Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors

Detalhes bibliográficos
Autor(a) principal: Picchio, Matías L.
Data de Publicação: 2022
Outros Autores: Minudri, Daniela, Mantione, Daniele, Criado-Gonzalez, Miryam, Guzmán-González, Gregorio, Schmarsow, Ruth, Müller, Alejandro J., Tomé, Liliana C., Minari, Roque J., Mecerreyes, David
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/143504
Resumo: This work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under Grant Agreement No. 823989 “IONBIKE”. The financial supports received from CONICET and ANPCyT (Argentina) are also gratefully acknowledged. ). Publisher Copyright: © 2022 American Chemical Society. All rights reserved.
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spelling Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion ProtectorsCatechol chemistryCorrosion inhibitorsEutectic mixturesMetal-ligand coordinationPolyphenolsTissue adhesivesChemistry(all)Environmental ChemistryChemical Engineering(all)Renewable Energy, Sustainability and the EnvironmentSDG 7 - Affordable and Clean EnergyThis work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under Grant Agreement No. 823989 “IONBIKE”. The financial supports received from CONICET and ANPCyT (Argentina) are also gratefully acknowledged. ). Publisher Copyright: © 2022 American Chemical Society. All rights reserved.Natural deep eutectics solvents (NADES), owing to their high solvation capacity and nontoxicity, are actively being sought for many technological applications. Herein, we report a series of novel NADES based on choline chloride and plant-derived polyphenols. Most of the obtained phenolic NADES have a wide liquid range and high thermal stability above 150 °C. Among them, small-sized polyphenols, like pyrogallol, vanillyl alcohol, or gentisic acid, lead to low-viscosity liquids with ionic conductivities in the order of 10-3S cm-1at room temperature. Interestingly, polyphenols possess valuable properties as therapeutic agents, antioxidants, adhesives, or redox-active compounds, among others. Thus, we evaluated the potential of these novel NADES for two applications: bioadhesives and corrosion protection. The mixture of choline chloride-vanillyl alcohol (2:3 mol ratio) and gelatin resulted in a highly adhesive viscoelastic liquid (adhesive stress ≈ 135 kPa), affording shear thinning behavior. Furthermore, choline chloride-tannic acid (20:1) showed an extraordinary ability to coordinate iron ions, reaching excellent corrosion inhibitive efficiencies in mild steel protection.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNPicchio, Matías L.Minudri, DanielaMantione, DanieleCriado-Gonzalez, MiryamGuzmán-González, GregorioSchmarsow, RuthMüller, Alejandro J.Tomé, Liliana C.Minari, Roque J.Mecerreyes, David2022-09-05T22:25:58Z2022-062022-06-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article8application/pdfhttp://hdl.handle.net/10362/143504eng2168-0485PURE: 46300276https://doi.org/10.1021/acssuschemeng.2c01976info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T18:04:51Zoai:run.unl.pt:10362/143504Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T18:04:51Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
title Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
spellingShingle Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
Picchio, Matías L.
Catechol chemistry
Corrosion inhibitors
Eutectic mixtures
Metal-ligand coordination
Polyphenols
Tissue adhesives
Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Renewable Energy, Sustainability and the Environment
SDG 7 - Affordable and Clean Energy
title_short Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
title_full Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
title_fullStr Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
title_full_unstemmed Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
title_sort Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors
author Picchio, Matías L.
author_facet Picchio, Matías L.
Minudri, Daniela
Mantione, Daniele
Criado-Gonzalez, Miryam
Guzmán-González, Gregorio
Schmarsow, Ruth
Müller, Alejandro J.
Tomé, Liliana C.
Minari, Roque J.
Mecerreyes, David
author_role author
author2 Minudri, Daniela
Mantione, Daniele
Criado-Gonzalez, Miryam
Guzmán-González, Gregorio
Schmarsow, Ruth
Müller, Alejandro J.
Tomé, Liliana C.
Minari, Roque J.
Mecerreyes, David
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Picchio, Matías L.
Minudri, Daniela
Mantione, Daniele
Criado-Gonzalez, Miryam
Guzmán-González, Gregorio
Schmarsow, Ruth
Müller, Alejandro J.
Tomé, Liliana C.
Minari, Roque J.
Mecerreyes, David
dc.subject.por.fl_str_mv Catechol chemistry
Corrosion inhibitors
Eutectic mixtures
Metal-ligand coordination
Polyphenols
Tissue adhesives
Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Renewable Energy, Sustainability and the Environment
SDG 7 - Affordable and Clean Energy
topic Catechol chemistry
Corrosion inhibitors
Eutectic mixtures
Metal-ligand coordination
Polyphenols
Tissue adhesives
Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Renewable Energy, Sustainability and the Environment
SDG 7 - Affordable and Clean Energy
description This work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under Grant Agreement No. 823989 “IONBIKE”. The financial supports received from CONICET and ANPCyT (Argentina) are also gratefully acknowledged. ). Publisher Copyright: © 2022 American Chemical Society. All rights reserved.
publishDate 2022
dc.date.none.fl_str_mv 2022-09-05T22:25:58Z
2022-06
2022-06-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/143504
url http://hdl.handle.net/10362/143504
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2168-0485
PURE: 46300276
https://doi.org/10.1021/acssuschemeng.2c01976
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 8
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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