Molybdenum and tungsten enzymes redox properties – A brief overview

Detalhes bibliográficos
Autor(a) principal: Cordas, Cristina M.
Data de Publicação: 2019
Outros Autores: Moura, José J. G.
Tipo de documento: Outros
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: https://doi.org/10.1016/j.ccr.2019.05.005
Resumo: FCT/ MCTES ( UID/QUI/50006/2019 ).
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spelling Molybdenum and tungsten enzymes redox properties – A brief overviewCatalysisElectrochemistryMetalloproteinsMolybdenumRedox potentialChemistry(all)Physical and Theoretical ChemistryInorganic ChemistryMaterials ChemistryFCT/ MCTES ( UID/QUI/50006/2019 ).Metalloproteins and metal-containing enzymes are well known to be essential to life. Molybdenum and tungsten are the heaviest transition metals used by biology. The mononuclear molybdenum (and tungsten)containing enzymes have in common a particular conserved metal centre (Mo, W)coordinated by one or two pyranopterins. The metal coordination sphere is completed with oxygen and/or sulfur and/or selenium atoms in a diversity of arrangements. The enzymes organized in families (XO, SO and DMSOR)being diverse, can participate in a myriad of reactions involving atom insertion or abstraction and others, with different substrates and partners (physiological or not). The first and second coordination spheres tune the redox properties of the metal centres (and its catalytic features)for a wide range of reactions. In this review, a brief account is given on the main reactions catalysed by this class of enzymes, as well as a representative summary of the redox properties.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNCordas, Cristina M.Moura, José J. G.2022-02-27T01:30:55Z2019-09-012019-09-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/other12application/pdfhttps://doi.org/10.1016/j.ccr.2019.05.005eng0010-8545PURE: 13859254http://www.scopus.com/inward/record.url?scp=85066260970&partnerID=8YFLogxKhttps://doi.org/10.1016/j.ccr.2019.05.005info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T17:40:20Zoai:run.unl.pt:10362/75687Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T17:40:20Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Molybdenum and tungsten enzymes redox properties – A brief overview
title Molybdenum and tungsten enzymes redox properties – A brief overview
spellingShingle Molybdenum and tungsten enzymes redox properties – A brief overview
Cordas, Cristina M.
Catalysis
Electrochemistry
Metalloproteins
Molybdenum
Redox potential
Chemistry(all)
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry
title_short Molybdenum and tungsten enzymes redox properties – A brief overview
title_full Molybdenum and tungsten enzymes redox properties – A brief overview
title_fullStr Molybdenum and tungsten enzymes redox properties – A brief overview
title_full_unstemmed Molybdenum and tungsten enzymes redox properties – A brief overview
title_sort Molybdenum and tungsten enzymes redox properties – A brief overview
author Cordas, Cristina M.
author_facet Cordas, Cristina M.
Moura, José J. G.
author_role author
author2 Moura, José J. G.
author2_role author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Cordas, Cristina M.
Moura, José J. G.
dc.subject.por.fl_str_mv Catalysis
Electrochemistry
Metalloproteins
Molybdenum
Redox potential
Chemistry(all)
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry
topic Catalysis
Electrochemistry
Metalloproteins
Molybdenum
Redox potential
Chemistry(all)
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry
description FCT/ MCTES ( UID/QUI/50006/2019 ).
publishDate 2019
dc.date.none.fl_str_mv 2019-09-01
2019-09-01T00:00:00Z
2022-02-27T01:30:55Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/other
format other
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://doi.org/10.1016/j.ccr.2019.05.005
url https://doi.org/10.1016/j.ccr.2019.05.005
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0010-8545
PURE: 13859254
http://www.scopus.com/inward/record.url?scp=85066260970&partnerID=8YFLogxK
https://doi.org/10.1016/j.ccr.2019.05.005
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 12
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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