Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2023 |
| Outros Autores: | , , , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10362/155062 |
Resumo: | Funding Information: Thanks are also due to FCT for the project PTDC/BII-BIO/30884/2017. A.F.P. and M.M.M. thank FCT for funding through the Individual Call to Scientific Employment Stimulus (ref. 2020.01614.CEECIND/CP1596/CT0007 and CEEC-IND/02702/2017, respectively). O.D. is thankful for the Ph.D. grant supported by FCT (2021.05322.BD). Funding Information: This work was funded by Portuguese funds through Fundação para a Ciência e a Tecnologia (FCT/MCTES) in the framework of the projects UIDB/50006/2020, UIDP/50006/2020, and EXPL/BII-BIO/0436/2021 and also by BIP Proof 2022/2023 through UI-Transfer, a cofunding project by European Union through COMPETE 2020-Portugal 2020, CIQUP, Centro de Investigação em Química da Universidade do Porto (UIDB/00081/2020), and IMS, Institute of Molecular Sciences (LA/P/0056/2020). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
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Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel StabilityExperimental Tests and Preliminary Life Cycle Assessmentbiodieselenvironmental sustainabilitylife cycle assessmentsubcritical water extraction; natural antioxidantsvineyard pruning wasteChemistry(all)Environmental ChemistryChemical Engineering(all)Renewable Energy, Sustainability and the EnvironmentSDG 7 - Affordable and Clean EnergySDG 12 - Responsible Consumption and ProductionFunding Information: Thanks are also due to FCT for the project PTDC/BII-BIO/30884/2017. A.F.P. and M.M.M. thank FCT for funding through the Individual Call to Scientific Employment Stimulus (ref. 2020.01614.CEECIND/CP1596/CT0007 and CEEC-IND/02702/2017, respectively). O.D. is thankful for the Ph.D. grant supported by FCT (2021.05322.BD). Funding Information: This work was funded by Portuguese funds through Fundação para a Ciência e a Tecnologia (FCT/MCTES) in the framework of the projects UIDB/50006/2020, UIDP/50006/2020, and EXPL/BII-BIO/0436/2021 and also by BIP Proof 2022/2023 through UI-Transfer, a cofunding project by European Union through COMPETE 2020-Portugal 2020, CIQUP, Centro de Investigação em Química da Universidade do Porto (UIDB/00081/2020), and IMS, Institute of Molecular Sciences (LA/P/0056/2020). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.The control of the oxidative stability of biodiesel and blends of biodiesel with diesel is one of the major concerns of the biofuel industry. The oxidative degradation of biodiesel can be accelerated by several factors, and this is most critical in the so-called second generation biodiesel, which is produced from low-cost raw materials with lower environmental impacts. The addition of antioxidants is imperative to ensure the oxidative stability of biodiesel, and these are considered products of high commercial value. The antioxidants currently available on the market are from synthetic origin, so the existence/availability of alternative antioxidants of natural origin (less dependent on fossil sources) at a competitive price presents itself as a strong business opportunity. This work describes and characterizes a sustainable alternative to synthetic antioxidants used in the biodiesel market developed from extracts of vineyard pruning waste (VPW), which are naturally rich in phenolic compounds with antioxidant properties. A hydrothermal extraction process was applied as a more efficient and sustainable technology than the conventional one with the potential of the extracts as antioxidant additives in biodiesel evaluated in Rancitech equipment. The VPW extract showed comparable antioxidant activity as the commercial antioxidant butylated hydroxytoluene (BHT) typically used in biodiesel. The stability of the biodiesel is dependent from the amount of the extract added. Further, for the first time, the assessment of the environmental impacts of using natural extracts to control the oxidative stability of biodiesel in the production process is also discussed as a key factor of the process environmental sustainability.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNDorosh, OlenaSurra, ElenaEusebio, MárioMonteiro, Ana L.Ribeiro, Jorge C.Branco, Nuno F. M.Moreira, Manuela M.Peixoto, Andreia F.Santos, Luís M. N. B. F.Delerue-Matos, Cristina2023-07-10T22:16:00Z2023-05-292023-05-29T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article12application/pdfhttp://hdl.handle.net/10362/155062eng2168-0485PURE: 64803491https://doi.org/10.1021/acssuschemeng.3c00764info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:37:31Zoai:run.unl.pt:10362/155062Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:55:53.601858Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability Experimental Tests and Preliminary Life Cycle Assessment |
| title |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability |
| spellingShingle |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability Dorosh, Olena biodiesel environmental sustainability life cycle assessment subcritical water extraction; natural antioxidants vineyard pruning waste Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production |
| title_short |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability |
| title_full |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability |
| title_fullStr |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability |
| title_full_unstemmed |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability |
| title_sort |
Vineyard Pruning Extracts as Natural Antioxidants for Biodiesel Stability |
| author |
Dorosh, Olena |
| author_facet |
Dorosh, Olena Surra, Elena Eusebio, Mário Monteiro, Ana L. Ribeiro, Jorge C. Branco, Nuno F. M. Moreira, Manuela M. Peixoto, Andreia F. Santos, Luís M. N. B. F. Delerue-Matos, Cristina |
| author_role |
author |
| author2 |
Surra, Elena Eusebio, Mário Monteiro, Ana L. Ribeiro, Jorge C. Branco, Nuno F. M. Moreira, Manuela M. Peixoto, Andreia F. Santos, Luís M. N. B. F. Delerue-Matos, Cristina |
| author2_role |
author author author author author author author author author |
| dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
| dc.contributor.author.fl_str_mv |
Dorosh, Olena Surra, Elena Eusebio, Mário Monteiro, Ana L. Ribeiro, Jorge C. Branco, Nuno F. M. Moreira, Manuela M. Peixoto, Andreia F. Santos, Luís M. N. B. F. Delerue-Matos, Cristina |
| dc.subject.por.fl_str_mv |
biodiesel environmental sustainability life cycle assessment subcritical water extraction; natural antioxidants vineyard pruning waste Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production |
| topic |
biodiesel environmental sustainability life cycle assessment subcritical water extraction; natural antioxidants vineyard pruning waste Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production |
| description |
Funding Information: Thanks are also due to FCT for the project PTDC/BII-BIO/30884/2017. A.F.P. and M.M.M. thank FCT for funding through the Individual Call to Scientific Employment Stimulus (ref. 2020.01614.CEECIND/CP1596/CT0007 and CEEC-IND/02702/2017, respectively). O.D. is thankful for the Ph.D. grant supported by FCT (2021.05322.BD). Funding Information: This work was funded by Portuguese funds through Fundação para a Ciência e a Tecnologia (FCT/MCTES) in the framework of the projects UIDB/50006/2020, UIDP/50006/2020, and EXPL/BII-BIO/0436/2021 and also by BIP Proof 2022/2023 through UI-Transfer, a cofunding project by European Union through COMPETE 2020-Portugal 2020, CIQUP, Centro de Investigação em Química da Universidade do Porto (UIDB/00081/2020), and IMS, Institute of Molecular Sciences (LA/P/0056/2020). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023-07-10T22:16:00Z 2023-05-29 2023-05-29T00:00:00Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/155062 |
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http://hdl.handle.net/10362/155062 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
2168-0485 PURE: 64803491 https://doi.org/10.1021/acssuschemeng.3c00764 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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12 application/pdf |
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RCAAP |
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