Diels-Alder Cycloaddition Reactions in Sustainable Media

Detalhes bibliográficos
Autor(a) principal: Soares, Maria I. L.
Data de Publicação: 2022
Outros Autores: Cardoso, Ana L., Melo, Teresa M. V. D. Pinho e
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
DOI: 10.3390/molecules27041304
Texto Completo: http://hdl.handle.net/10316/103395
https://doi.org/10.3390/molecules27041304
Resumo: Diels-Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity. In this review, an insight into the most relevant advances on sustainable Diels-Alder reactions since 2010 is provided. Various environmentally benign solvent systems are discussed, namely bio-based derived solvents (such as glycerol and gluconic acid), polyethylene glycol, deep eutectic solvents, supercritical carbon dioxide, water and water-based aqueous systems. Issues such as method's scope, efficiency, selectivity and reaction mechanism, as well as sustainability, advantages and limitations of these reaction media, are addressed.
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spelling Diels-Alder Cycloaddition Reactions in Sustainable MediaDiels–Alder reactiongreen solventbio-based solventdeep eutectic solventswaterDiels-Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity. In this review, an insight into the most relevant advances on sustainable Diels-Alder reactions since 2010 is provided. Various environmentally benign solvent systems are discussed, namely bio-based derived solvents (such as glycerol and gluconic acid), polyethylene glycol, deep eutectic solvents, supercritical carbon dioxide, water and water-based aqueous systems. Issues such as method's scope, efficiency, selectivity and reaction mechanism, as well as sustainability, advantages and limitations of these reaction media, are addressed.2022-02-15info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/103395http://hdl.handle.net/10316/103395https://doi.org/10.3390/molecules27041304eng1420-3049Soares, Maria I. L.Cardoso, Ana L.Melo, Teresa M. V. D. Pinho einfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-11-11T21:39:33Zoai:estudogeral.uc.pt:10316/103395Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:20:14.555946Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Diels-Alder Cycloaddition Reactions in Sustainable Media
title Diels-Alder Cycloaddition Reactions in Sustainable Media
spellingShingle Diels-Alder Cycloaddition Reactions in Sustainable Media
Diels-Alder Cycloaddition Reactions in Sustainable Media
Soares, Maria I. L.
Diels–Alder reaction
green solvent
bio-based solvent
deep eutectic solvents
water
Soares, Maria I. L.
Diels–Alder reaction
green solvent
bio-based solvent
deep eutectic solvents
water
title_short Diels-Alder Cycloaddition Reactions in Sustainable Media
title_full Diels-Alder Cycloaddition Reactions in Sustainable Media
title_fullStr Diels-Alder Cycloaddition Reactions in Sustainable Media
Diels-Alder Cycloaddition Reactions in Sustainable Media
title_full_unstemmed Diels-Alder Cycloaddition Reactions in Sustainable Media
Diels-Alder Cycloaddition Reactions in Sustainable Media
title_sort Diels-Alder Cycloaddition Reactions in Sustainable Media
author Soares, Maria I. L.
author_facet Soares, Maria I. L.
Soares, Maria I. L.
Cardoso, Ana L.
Melo, Teresa M. V. D. Pinho e
Cardoso, Ana L.
Melo, Teresa M. V. D. Pinho e
author_role author
author2 Cardoso, Ana L.
Melo, Teresa M. V. D. Pinho e
author2_role author
author
dc.contributor.author.fl_str_mv Soares, Maria I. L.
Cardoso, Ana L.
Melo, Teresa M. V. D. Pinho e
dc.subject.por.fl_str_mv Diels–Alder reaction
green solvent
bio-based solvent
deep eutectic solvents
water
topic Diels–Alder reaction
green solvent
bio-based solvent
deep eutectic solvents
water
description Diels-Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity. In this review, an insight into the most relevant advances on sustainable Diels-Alder reactions since 2010 is provided. Various environmentally benign solvent systems are discussed, namely bio-based derived solvents (such as glycerol and gluconic acid), polyethylene glycol, deep eutectic solvents, supercritical carbon dioxide, water and water-based aqueous systems. Issues such as method's scope, efficiency, selectivity and reaction mechanism, as well as sustainability, advantages and limitations of these reaction media, are addressed.
publishDate 2022
dc.date.none.fl_str_mv 2022-02-15
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/103395
http://hdl.handle.net/10316/103395
https://doi.org/10.3390/molecules27041304
url http://hdl.handle.net/10316/103395
https://doi.org/10.3390/molecules27041304
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1420-3049
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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dc.identifier.doi.none.fl_str_mv 10.3390/molecules27041304

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