Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones

Detalhes bibliográficos
Autor(a) principal: Moreno Montoya, Carmen Alicia
Data de Publicação: 2016
Outros Autores: Gomez, Clara F., Paninho, Ana B., Nunes, Ana V. M., Mahmudov, Kamran, Najdanovic-Visak, Vesna, Martins, Luisa, Guedes Da Silva, M. Fátima C., Pombeiro, Armando, Nunes Da Ponte, Manuel
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.21/9590
Resumo: Zinc(II) complexes of arylhydrazones of beta-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.
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spelling Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketonesCarbon dioxideEpoxideStyrene carbonateCyclic carbonatesZincArylhydrazone of B-diketonesZinc(II) complexes of arylhydrazones of beta-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.ElsevierRCIPLMoreno Montoya, Carmen AliciaGomez, Clara F.Paninho, Ana B.Nunes, Ana V. M.Mahmudov, KamranNajdanovic-Visak, VesnaMartins, LuisaGuedes Da Silva, M. Fátima C.Pombeiro, ArmandoNunes Da Ponte, Manuel2019-02-26T10:08:13Z2016-032016-03-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/9590engMONTOYA, Carmen A.; [et al] – Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones. Journal of Catalysis. ISSN 0021-9517. Vol. 335 (2016), pp. 135-1400021-951710.1016/j.jcat.2015.12.027metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:58:28Zoai:repositorio.ipl.pt:10400.21/9590Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:18:08.186789Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
title Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
spellingShingle Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
Moreno Montoya, Carmen Alicia
Carbon dioxide
Epoxide
Styrene carbonate
Cyclic carbonates
Zinc
Arylhydrazone of B-diketones
title_short Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
title_full Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
title_fullStr Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
title_full_unstemmed Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
title_sort Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones
author Moreno Montoya, Carmen Alicia
author_facet Moreno Montoya, Carmen Alicia
Gomez, Clara F.
Paninho, Ana B.
Nunes, Ana V. M.
Mahmudov, Kamran
Najdanovic-Visak, Vesna
Martins, Luisa
Guedes Da Silva, M. Fátima C.
Pombeiro, Armando
Nunes Da Ponte, Manuel
author_role author
author2 Gomez, Clara F.
Paninho, Ana B.
Nunes, Ana V. M.
Mahmudov, Kamran
Najdanovic-Visak, Vesna
Martins, Luisa
Guedes Da Silva, M. Fátima C.
Pombeiro, Armando
Nunes Da Ponte, Manuel
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv RCIPL
dc.contributor.author.fl_str_mv Moreno Montoya, Carmen Alicia
Gomez, Clara F.
Paninho, Ana B.
Nunes, Ana V. M.
Mahmudov, Kamran
Najdanovic-Visak, Vesna
Martins, Luisa
Guedes Da Silva, M. Fátima C.
Pombeiro, Armando
Nunes Da Ponte, Manuel
dc.subject.por.fl_str_mv Carbon dioxide
Epoxide
Styrene carbonate
Cyclic carbonates
Zinc
Arylhydrazone of B-diketones
topic Carbon dioxide
Epoxide
Styrene carbonate
Cyclic carbonates
Zinc
Arylhydrazone of B-diketones
description Zinc(II) complexes of arylhydrazones of beta-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.
publishDate 2016
dc.date.none.fl_str_mv 2016-03
2016-03-01T00:00:00Z
2019-02-26T10:08:13Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.21/9590
url http://hdl.handle.net/10400.21/9590
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv MONTOYA, Carmen A.; [et al] – Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones. Journal of Catalysis. ISSN 0021-9517. Vol. 335 (2016), pp. 135-140
0021-9517
10.1016/j.jcat.2015.12.027
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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