermore, choline chloride-tannic acid (20:1) showed an extraordinary ability to coordinate iron ions, reaching excellent corrosion inhibitive efficiencies in mild steel protection.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNPicchio, Matías L.Minudri, DanielaMantione, DanieleCriado-Gonzalez, MiryamGuzmán-González, GregorioSchmarsow, RuthMüller, Alejandro J.Tomé, Liliana C.Minari, Roque J.Mecerreyes, David2022-09-05T22:25:58Z2022-062022-06-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article8application/pdfhttp://hdl.handle.net/10362/143504eng2168-0485PURE: 46300276https://doi.org/10.1021/acssuschemeng.2c01976info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T18:04:51Zoai:run.unl.pt:10362/143504Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T18:04:51Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors |
title |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors |
spellingShingle |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors Picchio, Matías L. Catechol chemistry Corrosion inhibitors Eutectic mixtures Metal-ligand coordination Polyphenols Tissue adhesives Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 7 - Affordable and Clean Energy |
title_short |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors |
title_full |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors |
title_fullStr |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors |
title_full_unstemmed |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors |
title_sort |
Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors |
author |
Picchio, Matías L. |
author_facet |
Picchio, Matías L. Minudri, Daniela Mantione, Daniele Criado-Gonzalez, Miryam Guzmán-González, Gregorio Schmarsow, Ruth Müller, Alejandro J. Tomé, Liliana C. Minari, Roque J. Mecerreyes, David |
author_role |
author |
author2 |
Minudri, Daniela Mantione, Daniele Criado-Gonzalez, Miryam Guzmán-González, Gregorio Schmarsow, Ruth Müller, Alejandro J. Tomé, Liliana C. Minari, Roque J. Mecerreyes, David |
author2_role |
author author author author author author author author author |
dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
dc.contributor.author.fl_str_mv |
Picchio, Matías L. Minudri, Daniela Mantione, Daniele Criado-Gonzalez, Miryam Guzmán-González, Gregorio Schmarsow, Ruth Müller, Alejandro J. Tomé, Liliana C. Minari, Roque J. Mecerreyes, David |
dc.subject.por.fl_str_mv |
Catechol chemistry Corrosion inhibitors Eutectic mixtures Metal-ligand coordination Polyphenols Tissue adhesives Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 7 - Affordable and Clean Energy |
topic |
Catechol chemistry Corrosion inhibitors Eutectic mixtures Metal-ligand coordination Polyphenols Tissue adhesives Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 7 - Affordable and Clean Energy |
description |
This work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under Grant Agreement No. 823989 “IONBIKE”. The financial supports received from CONICET and ANPCyT (Argentina) are also gratefully acknowledged. ). Publisher Copyright: © 2022 American Chemical Society. All rights reserved. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-09-05T22:25:58Z 2022-06 2022-06-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/143504 |
url |
http://hdl.handle.net/10362/143504 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2168-0485 PURE: 46300276 https://doi.org/10.1021/acssuschemeng.2c01976 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
8 application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
mluisa.alvim@gmail.com |
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1817545884591718400 |