Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004 |
Resumo: | Inhibitive and adsorption properties of ethanol extract of vernonia amygdalina for the corrosion of mild steel were studied using weight loss, thermometric, gasometric and IR methods of monitoring corrosion. The results revealed that ethanol extract of Vernonia amygdalina inhibited the corrosion of mild steel. The inhibition efficiency of the extract increased as the concentration of the extract increases. The inhibitor was found to function by being adsorbed on the surface of mild steel. The adsorption of the inhibitor followed the Langmuir adsorption isotherm. IR spectra of the corrosion product (without inhibitor), the extract and the corrosion product (with the inhibitor) confirmed that ethanol extract of vernonia amygdalina is an adsorption inhibitor. Phytochemical studies also revealed that ethanol vernonia amygdalina contains tannin, saponnins, flavanoid and anthraquinone, all of them contributing to the corrosion inhibition. Physical adsorption mechanism has been proposed from the values of some of the thermodynamic parameters obtained. |
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Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4corrosion inhibitionmild steeladsorptionvernonia amygdalinaInhibitive and adsorption properties of ethanol extract of vernonia amygdalina for the corrosion of mild steel were studied using weight loss, thermometric, gasometric and IR methods of monitoring corrosion. The results revealed that ethanol extract of Vernonia amygdalina inhibited the corrosion of mild steel. The inhibition efficiency of the extract increased as the concentration of the extract increases. The inhibitor was found to function by being adsorbed on the surface of mild steel. The adsorption of the inhibitor followed the Langmuir adsorption isotherm. IR spectra of the corrosion product (without inhibitor), the extract and the corrosion product (with the inhibitor) confirmed that ethanol extract of vernonia amygdalina is an adsorption inhibitor. Phytochemical studies also revealed that ethanol vernonia amygdalina contains tannin, saponnins, flavanoid and anthraquinone, all of them contributing to the corrosion inhibition. Physical adsorption mechanism has been proposed from the values of some of the thermodynamic parameters obtained.Sociedade Portuguesa de Electroquímica2009-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004Portugaliae Electrochimica Acta v.27 n.1 2009reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004Odiongenyi,A.O.Odoemelam,S.A.Eddy,N.O.info:eu-repo/semantics/openAccess2024-02-06T17:06:57Zoai:scielo:S0872-19042009000100004Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:05.235406Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 |
title |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 |
spellingShingle |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 Odiongenyi,A.O. corrosion inhibition mild steel adsorption vernonia amygdalina |
title_short |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 |
title_full |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 |
title_fullStr |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 |
title_full_unstemmed |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 |
title_sort |
Corrosion Inhibition and Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild Steel in H2SO4 |
author |
Odiongenyi,A.O. |
author_facet |
Odiongenyi,A.O. Odoemelam,S.A. Eddy,N.O. |
author_role |
author |
author2 |
Odoemelam,S.A. Eddy,N.O. |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Odiongenyi,A.O. Odoemelam,S.A. Eddy,N.O. |
dc.subject.por.fl_str_mv |
corrosion inhibition mild steel adsorption vernonia amygdalina |
topic |
corrosion inhibition mild steel adsorption vernonia amygdalina |
description |
Inhibitive and adsorption properties of ethanol extract of vernonia amygdalina for the corrosion of mild steel were studied using weight loss, thermometric, gasometric and IR methods of monitoring corrosion. The results revealed that ethanol extract of Vernonia amygdalina inhibited the corrosion of mild steel. The inhibition efficiency of the extract increased as the concentration of the extract increases. The inhibitor was found to function by being adsorbed on the surface of mild steel. The adsorption of the inhibitor followed the Langmuir adsorption isotherm. IR spectra of the corrosion product (without inhibitor), the extract and the corrosion product (with the inhibitor) confirmed that ethanol extract of vernonia amygdalina is an adsorption inhibitor. Phytochemical studies also revealed that ethanol vernonia amygdalina contains tannin, saponnins, flavanoid and anthraquinone, all of them contributing to the corrosion inhibition. Physical adsorption mechanism has been proposed from the values of some of the thermodynamic parameters obtained. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000100004 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.27 n.1 2009 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137289905897472 |