Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2020 |
| Outros Autores: | , , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10400.21/11101 |
Resumo: | Este trabalho foi financiado pelo Concurso Anual para Projetos de Investigação, Desenvolvimento, Inovação e Criação Artística (IDI&CA) 2019 do Instituto Politécnico de Lisboa. Código de referência IPL/2019/STREAM_ISEL |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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7160 |
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Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalystsIron catalystsAlcohol oxidationBall-millingMechanochemical synthesisMicrowave irradiationUltrasoundInduction heatingMagnetic recoveryEste trabalho foi financiado pelo Concurso Anual para Projetos de Investigação, Desenvolvimento, Inovação e Criação Artística (IDI&CA) 2019 do Instituto Politécnico de Lisboa. Código de referência IPL/2019/STREAM_ISELIron-containingparticulatecatalystsof0.1–1 µmsizewerepreparedbywetandball-milling procedures from common salts and characterized by FTIR, TGA, UV-Vis, PXRD, FEG-SEM, and XPS analyses. It was found that when the wet method was used, semi-spherical magnetic nanoparticles were formed, whereas the mechanochemical method resulted in the formation of nonmagnetic microscale needles and rectangles. Catalytic activity of the prepared materials in the oxidation of 1-phenylethanol to acetophenone was assessed under conventional heating, microwave (MW) irradiation, ultrasound (US), and oscillating magnetic field of high frequency (induction heating). In general, the catalysts obtained by wet methods exhibit lower activities, whereas the materials prepared by ball milling afford better acetophenone yields (up to 83%). A significant increase in yield (up to 4 times) was observed under the induction heating if compared to conventional heating. The study demonstrated that MW, US irradiations, and induction heating may have great potential as alternative ways to activate the catalytic system for alcohol oxidation. The possibility of the synthesized material to be magnetically recoverable has been also verified.MDPIRCIPLSoliman, Mohamed Mostafa AboelhassanKopylovich, Maximilian N.Alegria, ElisabeteDa Costa Ribeiro, Ana PaulaFerraria, Ana MariaRego, AnaCorreia, Luís M. M.Saraiva, Marta S.Pombeiro, Armando2020-02-14T14:58:27Z2020-02-012020-02-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/11101engSOLIMAN, Mohamed M. A.; [et al] – Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts. Molecules. ISSN 1420-3049. Vol. 25, N.º 3 (2020), pp. 1-151420-304910.3390/molecules25030740info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T10:01:57Zoai:repositorio.ipl.pt:10400.21/11101Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:19:25.396681Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts |
| title |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts |
| spellingShingle |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts Soliman, Mohamed Mostafa Aboelhassan Iron catalysts Alcohol oxidation Ball-milling Mechanochemical synthesis Microwave irradiation Ultrasound Induction heating Magnetic recovery |
| title_short |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts |
| title_full |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts |
| title_fullStr |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts |
| title_full_unstemmed |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts |
| title_sort |
Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts |
| author |
Soliman, Mohamed Mostafa Aboelhassan |
| author_facet |
Soliman, Mohamed Mostafa Aboelhassan Kopylovich, Maximilian N. Alegria, Elisabete Da Costa Ribeiro, Ana Paula Ferraria, Ana Maria Rego, Ana Correia, Luís M. M. Saraiva, Marta S. Pombeiro, Armando |
| author_role |
author |
| author2 |
Kopylovich, Maximilian N. Alegria, Elisabete Da Costa Ribeiro, Ana Paula Ferraria, Ana Maria Rego, Ana Correia, Luís M. M. Saraiva, Marta S. Pombeiro, Armando |
| author2_role |
author author author author author author author author |
| dc.contributor.none.fl_str_mv |
RCIPL |
| dc.contributor.author.fl_str_mv |
Soliman, Mohamed Mostafa Aboelhassan Kopylovich, Maximilian N. Alegria, Elisabete Da Costa Ribeiro, Ana Paula Ferraria, Ana Maria Rego, Ana Correia, Luís M. M. Saraiva, Marta S. Pombeiro, Armando |
| dc.subject.por.fl_str_mv |
Iron catalysts Alcohol oxidation Ball-milling Mechanochemical synthesis Microwave irradiation Ultrasound Induction heating Magnetic recovery |
| topic |
Iron catalysts Alcohol oxidation Ball-milling Mechanochemical synthesis Microwave irradiation Ultrasound Induction heating Magnetic recovery |
| description |
Este trabalho foi financiado pelo Concurso Anual para Projetos de Investigação, Desenvolvimento, Inovação e Criação Artística (IDI&CA) 2019 do Instituto Politécnico de Lisboa. Código de referência IPL/2019/STREAM_ISEL |
| publishDate |
2020 |
| dc.date.none.fl_str_mv |
2020-02-14T14:58:27Z 2020-02-01 2020-02-01T00:00:00Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.21/11101 |
| url |
http://hdl.handle.net/10400.21/11101 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
SOLIMAN, Mohamed M. A.; [et al] – Ultrasound and radiation-induced catalytic oxidation of 1-phenylethanol to acetophenone with iron-containing particulate catalysts. Molecules. ISSN 1420-3049. Vol. 25, N.º 3 (2020), pp. 1-15 1420-3049 10.3390/molecules25030740 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
| dc.publisher.none.fl_str_mv |
MDPI |
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MDPI |
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reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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