Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes

Detalhes bibliográficos
Autor(a) principal: Lopes, Susana M. M.
Data de Publicação: 2020
Outros Autores: Melo, Teresa M. V. D. Pinho e
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/90922
https://doi.org/10.1021/acs.joc.9b03151
Resumo: The synthesis of bilanes and hexapyrroles containing an oxime functionality, prepared by two and three consecutive hetero-Diels-Alder reactions (or conjugated additions) between nitrosoalkenes and dipyrromethanes, is described. Bilanes underwent oxidative macrocyclization to afford a new class of trans-A2B-corroles. Porphyrins could also be obtained by reacting bilanes with aldehydes in the presence of trifluoroacetic acid, followed by an oxidative step.
id RCAP_3b33e9bf0166373491b2c9f23b677b27
oai_identifier_str oai:estudogeral.uc.pt:10316/90922
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling Meso-Substituted Corroles from Nitrosoalkenes and DipyrromethanesThe synthesis of bilanes and hexapyrroles containing an oxime functionality, prepared by two and three consecutive hetero-Diels-Alder reactions (or conjugated additions) between nitrosoalkenes and dipyrromethanes, is described. Bilanes underwent oxidative macrocyclization to afford a new class of trans-A2B-corroles. Porphyrins could also be obtained by reacting bilanes with aldehydes in the presence of trifluoroacetic acid, followed by an oxidative step.ACS Publications2020-03-06info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/90922http://hdl.handle.net/10316/90922https://doi.org/10.1021/acs.joc.9b03151eng0022-32631520-6904https://pubs.acs.org/doi/10.1021/acs.joc.9b03151Lopes, Susana M. M.Melo, Teresa M. V. D. Pinho einfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-05-25T05:46:29Zoai:estudogeral.uc.pt:10316/90922Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:10:54.605296Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
title Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
spellingShingle Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
Lopes, Susana M. M.
title_short Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
title_full Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
title_fullStr Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
title_full_unstemmed Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
title_sort Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
author Lopes, Susana M. M.
author_facet Lopes, Susana M. M.
Melo, Teresa M. V. D. Pinho e
author_role author
author2 Melo, Teresa M. V. D. Pinho e
author2_role author
dc.contributor.author.fl_str_mv Lopes, Susana M. M.
Melo, Teresa M. V. D. Pinho e
description The synthesis of bilanes and hexapyrroles containing an oxime functionality, prepared by two and three consecutive hetero-Diels-Alder reactions (or conjugated additions) between nitrosoalkenes and dipyrromethanes, is described. Bilanes underwent oxidative macrocyclization to afford a new class of trans-A2B-corroles. Porphyrins could also be obtained by reacting bilanes with aldehydes in the presence of trifluoroacetic acid, followed by an oxidative step.
publishDate 2020
dc.date.none.fl_str_mv 2020-03-06
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/90922
http://hdl.handle.net/10316/90922
https://doi.org/10.1021/acs.joc.9b03151
url http://hdl.handle.net/10316/90922
https://doi.org/10.1021/acs.joc.9b03151
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0022-3263
1520-6904
https://pubs.acs.org/doi/10.1021/acs.joc.9b03151
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv ACS Publications
publisher.none.fl_str_mv ACS Publications
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1817551245893697536

Registros relacionados