Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes

Detalhes bibliográficos
Autor(a) principal: Monteiro, Bernardo
Data de Publicação: 2018
Outros Autores: Nabais, Ana R., Casimiro, Maria H., Martins, Ana P. S., Francisco, Rute O., Neves, Luísa A., Pereira, Cláudia C. L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: https://doi.org/10.3390/membranes8040093
Resumo: PTDC/CTM-POL/2676/2014 IF/00505/2014 This work was performed under the project "SunStorage-Harvesting and storage of solar energy", with reference POCI-01-0145-FEDER-016387, funded by European Regional Development Fund (ERDF), through COMPETE 2020-Operational Programme for Competitiveness and Internationalization (OPCI), and by national funds, through FCT-Fundacao para a Ciencia e a Tecnologia I.P. This work was supported by the Associated Laboratory for Sustainable Chemistry-Clean Processes and Technologies-LAQV which is financed by national funds from FCT/MEC (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265) The NMR spectrometers are part of The National NMR Facility, supported by Fundacao para a Ciencia e a Tecnologia (RECI/BBB-BQB/0230/2012). A.R.N. and L.A.N. acknowledge FCT/MCTES for financial support through project PTDC/CTM-POL/2676/2014 and FCT Investigator Contract IF/00505/2014, respectively. C2TN/IST authors gratefully acknowledge the Fundacao para a Ciencia e Tecnologia support through the UID/Multi/04349/2013 project.
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spelling Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranesCu(BTC)2Gas separationIL@Cu(BTC)2IL@MOFIonic liquidsMetal-organic frameworksMixed matrix membranesChemical Engineering (miscellaneous)Process Chemistry and TechnologyFiltration and SeparationPTDC/CTM-POL/2676/2014 IF/00505/2014 This work was performed under the project "SunStorage-Harvesting and storage of solar energy", with reference POCI-01-0145-FEDER-016387, funded by European Regional Development Fund (ERDF), through COMPETE 2020-Operational Programme for Competitiveness and Internationalization (OPCI), and by national funds, through FCT-Fundacao para a Ciencia e a Tecnologia I.P. This work was supported by the Associated Laboratory for Sustainable Chemistry-Clean Processes and Technologies-LAQV which is financed by national funds from FCT/MEC (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265) The NMR spectrometers are part of The National NMR Facility, supported by Fundacao para a Ciencia e a Tecnologia (RECI/BBB-BQB/0230/2012). A.R.N. and L.A.N. acknowledge FCT/MCTES for financial support through project PTDC/CTM-POL/2676/2014 and FCT Investigator Contract IF/00505/2014, respectively. C2TN/IST authors gratefully acknowledge the Fundacao para a Ciencia e Tecnologia support through the UID/Multi/04349/2013 project.The efficient separation of gases has industrial, economic, and environmental importance. Here, we report the improvement in gas separation performance of a polyimide-based matrix (Matrimid®5218) filled with a Cu-based metal organic framework [MOF, Cu3(BTC)2] with two different ionic liquids (ILs) confined within the pores. The chosen ILs are commonly used in gas solubilization, 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]) and 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][OTf]), and the incorporation of the [EMIM][BF4]@Cu-BTC and [EMIM][OTf]@Cu-BTC composites in Matrimid®5218 proved to be an efficient strategy to improve the permeability and selectivity toward CO2/N2 and CO2/CH4 mixtures.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNMonteiro, BernardoNabais, Ana R.Casimiro, Maria H.Martins, Ana P. S.Francisco, Rute O.Neves, Luísa A.Pereira, Cláudia C. L.2019-01-25T23:43:26Z2018-12-012018-12-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://doi.org/10.3390/membranes8040093eng0076-6356PURE: 6547862http://www.scopus.com/inward/record.url?scp=85055641753&partnerID=8YFLogxKhttps://doi.org/10.3390/membranes8040093info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:28:19Zoai:run.unl.pt:10362/58658Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:33:18.420045Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
title Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
spellingShingle Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
Monteiro, Bernardo
Cu(BTC)2
Gas separation
IL@Cu(BTC)2
IL@MOF
Ionic liquids
Metal-organic frameworks
Mixed matrix membranes
Chemical Engineering (miscellaneous)
Process Chemistry and Technology
Filtration and Separation
title_short Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
title_full Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
title_fullStr Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
title_full_unstemmed Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
title_sort Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes
author Monteiro, Bernardo
author_facet Monteiro, Bernardo
Nabais, Ana R.
Casimiro, Maria H.
Martins, Ana P. S.
Francisco, Rute O.
Neves, Luísa A.
Pereira, Cláudia C. L.
author_role author
author2 Nabais, Ana R.
Casimiro, Maria H.
Martins, Ana P. S.
Francisco, Rute O.
Neves, Luísa A.
Pereira, Cláudia C. L.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Monteiro, Bernardo
Nabais, Ana R.
Casimiro, Maria H.
Martins, Ana P. S.
Francisco, Rute O.
Neves, Luísa A.
Pereira, Cláudia C. L.
dc.subject.por.fl_str_mv Cu(BTC)2
Gas separation
IL@Cu(BTC)2
IL@MOF
Ionic liquids
Metal-organic frameworks
Mixed matrix membranes
Chemical Engineering (miscellaneous)
Process Chemistry and Technology
Filtration and Separation
topic Cu(BTC)2
Gas separation
IL@Cu(BTC)2
IL@MOF
Ionic liquids
Metal-organic frameworks
Mixed matrix membranes
Chemical Engineering (miscellaneous)
Process Chemistry and Technology
Filtration and Separation
description PTDC/CTM-POL/2676/2014 IF/00505/2014 This work was performed under the project "SunStorage-Harvesting and storage of solar energy", with reference POCI-01-0145-FEDER-016387, funded by European Regional Development Fund (ERDF), through COMPETE 2020-Operational Programme for Competitiveness and Internationalization (OPCI), and by national funds, through FCT-Fundacao para a Ciencia e a Tecnologia I.P. This work was supported by the Associated Laboratory for Sustainable Chemistry-Clean Processes and Technologies-LAQV which is financed by national funds from FCT/MEC (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265) The NMR spectrometers are part of The National NMR Facility, supported by Fundacao para a Ciencia e a Tecnologia (RECI/BBB-BQB/0230/2012). A.R.N. and L.A.N. acknowledge FCT/MCTES for financial support through project PTDC/CTM-POL/2676/2014 and FCT Investigator Contract IF/00505/2014, respectively. C2TN/IST authors gratefully acknowledge the Fundacao para a Ciencia e Tecnologia support through the UID/Multi/04349/2013 project.
publishDate 2018
dc.date.none.fl_str_mv 2018-12-01
2018-12-01T00:00:00Z
2019-01-25T23:43:26Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://doi.org/10.3390/membranes8040093
url https://doi.org/10.3390/membranes8040093
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0076-6356
PURE: 6547862
http://www.scopus.com/inward/record.url?scp=85055641753&partnerID=8YFLogxK
https://doi.org/10.3390/membranes8040093
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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