Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/57354 |
Resumo: | Polymer composites based on poly(vinylidene fluoride) (PVDF) filled with carbon nanotubes (CNT) decorated with metal nanoparticles (NP) of cobalt, nickel, platinum and palladium have been produced. The CNT nano fillers decorated with metal NP were synthesized by a modified wet impregnation method and their structural, morphological and thermal properties were evaluated. The metal NP ranging from 2 to 10 nm were found well dispersed on the CNT structure. The structural, optical, thermal and electrical properties of the metal/CNT/PVDF composite films demonstrate that the inclusion of the nanofillers leads to the nucleation of the gamma-PVDF phase (up to 90%) and enhance the thermal properties (higher melting point) of the polymer. The nanofillers also proved to be suitability to tailor the optical properties of the polymer composite films and lead to an increase in the d.c. electrical conductivity (up to 10(-13)S/cm). Thus, the reported metal/CNT nanofillers are suitable to tune PVDF polymer properties towards specific applications. |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticlesPiezoelectric polymersPVDFCarbon nanotubesSmart materialsElectrical propertiesScience & TechnologyPolymer composites based on poly(vinylidene fluoride) (PVDF) filled with carbon nanotubes (CNT) decorated with metal nanoparticles (NP) of cobalt, nickel, platinum and palladium have been produced. The CNT nano fillers decorated with metal NP were synthesized by a modified wet impregnation method and their structural, morphological and thermal properties were evaluated. The metal NP ranging from 2 to 10 nm were found well dispersed on the CNT structure. The structural, optical, thermal and electrical properties of the metal/CNT/PVDF composite films demonstrate that the inclusion of the nanofillers leads to the nucleation of the gamma-PVDF phase (up to 90%) and enhance the thermal properties (higher melting point) of the polymer. The nanofillers also proved to be suitability to tailor the optical properties of the polymer composite films and lead to an increase in the d.c. electrical conductivity (up to 10(-13)S/cm). Thus, the reported metal/CNT nanofillers are suitable to tune PVDF polymer properties towards specific applications.This work was supported by the Portuguese Foundation for Science and Technology (FCT) in the framework of the strategic project UID/FIS/04650/2013, by FEDER funds through the COMPETE 2020 - Programa Operacional Competitividade e Internacionalizacao (POCI) with the reference project POCI-01-0145-FEDER-006941. JNP wish to thank the financial support of the project Centro-01-0145-FEDER-000017 - EMaDeS - Energy, Materials and Sustainable Development, co-financed by the Portugal 2020 Program (PT 2020), within the Regional Operational Program of the Center (CENTRO 2020) and the European Union through the European Regional Development Fund (ERDF). JO wish to thank the FCT for the SFRH/BD/98219/2013 grant. The authors also acknowledge funding by the Spanish Ministry of Economy and Competitiveness (MINECO) through the project MAT2016-76039-C4-3-R (AEI/FEDER, UE) (including the FEDER financial support), and financial support from the Basque Government Industry Department under the ELKARTEK Program.info:eu-repo/semantics/publishedVersionElsevier Science LtdUniversidade do MinhoNunes-Pereira, J.Sharmac, P.Fernandes, L. C.Oliveira, J.Moreira, J. A.Sharma, R. K.Lanceros-Méndez, S.20182018-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/57354eng1359-836810.1016/j.compositesb.2017.12.047info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:19:47Zoai:repositorium.sdum.uminho.pt:1822/57354Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:12:45.950008Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles |
title |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles |
spellingShingle |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles Nunes-Pereira, J. Piezoelectric polymers PVDF Carbon nanotubes Smart materials Electrical properties Science & Technology |
title_short |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles |
title_full |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles |
title_fullStr |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles |
title_full_unstemmed |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles |
title_sort |
Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles |
author |
Nunes-Pereira, J. |
author_facet |
Nunes-Pereira, J. Sharmac, P. Fernandes, L. C. Oliveira, J. Moreira, J. A. Sharma, R. K. Lanceros-Méndez, S. |
author_role |
author |
author2 |
Sharmac, P. Fernandes, L. C. Oliveira, J. Moreira, J. A. Sharma, R. K. Lanceros-Méndez, S. |
author2_role |
author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Nunes-Pereira, J. Sharmac, P. Fernandes, L. C. Oliveira, J. Moreira, J. A. Sharma, R. K. Lanceros-Méndez, S. |
dc.subject.por.fl_str_mv |
Piezoelectric polymers PVDF Carbon nanotubes Smart materials Electrical properties Science & Technology |
topic |
Piezoelectric polymers PVDF Carbon nanotubes Smart materials Electrical properties Science & Technology |
description |
Polymer composites based on poly(vinylidene fluoride) (PVDF) filled with carbon nanotubes (CNT) decorated with metal nanoparticles (NP) of cobalt, nickel, platinum and palladium have been produced. The CNT nano fillers decorated with metal NP were synthesized by a modified wet impregnation method and their structural, morphological and thermal properties were evaluated. The metal NP ranging from 2 to 10 nm were found well dispersed on the CNT structure. The structural, optical, thermal and electrical properties of the metal/CNT/PVDF composite films demonstrate that the inclusion of the nanofillers leads to the nucleation of the gamma-PVDF phase (up to 90%) and enhance the thermal properties (higher melting point) of the polymer. The nanofillers also proved to be suitability to tailor the optical properties of the polymer composite films and lead to an increase in the d.c. electrical conductivity (up to 10(-13)S/cm). Thus, the reported metal/CNT nanofillers are suitable to tune PVDF polymer properties towards specific applications. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018 2018-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/57354 |
url |
http://hdl.handle.net/1822/57354 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1359-8368 10.1016/j.compositesb.2017.12.047 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Ltd |
publisher.none.fl_str_mv |
Elsevier Science Ltd |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799132563440140288 |