Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect

Detalhes bibliográficos
Autor(a) principal: Figueiredo, Paulo
Data de Publicação: 1994
Outros Autores: Pina, Fernando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10884/1335
Resumo: The influence of the addition of ionic salts (NaCI, NaBr, Nal, NaCIO,) on anthocyanin equilibria is studied in this work. The effect of their addition is a colour enhancement through the formation of an ion-pair between the charged flavylium cation and the anion, which displaces the equilibria towards the coloured flavylium form. The ion-pair formation is an alternative model to that which suggests a preferable hydration of salt anions instead of the flavylium cation. Throughout this work two natural anthocyanins are studied (malvidin 3,5-diglucoside and malvidin 3-glucoside) as well as one anthocyanidin (malvidin). The thermal and photochemical stability of the ion-pairs formed is also examined. Experiments with a synthetic anthocyanin anaIogue (4',7-dihydroxyf lavyIiu m c hloride) w hich has photochromic properties are also described for comparison purposes
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spelling Formation of Anthocyanin Ion-pairs. A Co-Pigmentation EffectThe influence of the addition of ionic salts (NaCI, NaBr, Nal, NaCIO,) on anthocyanin equilibria is studied in this work. The effect of their addition is a colour enhancement through the formation of an ion-pair between the charged flavylium cation and the anion, which displaces the equilibria towards the coloured flavylium form. The ion-pair formation is an alternative model to that which suggests a preferable hydration of salt anions instead of the flavylium cation. Throughout this work two natural anthocyanins are studied (malvidin 3,5-diglucoside and malvidin 3-glucoside) as well as one anthocyanidin (malvidin). The thermal and photochemical stability of the ion-pairs formed is also examined. Experiments with a synthetic anthocyanin anaIogue (4',7-dihydroxyf lavyIiu m c hloride) w hich has photochromic properties are also described for comparison purposes2018-09-03T22:13:05Z1994-01-01T00:00:00Z1994info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10884/1335engFigueiredo, PauloPina, Fernandoinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-04T11:08:03Zoai:repositorio-cientifico.uatlantica.pt:10884/1335Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:29:54.365652Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
title Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
spellingShingle Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
Figueiredo, Paulo
title_short Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
title_full Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
title_fullStr Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
title_full_unstemmed Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
title_sort Formation of Anthocyanin Ion-pairs. A Co-Pigmentation Effect
author Figueiredo, Paulo
author_facet Figueiredo, Paulo
Pina, Fernando
author_role author
author2 Pina, Fernando
author2_role author
dc.contributor.author.fl_str_mv Figueiredo, Paulo
Pina, Fernando
description The influence of the addition of ionic salts (NaCI, NaBr, Nal, NaCIO,) on anthocyanin equilibria is studied in this work. The effect of their addition is a colour enhancement through the formation of an ion-pair between the charged flavylium cation and the anion, which displaces the equilibria towards the coloured flavylium form. The ion-pair formation is an alternative model to that which suggests a preferable hydration of salt anions instead of the flavylium cation. Throughout this work two natural anthocyanins are studied (malvidin 3,5-diglucoside and malvidin 3-glucoside) as well as one anthocyanidin (malvidin). The thermal and photochemical stability of the ion-pairs formed is also examined. Experiments with a synthetic anthocyanin anaIogue (4',7-dihydroxyf lavyIiu m c hloride) w hich has photochromic properties are also described for comparison purposes
publishDate 1994
dc.date.none.fl_str_mv 1994-01-01T00:00:00Z
1994
2018-09-03T22:13:05Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10884/1335
url http://hdl.handle.net/10884/1335
dc.language.iso.fl_str_mv eng
language eng
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dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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