Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042010000600002 |
Resumo: | The corrosion inhibition effect of acid extract of the pericarp of the fruit Garcinia mangostana on mild steel in hydrochloric acid medium is studied. Using weight-loss data, corrosion rate (CR) and thermodynamic parameters such as energy of activation for corrosion of mild steel (E), heat of adsorption of the inhibitors on the metal surface (Q) and change in free energy (∆G) are calculated. Adsorption isotherm is also recorded between log C and θ. Electrochemical parameters are evaluated from AC impedance and Tafel polarization studies in the presence and absence of different concentrations of inhibitor. Infra-red spectra are recorded for the extract and the adsorption product to find out the changes in the functional group frequencies of the organic components of the extract. The surface morphological changes are analysed using the SEM images. The entire study shows that the pericarp extract of the fruit G. mangostana is a non-toxic, cost-effective corrosion inhibitor for mild steel in acid medium. |
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Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Mediumcorrosionmild steelG. mangostanaTafel polarizationimpedanceSEMThe corrosion inhibition effect of acid extract of the pericarp of the fruit Garcinia mangostana on mild steel in hydrochloric acid medium is studied. Using weight-loss data, corrosion rate (CR) and thermodynamic parameters such as energy of activation for corrosion of mild steel (E), heat of adsorption of the inhibitors on the metal surface (Q) and change in free energy (∆G) are calculated. Adsorption isotherm is also recorded between log C and θ. Electrochemical parameters are evaluated from AC impedance and Tafel polarization studies in the presence and absence of different concentrations of inhibitor. Infra-red spectra are recorded for the extract and the adsorption product to find out the changes in the functional group frequencies of the organic components of the extract. The surface morphological changes are analysed using the SEM images. The entire study shows that the pericarp extract of the fruit G. mangostana is a non-toxic, cost-effective corrosion inhibitor for mild steel in acid medium.Sociedade Portuguesa de Electroquímica2010-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042010000600002Portugaliae Electrochimica Acta v.28 n.6 2010reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042010000600002Kumar,K.P. VinodPillai,M.S. NarayananThusnavis,G. Rexininfo:eu-repo/semantics/openAccess2024-02-06T17:07:06Zoai:scielo:S0872-19042010000600002Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:09.785599Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium |
title |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium |
spellingShingle |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium Kumar,K.P. Vinod corrosion mild steel G. mangostana Tafel polarization impedance SEM |
title_short |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium |
title_full |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium |
title_fullStr |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium |
title_full_unstemmed |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium |
title_sort |
Pericarp of the Fruit of Garcinia Mangostana as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Medium |
author |
Kumar,K.P. Vinod |
author_facet |
Kumar,K.P. Vinod Pillai,M.S. Narayanan Thusnavis,G. Rexin |
author_role |
author |
author2 |
Pillai,M.S. Narayanan Thusnavis,G. Rexin |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Kumar,K.P. Vinod Pillai,M.S. Narayanan Thusnavis,G. Rexin |
dc.subject.por.fl_str_mv |
corrosion mild steel G. mangostana Tafel polarization impedance SEM |
topic |
corrosion mild steel G. mangostana Tafel polarization impedance SEM |
description |
The corrosion inhibition effect of acid extract of the pericarp of the fruit Garcinia mangostana on mild steel in hydrochloric acid medium is studied. Using weight-loss data, corrosion rate (CR) and thermodynamic parameters such as energy of activation for corrosion of mild steel (E), heat of adsorption of the inhibitors on the metal surface (Q) and change in free energy (∆G) are calculated. Adsorption isotherm is also recorded between log C and θ. Electrochemical parameters are evaluated from AC impedance and Tafel polarization studies in the presence and absence of different concentrations of inhibitor. Infra-red spectra are recorded for the extract and the adsorption product to find out the changes in the functional group frequencies of the organic components of the extract. The surface morphological changes are analysed using the SEM images. The entire study shows that the pericarp extract of the fruit G. mangostana is a non-toxic, cost-effective corrosion inhibitor for mild steel in acid medium. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042010000600002 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042010000600002 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042010000600002 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.28 n.6 2010 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
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1817553974911303680 |