Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.26/38426 |
Resumo: | Eggshells wastes are produced in huge amounts worldwide. The recycling or valorization of this waste, which otherwise is usually disposed in landfills, represents an opportunity within a circular economy perspective. In the present work, the potential of chicken eggshell waste to produce calcitic lime was explored. After collection from an industry supplier, the waste was thoroughly characterized for its mineralogical, chemical, and thermal properties. The material was calcined at 1000 °C, and the obtained calcium oxide was evaluated for its reactivity in wet slaking tests. Comparison was made with commercial limestone used as reference. It was found that the calcium oxide from eggshell waste belonged to the most reactive class (R5—60 °C within 10 min), the same of the calcium oxide from limestone. However, different times were obtained to reach 60 °C (25 s and 4:37 min:s) and for 80% of the reaction (28 s and 5 min) for calcium oxide from limestone and eggshell waste, respectively. The lower reactivity of calcium oxide from eggshell waste was related to its larger size particles with smoother surfaces and lower specific surface area in comparison to limestone calcium oxide. Industrial, environmental and economic implications concerning the use of this waste to produce lime were also evaluated. The eggshell waste could be all consumed at an industrial scale in Portugal allowing for approximately 2.6% partial substitution of limestone in a lime factory. |
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Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implicationsBy-productQuicklimeWet slakingHydration rateInduction periodsColourEggshells wastes are produced in huge amounts worldwide. The recycling or valorization of this waste, which otherwise is usually disposed in landfills, represents an opportunity within a circular economy perspective. In the present work, the potential of chicken eggshell waste to produce calcitic lime was explored. After collection from an industry supplier, the waste was thoroughly characterized for its mineralogical, chemical, and thermal properties. The material was calcined at 1000 °C, and the obtained calcium oxide was evaluated for its reactivity in wet slaking tests. Comparison was made with commercial limestone used as reference. It was found that the calcium oxide from eggshell waste belonged to the most reactive class (R5—60 °C within 10 min), the same of the calcium oxide from limestone. However, different times were obtained to reach 60 °C (25 s and 4:37 min:s) and for 80% of the reaction (28 s and 5 min) for calcium oxide from limestone and eggshell waste, respectively. The lower reactivity of calcium oxide from eggshell waste was related to its larger size particles with smoother surfaces and lower specific surface area in comparison to limestone calcium oxide. Industrial, environmental and economic implications concerning the use of this waste to produce lime were also evaluated. The eggshell waste could be all consumed at an industrial scale in Portugal allowing for approximately 2.6% partial substitution of limestone in a lime factory.The authors are grateful to Derovo - Derivados de Ovos, S.A. (Pombal, Portugal) and VAC Minerais, S.A. (Rio Maior, Portugal) for the supply of industrial chicken eggshell waste and commercial limestone, respectively. This research was supported by Sistema de Incentivos à Investigação e Desenvolvimento Tecnológico through Quadro de Referência Estratégica Nacional (QREN) and by Geobiotec R&D Unit (UID/GEO/04035/2013) financed by the Fundação para a Ciência e a Tecnologia (FCT).SpringerRepositório ComumFerraz, EduardoGamelas, José A. F.Coroado, JoãoMonteiro, CarlosRocha, Fernando2021-12-23T00:03:31Z2018-09-032021-12-22T20:10:10Z2018-09-03T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.26/38426eng1359-5997cv-prod-70365110.1617/s11527-018-1243-7metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-10-20T10:52:49Zoai:comum.rcaap.pt:10400.26/38426Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:37:16.066009Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications |
title |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications |
spellingShingle |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications Ferraz, Eduardo By-product Quicklime Wet slaking Hydration rate Induction periods Colour |
title_short |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications |
title_full |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications |
title_fullStr |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications |
title_full_unstemmed |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications |
title_sort |
Eggshell waste to produce building lime: calcium oxide reactivity, industrial, environmental and economic implications |
author |
Ferraz, Eduardo |
author_facet |
Ferraz, Eduardo Gamelas, José A. F. Coroado, João Monteiro, Carlos Rocha, Fernando |
author_role |
author |
author2 |
Gamelas, José A. F. Coroado, João Monteiro, Carlos Rocha, Fernando |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Repositório Comum |
dc.contributor.author.fl_str_mv |
Ferraz, Eduardo Gamelas, José A. F. Coroado, João Monteiro, Carlos Rocha, Fernando |
dc.subject.por.fl_str_mv |
By-product Quicklime Wet slaking Hydration rate Induction periods Colour |
topic |
By-product Quicklime Wet slaking Hydration rate Induction periods Colour |
description |
Eggshells wastes are produced in huge amounts worldwide. The recycling or valorization of this waste, which otherwise is usually disposed in landfills, represents an opportunity within a circular economy perspective. In the present work, the potential of chicken eggshell waste to produce calcitic lime was explored. After collection from an industry supplier, the waste was thoroughly characterized for its mineralogical, chemical, and thermal properties. The material was calcined at 1000 °C, and the obtained calcium oxide was evaluated for its reactivity in wet slaking tests. Comparison was made with commercial limestone used as reference. It was found that the calcium oxide from eggshell waste belonged to the most reactive class (R5—60 °C within 10 min), the same of the calcium oxide from limestone. However, different times were obtained to reach 60 °C (25 s and 4:37 min:s) and for 80% of the reaction (28 s and 5 min) for calcium oxide from limestone and eggshell waste, respectively. The lower reactivity of calcium oxide from eggshell waste was related to its larger size particles with smoother surfaces and lower specific surface area in comparison to limestone calcium oxide. Industrial, environmental and economic implications concerning the use of this waste to produce lime were also evaluated. The eggshell waste could be all consumed at an industrial scale in Portugal allowing for approximately 2.6% partial substitution of limestone in a lime factory. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-09-03 2018-09-03T00:00:00Z 2021-12-23T00:03:31Z 2021-12-22T20:10:10Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.26/38426 |
url |
http://hdl.handle.net/10400.26/38426 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1359-5997 cv-prod-703651 10.1617/s11527-018-1243-7 |
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metadata only access info:eu-repo/semantics/openAccess |
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metadata only access |
eu_rights_str_mv |
openAccess |
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application/pdf |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
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reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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