Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/144487 |
Resumo: | Kingdom of Saudi Arabia, Award Number (2-17-01-001-0042 |
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7160 |
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Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic CompoundsFTIR spectroscopyionic conductivityNMR analysisp-toluene sulfonic acidprotic ionic liquidsChemical Engineering(all)Materials Science(all)Condensed Matter PhysicsInorganic ChemistryKingdom of Saudi Arabia, Award Number (2-17-01-001-0042In the present work, six protic ionic liquid (PIL) compounds based on p-toluene sulfonic acid [PTSA] anion along with different cations viz. tetraethylenepentammonium [TEPA], triethy-lammonium [TEA], pyridinium [Py], N-methylpiperidinium [Pip], 1-methylimidazolium [Im], and N-methylpyrrolidinium [Pyrr] were synthesized using the standard neutralization reaction method. The structural characterization of these compounds was achieved using FTIR,1H and13C NMR spectroscopies. Thermal behavior was studied using differential scanning calorimetry to determine the melting point (Tm) and crystallization (Tc ) temperatures. Thermogravimetric analysis was carried out to determine the thermal stability and degradation temperatures (Tdec) and to ascertain the hygroscopic or hydrophobic nature of the synthesized compounds. Structural effects on the outcome of various properties were witnessed and discussed in detail. Electrochemical impedance spectroscopy was utilized to study the electrical transport properties of the PILs at different temperatures. Cyclic voltammetry was performed to analyze the electrochemical stability of these PILs. Low values of activation energy indicating easy proton transportation along with good electrochemical stability make the PILs a potential candidate for use in the preparation of polymer electrolytes membranes for fuel cell applications.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNAnis, ArfatAlam, ManawwerAlhamidi, AbdullahAlam, Mohammad AsifGupta, Ravindra KumarTariq, MohammadShaikh, HamidPoulose, Anesh ManjalyAl-Zahrani, Saeed M.2022-10-05T22:16:03Z2022-04-062022-04-06T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article15application/pdfhttp://hdl.handle.net/10362/144487eng2073-4352PURE: 46294679https://doi.org/10.3390/cryst12040507info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:24:08Zoai:run.unl.pt:10362/144487Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:51:35.610675Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds |
title |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds |
spellingShingle |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds Anis, Arfat FTIR spectroscopy ionic conductivity NMR analysis p-toluene sulfonic acid protic ionic liquids Chemical Engineering(all) Materials Science(all) Condensed Matter Physics Inorganic Chemistry |
title_short |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds |
title_full |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds |
title_fullStr |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds |
title_full_unstemmed |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds |
title_sort |
Characterization of Thermal, Ionic Conductivity and Electrochemical Properties of Some p-Tosylate Anions-Based Protic Ionic Compounds |
author |
Anis, Arfat |
author_facet |
Anis, Arfat Alam, Manawwer Alhamidi, Abdullah Alam, Mohammad Asif Gupta, Ravindra Kumar Tariq, Mohammad Shaikh, Hamid Poulose, Anesh Manjaly Al-Zahrani, Saeed M. |
author_role |
author |
author2 |
Alam, Manawwer Alhamidi, Abdullah Alam, Mohammad Asif Gupta, Ravindra Kumar Tariq, Mohammad Shaikh, Hamid Poulose, Anesh Manjaly Al-Zahrani, Saeed M. |
author2_role |
author author author author author author author author |
dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
dc.contributor.author.fl_str_mv |
Anis, Arfat Alam, Manawwer Alhamidi, Abdullah Alam, Mohammad Asif Gupta, Ravindra Kumar Tariq, Mohammad Shaikh, Hamid Poulose, Anesh Manjaly Al-Zahrani, Saeed M. |
dc.subject.por.fl_str_mv |
FTIR spectroscopy ionic conductivity NMR analysis p-toluene sulfonic acid protic ionic liquids Chemical Engineering(all) Materials Science(all) Condensed Matter Physics Inorganic Chemistry |
topic |
FTIR spectroscopy ionic conductivity NMR analysis p-toluene sulfonic acid protic ionic liquids Chemical Engineering(all) Materials Science(all) Condensed Matter Physics Inorganic Chemistry |
description |
Kingdom of Saudi Arabia, Award Number (2-17-01-001-0042 |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-10-05T22:16:03Z 2022-04-06 2022-04-06T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/144487 |
url |
http://hdl.handle.net/10362/144487 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2073-4352 PURE: 46294679 https://doi.org/10.3390/cryst12040507 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
15 application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799138109242212352 |