catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K
Autor(a) principal: | |
---|---|
Data de Publicação: | 2003 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/5820 |
Resumo: | The crystal structure of the title compound, (C3H12N2)- [V3O3(OH)2(PO4)2] 2H2O, has been reported by Soghomonian et al. [Chem. Mater. (1993), 5, 1690±1691]. We present here a redetermination of greatly improved precision and at a low temperature of 180 (2) K. The H atoms connected to oxygen have been successfully located and the coordination environments of the two crystallographically independent vanadium centres have been properly elucidated. Large channels, running along the a direction, contain water molecules and 1,3-diammoniopropane cations that are strongly hydrogen bonded to the anionic framework through N+ÐH O and OÐH O interactions. One vanadyl (V O) bond and the central ±CH2± group of 1,3-diammoniopropane are located on a mirror plane. |
id |
RCAP_24b6763be049ccd51b1a948e42812156 |
---|---|
oai_identifier_str |
oai:ria.ua.pt:10773/5820 |
network_acronym_str |
RCAP |
network_name_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository_id_str |
7160 |
spelling |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) KThe crystal structure of the title compound, (C3H12N2)- [V3O3(OH)2(PO4)2] 2H2O, has been reported by Soghomonian et al. [Chem. Mater. (1993), 5, 1690±1691]. We present here a redetermination of greatly improved precision and at a low temperature of 180 (2) K. The H atoms connected to oxygen have been successfully located and the coordination environments of the two crystallographically independent vanadium centres have been properly elucidated. Large channels, running along the a direction, contain water molecules and 1,3-diammoniopropane cations that are strongly hydrogen bonded to the anionic framework through N+ÐH O and OÐH O interactions. One vanadyl (V O) bond and the central ±CH2± group of 1,3-diammoniopropane are located on a mirror plane.International Union of Crystallography2012-02-06T12:58:01Z2003-04-01T00:00:00Z2003-04info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/5820eng1600-5368Paz, Filipe A. AlmeidaShi, Fa-NianTrindade, TitoRocha, JoãoKlinowski, Jacekinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T11:06:39Zoai:ria.ua.pt:10773/5820Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:42:58.754286Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K |
title |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K |
spellingShingle |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K Paz, Filipe A. Almeida |
title_short |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K |
title_full |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K |
title_fullStr |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K |
title_full_unstemmed |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K |
title_sort |
catena-[1,3-diammoniopropane di-mu2-hydroxodi-mu4-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K |
author |
Paz, Filipe A. Almeida |
author_facet |
Paz, Filipe A. Almeida Shi, Fa-Nian Trindade, Tito Rocha, João Klinowski, Jacek |
author_role |
author |
author2 |
Shi, Fa-Nian Trindade, Tito Rocha, João Klinowski, Jacek |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Paz, Filipe A. Almeida Shi, Fa-Nian Trindade, Tito Rocha, João Klinowski, Jacek |
description |
The crystal structure of the title compound, (C3H12N2)- [V3O3(OH)2(PO4)2] 2H2O, has been reported by Soghomonian et al. [Chem. Mater. (1993), 5, 1690±1691]. We present here a redetermination of greatly improved precision and at a low temperature of 180 (2) K. The H atoms connected to oxygen have been successfully located and the coordination environments of the two crystallographically independent vanadium centres have been properly elucidated. Large channels, running along the a direction, contain water molecules and 1,3-diammoniopropane cations that are strongly hydrogen bonded to the anionic framework through N+ÐH O and OÐH O interactions. One vanadyl (V O) bond and the central ±CH2± group of 1,3-diammoniopropane are located on a mirror plane. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-04-01T00:00:00Z 2003-04 2012-02-06T12:58:01Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/5820 |
url |
http://hdl.handle.net/10773/5820 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1600-5368 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
International Union of Crystallography |
publisher.none.fl_str_mv |
International Union of Crystallography |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
_version_ |
1799137478116900864 |