4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate

Detalhes bibliográficos
Autor(a) principal: Martins, João P.
Data de Publicação: 2013
Outros Autores: Martín-Ramos, Pablo, Sobral, Abílio J. F. N., Silva, Manuela Ramos
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/80890
https://doi.org/10.1107/S1600536813014682
Resumo: The asymmetric unit of the title compound, C24H16N2·0.5CH3OH, is comprised of two independent bathophenanthroline mol-ecules (systematic name: 4,7-diphenyl-1,10-phenanthroline) and one methanol mol-ecule. The bathophenanthroline mol-ecules are not planar as there is a considerable rotation of all terminal phenyl rings with respect to the central phenanthroline units [dihedral angles in the range 52.21 (12)-62.14 (10)°]. In addition, a non-negligible torsion is apparent in one of the phenanthroline units: the angle between the mean planes of the two pyridine rings is 14.84 (13)°. The methanol solvent mol-ecule is linked to both N atoms of a bathophenanthroline mol-ecule through a bifurcated O-H⋯(N,N) hydrogen bond.
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spelling 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvateThe asymmetric unit of the title compound, C24H16N2·0.5CH3OH, is comprised of two independent bathophenanthroline mol-ecules (systematic name: 4,7-diphenyl-1,10-phenanthroline) and one methanol mol-ecule. The bathophenanthroline mol-ecules are not planar as there is a considerable rotation of all terminal phenyl rings with respect to the central phenanthroline units [dihedral angles in the range 52.21 (12)-62.14 (10)°]. In addition, a non-negligible torsion is apparent in one of the phenanthroline units: the angle between the mean planes of the two pyridine rings is 14.84 (13)°. The methanol solvent mol-ecule is linked to both N atoms of a bathophenanthroline mol-ecule through a bifurcated O-H⋯(N,N) hydrogen bond.2013info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/80890http://hdl.handle.net/10316/80890https://doi.org/10.1107/S1600536813014682por24046600Martins, João P.Martín-Ramos, PabloSobral, Abílio J. F. N.Silva, Manuela Ramosinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2021-10-29T11:41:08Zoai:estudogeral.uc.pt:10316/80890Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:03:08.828054Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
title 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
spellingShingle 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
Martins, João P.
title_short 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
title_full 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
title_fullStr 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
title_full_unstemmed 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
title_sort 4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate
author Martins, João P.
author_facet Martins, João P.
Martín-Ramos, Pablo
Sobral, Abílio J. F. N.
Silva, Manuela Ramos
author_role author
author2 Martín-Ramos, Pablo
Sobral, Abílio J. F. N.
Silva, Manuela Ramos
author2_role author
author
author
dc.contributor.author.fl_str_mv Martins, João P.
Martín-Ramos, Pablo
Sobral, Abílio J. F. N.
Silva, Manuela Ramos
description The asymmetric unit of the title compound, C24H16N2·0.5CH3OH, is comprised of two independent bathophenanthroline mol-ecules (systematic name: 4,7-diphenyl-1,10-phenanthroline) and one methanol mol-ecule. The bathophenanthroline mol-ecules are not planar as there is a considerable rotation of all terminal phenyl rings with respect to the central phenanthroline units [dihedral angles in the range 52.21 (12)-62.14 (10)°]. In addition, a non-negligible torsion is apparent in one of the phenanthroline units: the angle between the mean planes of the two pyridine rings is 14.84 (13)°. The methanol solvent mol-ecule is linked to both N atoms of a bathophenanthroline mol-ecule through a bifurcated O-H⋯(N,N) hydrogen bond.
publishDate 2013
dc.date.none.fl_str_mv 2013
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/80890
http://hdl.handle.net/10316/80890
https://doi.org/10.1107/S1600536813014682
url http://hdl.handle.net/10316/80890
https://doi.org/10.1107/S1600536813014682
dc.language.iso.fl_str_mv por
language por
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dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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